Valorization of spent coffee ground through pyrolysis as adsorbent for the removal of Vivizole Red 3BS dye from aqueous solution (original) (raw)
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Water Practice and Technology
Ever-increasing coffee consumption results in the generation of a significant amount of solid residue in the form of spent coffee grounds (SCG) and their subsequent disposal causes environmental pollution. Valorization of SCG through pyrolysis could be one of the solutions to this challenge. Pristine biochar of SCG shows less efficiency to remove dyes from aqueous solutions. Herein, iron(III) salt was used as a catalyst during the carbonization of SCG and has a good graphitization efficiency and thus enhanced the formation of aromatic structures, which provide adsorption sites for the dye. The physical characteristics of the prepared biochar were analyzed by FTIR, XRD, and BET. A predictive model for the removal of the dye was investigated with the Design Expert 11.0 software through the central composite design (CCD) - response surface methodology (RSM) by conducting a batch adsorption study, and the suggested optimum values of the CCD were 10 ppm initial dye concentration, 1 g per...
Journal of Environmental Management, 2013
A friendly environmental material for organic contaminants removal was prepared in this work: small particles of iron oxide dispersed over activated carbon from coffee waste for Fenton-like application. The materials were characterized by means of XRD, N 2 physisorption, Mössbauer spectroscopy and H 2 pulse titration. The composites showed very good catalytic performances for methylene blue organic dye oxidation. The small goethite particles are the predominant iron oxide phase in the composites. The apparent surface area is quite high and is not very affected after iron impregnation. ESI-MS studies revealed that the dye removal occurs through a Fenton-type system by the composite whereas for the activated carbon the dye removal occurs mainly via adsorption. The iron leaching from the catalysts was negligible, less than 0.5 ppm, which evidences the occurrence of a heterogenous oxidation process. The catalyst was very active for methylene blue oxidation and could be repeatedly used for at least 5 cycles. The catalyst was also active in the oxidation of other organic compounds, such as caffeine and atrazine.
Journal of the Brazilian Chemical Society, 2015
New carbon composite materials were prepared by pyrolysis of mixture of coffee wastes and red mud at 700 o C with the inorganic : organic ratios of 1.9 (CC-1.9) and 2.2 (CC-2.2). These adsorbents were used to remove reactive orange 16 (RO-16) and reactive red 120 (RR-120) textile dyes from aqueous solution. The CC-1.9 and CC-2.2 materials were characterized using Fourier transform infrared spectroscopy, Nitrogen adsorption/desorption curves, scanning electron Microscopy and X-ray diffraction. The kinetic of adsorption data was fitted by general order kinetic model. A three-parameter isotherm model, Liu isotherm model, gave the best fit of the equilibrium data (298 to 323 K). The maximum amounts of dyes removed at 323 K were 144.8 (CC-1.9) and 139.5 mg g −1 (CC-2.2) for RO-16 dye and 95.76 (CC-1.9) and 93.80 mg g −1 (CC-2.2) for RR-120 dye. Two simulated dyehouse effluents were used to investigate the application of the adsorbents for effluent treatment.
Catalysts
Green magnetite/carbonized spent coffee (MG/CFC) composite was synthesized from natural pyrite and characterized as an adsorbent and catalyst in photo-Fenton’s oxidation system of Congo red dye (C.R). The absorption behavior was illustrated based on the steric and energetic parameters of the advanced Monolayer equilibrium model of one energetic site (R2 > 0.99). The structure exhibits 855 mg/g as effective site density which induces its C.R saturation adsorption capacity to 436.1 mg/g. The change in the number of absorbed C.R per site with temperature (n = 1.53 (293) to 0.51 (313 K)) suggests changes in the mechanism from multimolecular (up to 2 molecules per site) to multianchorage (one molecule per more than one site) processes. The energetic studies (ΔE = 6.2–8.2 kJ/mol) validate the physical uptake of C.R by MG/CFC which might be included van der Waals forces, electrostatic attractions, and hydrogen bonding. As a catalyst, MG/CFC exhibits significant activity during the photo...
A novel carbon composite was prepared by pyrolysis of mixture of coffee wastes and clay at 700°C with the inorganic : organic ratio of 1.3 (CC-1.3). Considering the application of this adsorbent for removal of anionic dyes, the CC-1.3 was treated with 6 mol L-1 HCl for 24 h to obtain ACC-1.3. FTIR, N2 adsorption/desorption curves, SEM and X-ray diffraction were used for characterisation of the CC-1.3 and ACC-1.3 carbon adsorbents. The adsorbents were effectively utilised for removal of reactive blue 19 (RB-19) and reactive violet 5 (RV-5) textile dyes from aqueous solutions. The maximum amounts of RB-19 dye adsorbed at 25°C were 63.59 (CC-1.3) and 110.6 mg g-1 (ACC- 1.3) and for RV-5 dye were 54.34 (CC-1.3) and 94.32 mg g-1 (ACC-1.3). Four simulated dyehouse effluents were used to test the application of the adsorbents for effluents treatment. Keywords: adsorption, industrial effluents, carbon composites, general order kinetic model, nonlinear isotherms.
Bioresource technology, 2018
Functional carbon materials have been fabricated through simple and effective catalytic carbonization with waste coffee grounds (CGs) as carbon precursor and FeCl as catalyst. The effect of FeCl loading and carbonization temperature on carbon yield was investigated. The morphology and structure of as-synthesized carbons was characterized by scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray diffraction (XRD), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS) and nitrogen isothermal adsorption/desorption measurement, respectively. Furthermore, the carbon materials showed high efficiency for the removal of methylene blue (MB, 653.6 mg g), methyl orange (MO, 465.8 mg g) and rhodamine B (RB, 366.1 mg g). More importantly, the carbon was magnetic, so it can be easily separated by a magnet and reused multiple times. This work not only exploited a low-cost and large-scale preparation method to synthesize functional carbon materials from bioresources,...
Jurnal Teknologi
Used coffee grounds usually end up as landfill. However, the unique structural properties of its porous surface make coffee grounds can be transformed into biochar and performed as an alternative low cost adsorbent. Malachite green (MG) is a readily water soluble dye which is used extensively in textile and aquaculture industries. The mordant complex structures of MG generate destructive effects to animals and environment. In this study, adsorption of malachite green using spent coffee ground biochar as adsorbent was investigated. The experiments were designed in two methods: classical and optimisation by response surface methodology. Three parameters were studied, which are adsorbent dosage, contact time and pH while the responses in this study are malachite green removal (%) and adsorption capacity (mg/g). Optimisation studies were performed using response surface methodology. Quadratic model was chosen for both response and studied using central composite design. The correlation ...
Sustainability, 2022
Biowaste coffee grounds have been recognized as an effective and relatively low-cost adsorbent to complement conventional treatment techniques for removing emerging contaminants (ECs) from the waste stream through modification to useful biochar. The purpose of this study was to make biochar from biowaste coffee grounds through the pyrolysis process and investigate its potential capacity for the removal of pharmaceuticals from water. The biochar was prepared by pyrolysis process under argon gas conditions, and its adsorption capacity for pharmaceuticals was evaluated. The as-prepared biochar shows a surface area of 232 m2 g−1. The adsorption of salicylic acid, diclofenac, and caffeine onto the biochar show adsorption capacities of 40.47 mg g−1, 38.52 mg g−1, and 75.46 mg g−1, respectively. The morphology, functional groups, crystallinity, and specific surface area were determined by SEM, FTIR, XRD, and BET techniques, respectively. Kinetic results reveal that the experimental data fi...
Bulletin of the Chemical Society of Ethiopia
ABSTRACT. This work was conducted to evaluate the adsorption performance of coffee spent modified Fe-Al-Zr composite. The Al2O3/Fe3O4/ZrO2 ternary oxide system was efficiently synthesized from the respective salt precursors by a two-step co-precipitation method under nitrogen atmosphere in basic condition. XRD, SEM-EDX, FTIR and ICP-OES were used to characterize the features of the adsorbents. The pH point of zero charge of the selected adsorbent was also determined. Batch adsorption experiment was conducted under different conditions such as contact time, initial concentration of dye, pH, sorbent dosage and agitation speed. The Langmuir and Freundlich, isotherms were tested to examine the adsorption behavior. The equilibrium data was well fitted to Langmuir isotherm model. The maximum adsorption capacity (qo) was 8.4 mg/g for acidic brown 75 dyes. The kinetic data correlated (R2 = 0.999) well with the pseudo second order kinetic model. To evaluate the practical applicability of the...