Serendipitous synthesis of a cyclopropane-containing taxol analog via anchimeric participation of an unactivated angular methyl group (original) (raw)

Journal of Organic Chemistry, 1993

Abstract

... 1992,33.3979. Chen, S. H.; Combs, CM; Hill, S. E.; Farina, V.; Doyle, T. W. Tetrahedron Lett. 1992, 33, 7679. ... 17, 1993 4521 C7; Le., the geometry is ideal for Clg participation. (3) Participation of a vicinal methyl group usually manifests itself in a 1,2 Wagner-Meerwein shift. ...

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