Optimizing the electric field around solid and core-shell alloy nanostructures for near-field applications (original) (raw)

Near-field optical effect of a core-shell nanostructure in proximity to a flat surface

The Journal of Chemical Physics, 2014

We provide an analytical solution to study the near field optical effect of a core-shell nanostructure in proximity to a flat surface, within quasi-static approximation. The distribution of electrostatic potential and field enhancement in this complex geometry are obtained by solving a set of linear equations. This analytical result can be applied to a wide range of systems associated with near field optics and surface plasmon polaritons. As an illustration of the power of this technique, we study the field attenuation effect of oxidized shell in a silver tip in near field scanning microscope. The thickness of oxidized layer can be monitored by measuring the light intensity. In addition, we propose a novel method to detect local temperature with spatial resolution down to nm scale, based on a Ag-Au core-shell structure.

Squeezing the Optical Near-Field Zone by Plasmon Coupling of Metallic Nanoparticles

Physical Review Letters, 1999

We report on the experimental observation of near-field optical effects close to Au nanoparticles using a photon scanning tunneling microscope (PSTM). Constant height operation of the PSTM allowed an unprecedented direct comparison with theoretical computations of the distribution of the optical nearfield intensity. An unexpected squeezing of the optical near field due to plasmon coupling was observed above a chain of Au nanoparticles. [S0031-9007(99)08708-6]

Quantum Confinement Effects on the Near Field Enhancement in Metallic Nanoparticles

In this work, we study the strong confinement effects on the electromagnetic response of metallic nanoparticles. We calculate the field enhancement factor for nanospheres of various radii by using optical constants obtained from both classical and quantum approaches, and compare their size dependent features. To evaluate the scattered near field, we solve the electromagnetic wave equation within a finite element framework. When quantization of electronic states is considered for the input optical functions, a significant blue-shift in the resonance of the enhanced field is observed, in contrast to the case in which functions obtained classically are used. Furthermore, a noticeable underestimation of the field amplification is found in the calculation based on a classical dielectric function. Our results are in good agreement with available experimental reports and provide relevant information on the cross-over between classical and quantum regime, useful in potentiating nanoplasmonics applications.

Near-field plasmonics of gold nanoparticles in dielectric media

Journal of Quantitative Spectroscopy and Radiative Transfer, 2020

Metal nanoparticles have attracted intense attention due to their unique optical and thermal properties for applications such as micro-nano electronics and photonics. Relative orientation, interparticle spacing, and particle size strongly impact the optical behavior of the nanoparticle assemblies. The near-field confinement of electromagnetic fields between closely packed metal nanoparticles, which is enhanced due to their plasmonic behavior, creates high thermal energy densities under visible to near-infrared wavelength laser irradiation. As metal nanoparticles tend to be oxidized or change shape under laser illumination, resulting in non-linear optical and thermal behavior, surrounding each metal nanoparticle with a dielectric shell could be a potential way to mitigate these effects as well as to engineer their plasmonic behavior. In this study, we use numerical simulations to analyze the plasmonic behavior of gold (Au) nanoparticles surrounded with dielectric shell by investigating nanoparticle's various configurations to each other as well as their relative orientation to incoming light source under laser irradiation in dielectric media. Such geometries are of particular interest for applications such as photonic integrated circuits, photonic sintering and nanophotonic cooling.

Near field enhancement due to the optical response of small nanoparticles

In this work, we propose to describe the behavior of the optical response of small metal nanoparticles (particles below 10 nm of radius) as a function of size. We use classical models as well as quantum approaches to study the nanoparticles dielectric function in the whole range of nanometers using two infinite confinements, cubic and spherical, which are simple enough to obtain information of the quantum size effects on the optical response, measured on the enhancement field factor and absorption spectra, to find the limit of pure classical models at the nano-scale finding out enhancement factors of the order of 10310^3103 for small silver nanoparticles. We confirm the plasmon resonance frequency through the absorption spectra, besides that, we have studied the role played by Localized Surface Plasmon Resonance (LSPR) in small metal nanoparticles as a function of the particle size and the environment, which are in good agreement with reported experiments and have found a limit of the c...

Eigenmode Decomposition of the Near-Field Enhancement in Localized Surface Plasmon Resonances of Metallic Nanoparticles

Plasmonics, 2012

I present a direct and intuitive eigenmode method that evaluates the near-field enhancement around the surface of metallic nanoparticles of arbitrary shape. The method is based on the boundary integral equation in the electrostatic limit. Besides the nanoparticle polarizability and the far-field response, the near-field enhancement around nanoparticles can be also conveniently expressed as an eigenmode sum of resonant terms. Moreover, the spatial configuration of the nearfield enhancement depends explicitly on the eigenfunctions of both the BIE integral operator and of its adjoint. It is also established a direct physical meaning of the two types of eigenfunctions.

Mapping the Electromagnetic Near-Field Enhancements of Gold Nanocubes

The Journal of Physical Chemistry C, 2012

We imaged and quantitatively characterized electromagnetic hot spots near the surfaces of plasmon resonant gold nanocubes. The strongest fields are localized at the nanocube corners as compared to those on the sides. The near-field enhancement on the surface of the cube was imaged as a function of incident polarization, leading to information on the localization of fields on specific regions on the surface. We found that the field intensity drops dramatically when the nanocube corner is slightly tilted with respect to the incident laser polarization. This dramatic dependence on angle was verified by electrodynamics simulations. These results will enable the use of gold nanocubes in field enhancement applications and refractive-index sensing.

Probing the Plasmonic Near-Field of Gold Nanocrescent Antennas

ACS Nano, 2010

We present an investigation of the plasmon-induced electromagnetic near-field around gold nanocrescent (NC) antennas which exhibit localized surface plasmon resonances (LSPRs) in the infrared. To probe the near-field behavior, we monitored the LSPR shift of NCs to adsorption of dielectric layers of varying thickness. The experimental results are analyzed using theoretical simulations, and the EM field decay lengths for the NCs are determined. We discuss how the structural properties of NC antennas influence the near-field properties and compare the results with the near-fields of other metal nanostructures. We show that the near-field distribution around NCs depends strongly on the structural parameters of the NC and that its spatial extent can be tuned to large distances (>700 nm) from the nanostructure surface. In addition, we discuss NC antenna structural changes associated with exposure to ethanol and buffer solutions and the impact on LSPR properties.

Comparison of numerical methods in near-field computation for metallic nanoparticles

Optics Express, 2011

Four widely used electromagnetic field solvers are applied to the problem of scattering by a spherical or spheroidal silver nanoparticle in glass. The solvers are tested in a frequency range where the imaginary part of the scatterer refractive index is relatively large. The scattering efficiencies and near-field results obtained by the different methods are compared to each other, as well as to recent experiments on laser-induced shape transformation of silver nanoparticles in glass.

Surface Plasmon Near Field Effects in Silver Nano Cylinders Arranged in Triangular Geometry

Journal of Computational and Theoretical Nanoscience, 2013

We study numerically the near field surface plasmon characteristics of a triangular system of silver nano cylinders that interact with incident plane wave using finite element method as well as 2-D finite difference time domain method. The influence of the dielectric environment, radius, inter particle distance, and orientation of the source plane on the optical resonances of the nano cylinders was investigated. The strength of the near field intensity is found to be strongly dependent on the orientation of the incident field. The number and magnitude of the near field resonances depends on the cylinder dimension as well as the cylinder separation. The plasmon coupling between nanocylinders increases with increase in dielectric constant of the environment and this sensitivity can form the basis for novel plasmonics based chemo-and bio-sensing applications.