Evidence for pressure induced polarization rotation, octahedral tilting and reentrant ferroelectric phase in tetragonal (Pb0.5Bi0.5)(Ti0.5Fe0.5)O3 (original) (raw)

Despite the technological significance of the tetragonal PbTiO3 for the piezoelectric transducer industry, its high pressure behaviour is quite controversial as two entirely different scenarios, involving pressure induced (1) morphotropic phase boundary (MPB) like structural transition with concomitant rotation of the ferroelectric polarization vector and (2) antiferrodistortive (AFD) phase transition followed by emergence of a reentrant ferroelectric phase, have been proposed in recent theoretical and experimental studies. We have attempted to address these controversies through a high resolution synchrotron x-ray diffraction study of pressure induced phase transitions in the tetragonal phase of a modified PbTiO3 composition containing 50% BiFeO3, where BiFeO3 was added to enhance the AFD instability of PbTiO3. We present here the first experimental evidence for the presence of the characteristic superlattice reflections due to an AFD transition at a moderate pressure pc1 ~2.15 GPa...