One-Pot Enantioselective Formation of Eight-Membered Rings from Alkenyl Fischer Carbene Complexes and Ketone Enolates (original) (raw)
Journal of The American Chemical Society, 2002
Abstract
Eight-membered carbocycles with up to five new stereogenic centers are enantioselectively obtained following a one-pot procedure that involves the coupling of three components: an alkenyl Fischer carbene complex, a ketone enolate, and allyl lithium.
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