Syntheses and characterization of binuclear Rh2, Ir2 and RhIr complexes containing dimethyl phosphonate and pyrazolate bridging ligands (original) (raw)

Journal of the Chemical Society, Dalton Transactions, 1996

Daniel CarmonaDaniel Carmona

Abstract

The reaction of [Ir( 5 -C 5 Me 5 )I{PO(OMe) 2 }{P(OH)(OMe) 2 }] with pyrazole (Hpz) in the presence of AgPF 6 gave [Ir( 5 -C 5 Me 5 ){PO(OMe) 2 }{P(OH)(OMe) 2 }(Hpz)]PF 6 1. Deprotonation of 1 with sodium carbonate afforded the neutral compound [Ir( 5 -C 5 Me 5 ){PO(OMe) 2 } 2 ( ...

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