Tetra-n-alkyl Ammonium Bromates as a Primary Oxidants in the Oxidation of Alcohols to Carbonyl Compounds (original) (raw)
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Kinetics and mechanism of oxidation of some aryl alcohols by acid bromate
Tetrahedron, 1988
The kinetics of oxidation of sane substituted benzyl alcohols as well as the unsubstituted one by braate ion in hydrochloric acid medium has been suggested. The results. _.. ._ _. _ lnalcste that the reaction takes place by way of intermediate ester formation. Methoxy canpounds react at much faster rates than the corresponding nitro substituted derivatives. The thermodynamic values associated with the equilibria step and also for the 81~~ step have been evaluated. A mechanism consistent with the experimental observations has been suggested.
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