Influence of Base Additive on Nanoporous Carbon Materials via HTC for Catalyst Support (original) (raw)
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Influence of Acid Additive on Nanoporous Carbon Materials via HTC for Catalyst Support
Materials Today: Proceedings, 2020
Nanoporous carbon materials were successfully synthesized via hydrothermal carbonization with acid additives. In this study the effect of hydrothermal temperature (160-200 °C), hydrothermal time (4-24 h) and influence of acid additive (HCl, HNO 3 , H 2 SO 4 and H 3 PO 4) have been chosen in order to improve the surface structure. The samples have been characterized by scanning electron microscopy, nitrogen sorption, Fourier transform infrared spectroscopy and X-ray diffraction. The experimental results revealed that hydrothermal carbonization process and acid addition have effect on the properties of catalyst support. The results indicated that hydrothermal process at 200°C for 12 h and activation with H 3 PO 4 at 900 °C for 2 h, exhibited the highest surface area, porosity and pore volume leading to increased distribution of metal on the carbon support.