Roadmap on inorganic perovskites for energy applications (original) (raw)
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Energy and Environmental Science, 2018
PAPER Félix Urbain et al. Multijunction Si photocathodes with tunable photovoltages from 2.0 V to 2.8 V for light induced water splitting #These authors contributed equally. Broader Context Clean energy conversion is crucial to sustain the rapid development of human society and mitigate the greenhouse effect and environmental pollution from fossil fuel. Practical utilization of clean energies requires the energy conversions involving different process such as photovoltaics (PV, from solar energy to electrical energy), electrocatalysis (EC, from electrical energy to chemical energy), photocatalysis (PC, from solar energy to chemical energy). A key issue to realize high-efficiency conversion process is to search stable, low-cost and environment-friendly functional materials. Due to the extreme structural and compositional flexibilities, oxide perovskites and their derivates are attractive candidates for the diverse applications aforementioned. This paper reviews the structural and compositional flexibility oxide perovskites and their derivatives and the progress of their applications in clean energy conversion. It attempts to describe how the properties of oxide perovskites and their derivates are tuned for specific applications. Abstract Searching for novel functional materials represents an important direction in the research and development of renewable energy. Due to the unique structural and compositional flexibility and high material stability, oxide perovskites and their derivatives have recently been extensively explored as a class of versatile materials for applications in electrocatalysis (EC), photocatalysis (PC) and photovoltaics (PV), showing great promises in catalytic activity and device stability. In this review, we firstly discuss the extreme flexibilities of oxide perovskites in terms of their structures and compositions, which lead to a treasure trove of materials for diverse applications. Secondly, the current status of their applications and challenges in EC, PC and PV are reviewed. We attempt to build the connections between the structural and compositional flexibility and the tunable materials properties desirable for various applications.
Energy and Environmental Science, 2019
Broader Context Clean energy conversion is crucial to sustain the rapid development of human society and mitigate the greenhouse effect and environmental pollution from fossil fuel. Practical utilization of clean energies requires the energy conversions involving different process such as photovoltaics (PV, from solar energy to electrical energy), electrocatalysis (EC, from electrical energy to chemical energy), photocatalysis (PC, from solar energy to chemical energy). A key issue to realize high-efficiency conversion process is to search stable, low-cost and environment-friendly functional materials. Due to the extreme structural and compositional flexibilities, oxide perovskites and their derivates are attractive candidates for the diverse applications aforementioned. This paper reviews the structural and compositional flexibility oxide perovskites and their derivatives and the progress of their applications in clean energy conversion. It attempts to describe how the properties of oxide perovskites and their derivates are tuned for specific applications.
Advanced Materials, 2019
Solar energy is anticipated to be the most viable source of sustainable green energy. Perovskites have gained significant research attention in recent years as a solar energy harvesting material due to their desirable photovoltaic enabling properties. The potential strategies for a more effective use of these materials can involve multiple energy conversion mechanisms through a single device or employing materials where a solar or thermal input provides multiple electrical outputs to enhance the overall energy harvesting capability. In this context, the present review focuses on perovskites, including both organic halide perovskites and inorganic oxide perovskites, due to their proven properties as photovoltaic materials and their intriguing potential for additional functionality, such as ferroelectricity. Ferroelectrics are a special class of perovskites that have been studied in detail for photoferroic, pyroelectric and thermoelectric effects and energy storage, which we briefly review here. Furthermore, the possibilities of simultaneously tuning these mechanisms in perovskite materials for multiple energy conversion mechanisms and storage for ultra-high density capacitor and battery applications is also examined in order to attain a better understanding and to present novel opportunities. An understanding of all these mechanisms and device prospects will inspire and inform the selection of appropriate materials and potential novel designs so that the available solar and thermal resource could be utilized in a more effective manner. This review will not only help in selecting an appropriate material from the existing pool of perovskite materials, but will also provide an outlook and assistance to researchers in developing new material systems.
Perovskite Materials: Recent Advancements and Challenges
Perovskite Materials, Devices and Integration [Working Title], 2019
In the past decade, hybrid organic-inorganic perovskites (HOIP) have emerged as the exotic materials for the futuristic photovoltaics. The viability of lowtemperature, solution-processed manufacturing and a unique blend of electronic and optical properties that has further indicated its goal towards a potential commercialization. This article clearly articulates the emergence of HOIPs and various challenges such as toxicity, hysteresis in these devices. Additionally, this chapter also makes an effort to highlight the advancements made in the perovskite materials for solar cells in the recent years, that include the Ruddlesden-Popper (RP) phase that has enabled us reach the power conversion efficiency of 28%. This phase is reportedly a lower dimensional structure than the conventional HOIP and exhibit better stability than the latter. This chapter also focuses to elucidate a few challenges of these RP phased HOIPs such as its synthesis, stoichiometry and process-ability in integrating the organic and inorganic entities.
Perovskite nanocrystals for energy conversion and storage
Nanophotonics
The high demand for energy consumption in everyday life, and fears of climate change are driving the scientific community to explore prospective materials for efficient energy conversion and storage. Perovskites, a prominent category of materials, including metal halides and perovskite oxides have a significant role as energy materials, and can effectively replace conventional materials. The simultaneous need for new energy materials together with the increased interest for making new devices, and exploring new physics, thrust the research to control the structuring of the perovskite materials at the nanoscale. Nanostructuring of the perovskites offers unique features such as a large surface area, extensive porous structures, controlled transport and charge-carrier mobility, strong absorption and photoluminescence, and confinement effects. These features together with the unique tunability in their composition, shape, and functionalities make perovskite nanocrystals efficient for en...
2017
Solar energy is anticipated to be the most viable source of sustainable green energy. Perovskites have gained significant research attention in recent years as a solar energy harvesting material due to their desirable photovoltaic enabling properties. The potential strategies for a more effective use of these materials can involve multiple energy conversion mechanisms through a single device or employing materials where a solar or thermal input provides multiple electrical outputs to enhance the overall energy harvesting capability. In this context, the present review focuses on perovskites, including both organic halide perovskites and inorganic oxide perovskites, due to their proven properties as photovoltaic materials and their intriguing potential for additional functionality, such as ferroelectricity. Ferroelectrics are a special class of perovskites that have been studied in detail for photoferroic, pyroelectric and thermoelectric effects and energy storage, which we briefly r...
ACS Energy Letters, 2019
Since the first report of all-inorganic perovskite solar cells (PSCs) in 2014, more than 200 research articles have been published on this topic, reporting the enhancement in the stabilized power conversion efficiency (PCE) up to 18.4%. All-inorganic PSC has become one of the most astonishing research domains in the field of perovskite-based photovoltaics. In this review article, significant improvements in all-inorganic PSCs are analytically reviewed, with some insight kinetics of intrinsic phase, light and thermal stability of all-inorganic perovskites. Theoretical calculations specify that there is still a large capacity in further enhancement of device parameters. The critical challenges and the possible elucidations concerning improving the performance of allinorganic PSCs are also conferred. Our focus is towards the assessment of all-inorganic perovskite materials' properties and to recapitulate latest approaches to improve the PCE of corresponding devices, in order to introduce new horizons in the way of commercialization.
The expanding world of hybrid perovskites: materials properties and emerging applications
MRS Communications, 2015
Hybrid inorganic–organic perovskites have emerged over the last 5 years as a promising class of materials for optoelectronic applications. Most notably, their solar cells have achieved power conversion efficiencies above 20% in an unprecedented timeframe; however, many fundamental questions still remain about these materials. This Prospective Article reviews the procedures used to deposit hybrid perovskites and describes the resulting crystallographic and morphological structures. It further details the electrical and optical properties of perovskites and then concludes by highlighting a number of potential applications and the materials challenges that must be overcome before they can be realized.
Chemistry of Materials
The article primarily reflects the views of these authors, who were primarily responsible for writing the text and compiling the data ABSTRACT: Recently, there has been an explosive growth in research based on hybrid lead-halide perovskites for photovoltaics owing to rapid improvements in efficiency. The advent of these materials for solar applications has led to widespread interest in understanding the key enabling properties of these materials. This has resulted in renewed interest in related compounds and a search for materials that may replicate the defect-tolerant properties and long lifetimes of the hybrid lead-halide perovskites. Given the rapid pace of development of the field, the rises in efficiencies of these systems have outpaced the more basic understanding of these materials. Measuring or calculating the basic properties, such as crystal/electronic structure and composition, can be challenging because some of these materials have anisotropic structures, and/or are composed of both heavy metal cations and volatile, mobile, light elements. Some consequences are beam damage during characterization, composition change under vacuum, or compound effects, such as the alteration of the electronic structure through the influence of the substrate. These effects make it challenging to understand the basic properties integral to optoelectronic operation. Compounding these difficulties is the rapid pace with which the field progresses. This has created an ongoing need to continually evaluate best practices with respect to characterization and calculations, as well as to identify inconsistencies in reported values to determine if those inconsistencies are rooted in characterization methodology or materials synthesis. This article describes the difficulties in characterizing hybrid lead-halide perovskites and new materials, and how these challenges may be overcome. The topic was discussed at a seminar at the 2015 Materials Research Society Fall Meeting & Exhibit. This article highlights the lessons learned from the seminar and the insights of some of the attendees, with reference to both recent literature and controlled experiments to illustrate the Page 2 of 39 ACS Paragon Plus Environment Chemistry of Materials 2 challenges discussed. The focus in this article is on crystallography, composition measurements, photoemission spectroscopy and calculations on perovskites and new, related absorbers. We suggest how some of the important artifacts could be avoided and how the reporting for each technique could be streamlined between groups to ensure reproducibility as the field progresses.
Oxygen evolution reaction …………………………………………....19 CHAPTER 2. TRANSFORMATION OF STRUCTURE, ELECTRICAL CONDUCTIVITY AND MAGNETISM IN AA'Fe2O6-δ, A=Sr, Ca and A'= Sr..…... 21 Introduction ………………………………………………………………….. 21 Experimental ……... …………………………………………………………. 23 Results and discussion ………………………………………………………. 25 Crystal structure ……………………………………………………... 25 Magnetic structure …………………………………………………… 33 Electrical Properties ………………………………………………..… 36 Conclusion ………………………………………………………………...…. 43 CHAPTER 3. UNRAVELING THE ROLE OF STRUCTURAL ORDER IN TRANSFORMATION OF ELECTRICAL CONDUCTIVITY IN Ca2FeCoO6-δ, CaSrFeCoO6-δ and Sr2FeCoO6-δ …………………………………………………..….. 44 ix Introduction ………………………………………………………………...…. 44 Experimental ………………………………………………………………..…. 46 Results and discussion …………………………………….…………………. 48 Crystal structure ………………………………………….…………… 48 X-ray photoelectron spectroscopy …………………………………… 61 Electrical conductivities ……………………………………...………. 65 Conclusion …………………………………………………………………….. 73 CHAPTER 4. MAGNETIC STRIUCTURE OF CaSrFeCoO5 ………………..……… 75 Introduction …………………………………………………………….……….75 Experimental section ……………………………………………….………….. 77 Results and discussion ………………………………………………………….……. 78 Conclusion ……………………………………………………………….…………… 86 CHAPTER 5. ELECTRICAL PROPERTIES OF ORDERED OXYGEN-DEFICIENT PEROVSKITE Ca2Fe0.5Ga1.5O5…………..…..……………………………………….. 87 Introduction …………………………………………….……………………. 87 Materials and methods ………………………………….……………………. 90 Results and discussion ……………………………………...……….…………91 Crystal structure …………………………………………….….……… 91 x Electrical properties ………………………………..………….……… 94 Conclusion ……………………………………………..…………..…………. 99 CHAPTER 6. ENHANCED ELECTRICAL PROPERTIES OIN BaSrFe2O6-δ (δ=0.5): A DISORDERED DEFECT-PEROVSKITE………………………..………………..…. 100 Introduction …………………………………………………….…………… 100 Experimental……… ………………………………………..……………….. 102 Results and discussion …………………………………………..…………… 103 Crystal structure …………………………………………………...…. 103 Magnetic properties ………………………………………...…………109 Electrical properties ………………………………………………….. 111 Conclusion ……………………………………………….………………….. 115 CHAPTER 7. CHARGE-TRANSPORT PROPERTIES OF Ca2FeGaO6-δ AND CaSrFeGaO6-δ: THE EFFECT OF DIFECT-ORDERED .……………………...…….. 117 Introduction ………………………………………………………………….. 117 Experimental …………………………………………….………………….. 120 Results and discussion ………………………………..……………………… 121 Crystal structure ……………………………………………….…….. 121 Microstructure and X-ray photoelectron spectroscopy studies…………125 Electrical properties ………………………………….………………. 127 Conclusion ………………………………………………………..…………. 133 xi CHAPTER 8. DISPARITY IN ELECTRICAL AND MAGNETIC PROPERTIES OF ISOSTRUCTURAL OXYGEN-DEFICIENT PEROVSKITES BaSrCo2O6-δ AND BaSrCoFeO6-δ ………..………….……………………………………………..…….. 134 Introduction ……………………………………………………….…………. 134 Experimental……… …………………………………….….………………… Results and discussion …………………………………….……...………….. Crystal structure and crystallite morphology …….………….………… X-ray photoelectron spectroscopy (XPS) and iodometric titration ….…141 Magnetic properties ……………………………………………....…… Electrical conductivities ………………………………………..……... 147 Conclusion …………………………………………………………….……… CHAPTER 9. STRUCTURE-DEPEDANCE OF ELECTRICAL CONDUCTIVITY AND ELECTROCATALYTIC PROPERTIES OF Sr2Mn2O6 and CaSrMn2O6 ………..…..154 Introduction ……………………………………………….………………….. Experimental ………. ………………………………………………………… Results and discussion ………………………………………………………… Crystal structure …………………………...…………………………. Electrical properties …………………………...………………………. Correlation between electrocatalytic activity and conductivity …….….164 Conclusion …………………………………………………………………….. xii CHAPTER 10. VARIATION IN ELECTRICAL CONDUCTIVITY OF A2Fe2O5 (A=Sr, Ba) ….…….