Super-resolution from single photon emission: toward biological application (original) (raw)

2017

Properties of quantum light represent a tool for overcoming limits of classical optics. Several experiments have demonstrated this advantage ranging from quantum enhanced imaging to quantum illumination. In this work, experimental demonstration of quantum-enhanced resolution in confocal fluorescence microscopy will be presented. This is achieved by exploiting the non-classical photon statistics of fluorescence emission of single nitrogen-vacancy (NV) color centers in diamond. By developing a general model of super-resolution based on the direct sampling of the kth-order autocorrelation function of the photoluminescence signal, we show the possibility to resolve, in principle, arbitrarily close emitting centers. Finally, possible applications of NV-based fluorescent nanodiamonds in biosensing and future developments will be presented.

Nitrogen-Vacancy color center in diamond-emerging nanoscale applications in bioimaging and biosensing

Current opinion in chemical biology, 2014

Nitrogen-Vacancy (NV) color center in diamond is a flourishing research area that, in recent years, has displayed remarkable progress. The system offers great potential for realizing futuristic applications in nanoscience, benefiting a range of fields from bioimaging to quantum-sensing. The ability to image single NV color centers in a nanodiamond and manipulate NV electron spin optically under ambient condition is the main driving force behind developments in nanoscale sensing and novel imaging techniques. In this article we discuss current status on the applications of fluorescent nanodiamonds (FND) for optical super resolution nanoscopy, magneto-optical (spin-assisted) sub-wavelength localization and imaging. We present emerging applications such as single molecule spin imaging, nanoscale imaging of biomagnetic fields, sensing molecular fluctuations and temperatures in live cellular environments. We summarize other current advances and future prospects of NV diamond for imaging a...

Single spins in diamond for nanoscale sensing and microscopy

2017

This thesis is dedicated to applications of nanodiamonds with colour centres for imaging and magnetic field sensing. Diamond nanocrystals with optically active defects such as nitrogen-vacancy (NV) or silicon-vacancy (SiV) can be used as optical markers. They are characterized by highly stable emission in contrast to other known optical markers. Owing to this they are attractive for studies of biological systems. First part of this thesis demonstrates application of nanodiamonds for drug delivery process. Stabilization of the nanocrystal’s surface in different solutions was achieved by coating with HSA-protein. Utilizing protein-protected nanodiamonds as carriers for chemotherapy drug (Doxorubicin), targeted delivery to the acidic tumor was demonstrated. Pre-clinical test proved the effectivity of this method compared to free drug molecules. The negatively charged nitrogen-vacancy centre due to unique combination of its optical and spin properties can be used as an atomic scale magn...

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