Complete Characterization of a Chiral Lewis Acid−Product Complex for the Enantioselective Diels−Alder Reaction between Methacrolein and Cyclopentadiene:  Mechanistic Considerations (original) (raw)

Organometallics, 2007

Abstract

ABSTRACT The Diels−Alder reaction between methacrolein and cyclopentadiene catalyzed by [(η5-C5Me5)Ir{(R)-Prophos}(methacrolein)][SbF6]2 is inhibited by the products, this feature allowing, for the first time, the spectroscopic and crystallographic characterization of the major Lewis acid−product intermediate involving an enal as a dienophile.

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