Structural changes in ethanol–water mixtures: Ultrasonics, Brillouin scattering and molecular dynamics studies (original) (raw)

Vibrational Spectroscopy, 2012

Abstract

ABSTRACT Mixing of two hydrogen-bonded liquids may lead to significant composition dependent changes of liquid microscopic structure, which in turn will be reflected by changes of the corresponding thermodynamic, thermophysical and spectroscopic properties. For the liquid system {xEtOHC2H5OH+(1−xEtOH)H2O} at ambient temperatures and pressures, we show that major structural rearrangements occur in the composition range of 0.15

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