Solid-state spun fibers and yarns from 1-mm long carbon nanotube forests synthesized by water-assisted chemical vapor deposition (original) (raw)
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Structure and process-dependent properties of solid-state spun carbon nanotube yarns
Journal of Physics: Condensed Matter, 2010
The effects of processing conditions and apparent nanotube length on properties are investigated for carbon nanotube yarns obtained by solid-state drawing of an aerogel from a forest of multi-walled carbon nanotubes. Investigation of twist, false twist, liquid densification and combination methods for converting the drawn aerogel into dense yarn show that permanent twist is not needed for obtaining useful mechanical properties when nanotube lengths are long compared with nanotube diameters. Average mechanical strengths of 800 MPa were obtained for polymer-free twist-spun multi-walled carbon nanotube (MWNT) yarns and average mechanical strengths of 1040 MPa were obtained for MWNT yarns infiltrated with 10 wt% polystyrene solution. Strategies for increasing the mechanical properties are suggested based on analysis of intra-wall, intra-bundle and inter-bundle stress transfer.
Journal of Nanoscience and Nanotechnology, 2012
Continuous carbon nanotubes (CNT) fibers were directly spun from a vertically aligned CNT forest grown by a plasma-enhanced chemical vapor deposition (PECVD) process. The correlation of the CNT structure with Fe catalyst coarsening, reaction time, and the CNTs bundling phenomenon was investigated. We controlled the diameters and walls of the CNTs and minimized the amorphous carbon deposition on the CNTs for favorable bundling and spinning of the CNT fibers. The CNT fibers were fabricated with an as-grown vertically aligned CNT forest by a PECVD process using nanocatalyst an Al 2 O 3 buffer layer, followed by a dry spinning process. Well-aligned CNT fibers were successfully manufactured using a dry spinning process and a surface tension-based densification process by ethanol. The mechanical properties were characterized for the CNT fibers spun from different lengths of a vertically aligned CNT forest. Highly oriented CNT fibers from the dry spinning process were characterized with high strength, high modulus, and high electrical as well as thermal conductivities for possible application as ultralight, highly strong structural materials. Examples of structural materials include space elevator cables, artificial muscle, and armor material, while multifunctional materials include E-textile, touch panels, biosensors, and super capacitors.
Improved Processing of Carbon Nanotube Yarn
Journal of Nanomaterials
We compared mechanical and electrical properties of carbon nanotube (CNT) yarns formed from four different spinning methods. In these methods, a yarn was spun from two aligned CNT arrays. CNT yarns fabricated from each method were tested quantitatively through the mechanical and electrical properties and reported. This improvement is considered to be caused by multiple factors, such as reduction of the yarn diameter, densification, water evaporation, and CNT orientation. The best electrical and mechanical property of CNT yarn was observed from the fourth spinning method where heating and tension during spinning were applied. The introduced yarn spinning methods are appropriate for continuous mass production of high strength carbon nanotube yarns with controlled diameter, strength, and electrical conductivity.
Synthesis of carbon nanotube fiber via direct spinning for conducting wires
2021
The commercial conducting materials (Cu, Ag, Al etc.) have achieved their saturation due to their high density andJoule’s heating effect in terms of efficiency. In this outlook, carbon nanotubes (CNTs) are the most versatile, light weightand high electrically conducting material for advance generation. But it is difficult to weave them for commercialization.For the growth of 3-D CNT assemblies such as CNT fiber, CNT sheet, CNT rope and CNT ribbon, direct spinning is themost suitable technique because of its simplicity for continuous growth of CNT fiber. In the present work, different growthparameters were analysed for the growth of CNT fibers. The growth of CNT fibres has been carried out through directspinning of as-synthesised CNT aerogel. CNT fibers were grown successfully via optimizing different processingparameters like temperature, pressure and argon to hydrogen ratio. The morphology of as-spun fibers was investigated viamicroscopic techniques such as optical microscopy, SEM ...
A review on conducting carbon nanotube fibers spun via direct spinning technique
Journal of Materials Science, 2020
Due to our modern standard of living, the demand of electrical energy is growing rapidly. To meet this exigency, the conventional metal wires have become obsolete to meet highly efficient electrical energy supply demands. The suitable alternative to metal wires must exhibit good electrical and thermal conductivity, low mass density, negligible skin effects and non-corrosive properties. The axially aligned carbon nanotubes (CNT) assemblies, the CNT fibers, are among the most promising materials to meet these requirements. The CNT fibers hold great potential for highly fuel-efficient electric vehicles and low-power nanochips in ever-advancing computer hardware where conventional wires have no future. This article provides an overview of the conducting nature of CNT fibers. First, CNTs as futuristic conducting material will be elucidated briefly, followed by synthesis techniques of CNT fiber. Specific attention is devoted to the direct spinning technique (FC-CVD) as the fiber produced by this method has quite high electrical conductivity (EC) and of limitless length. Then, the effect of various parameters (during synthesis like carrier gas or feedstock flow rate and after synthesis like doping of metallic nanomaterials, coating of polymers or interaction with the acidic environment) on its EC is discussed. This study would pave the way for the bright future of CNT fiber to be used as electrical wiring by concentrating on current challenges confronting this field.
Systematic Investigations of Annealing and Functionalization of Carbon Nanotube Yarns
Molecules, 2020
Carbon nanotube yarns (CNY) are a novel carbonaceous material and have received a great deal of interest since the beginning of the 21st century. CNY are of particular interest due to their useful heat conducting, electrical conducting, and mechanical properties. The electrical conductivity of carbon nanotube yarns can also be influenced by functionalization and annealing. A systematical study of this post synthetic treatment will assist in understanding what factors influences the conductivity of these materials. In this investigation, it is shown that the electrical conductivity can be increased by a factor of 2 and 5.5 through functionalization with acids and high temperature annealing respectively. The scale of the enhancement is dependent on the reducing of intertube space in case of functionalization. For annealing, not only is the highly graphitic structure of the carbon nanotubes (CNT) important, but it is also shown to influence the residual amorphous carbon in the structur...