Synthesis and structure of novel group IV tridentate alkoxide complexes and ceramic thin films derived therefrom. X-ray structures of (HâCC(CHâ-μâ-O)(CHâ-μ-O)â)âTiâ(OCH(CHâ)â)ââ, (HâCCHâC(CHâ-μâ-O)(CHâ-μ-O)â)âTiâ(OCH(CHâ)â)ââ, and (HâCC(CHâ-μ-O)â)âZrâ(μOCH(CHâ)â)â(OCH(CH (original) (raw)

Inorganic Chemistry, 1995

Abstract

An alcoholysis exchange between tris(hydroxymethyl)ethane (THME-Hâ) or tris(hydroxymethyl)propane (THMP-Hâ) and group IV metal isopropoxides yields compounds of the general formula (THMR)âMâ(OCHMeâ)ââ[M = Ti (R = E, 1; P, 2); Zr (R = E, 3; P, 4)]. 1 and 2 are formed in toluene, at ambient glovebox temperatures, and adopt a typical fused-MâOââ structure where each titanium atom is surrounded by

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