High Specific Activity of Radium Isotopes in Baryte from the Czech Part of the Upper Silesian Basin—An Example of Spontaneous Mine Water Treatment (original) (raw)

Radium-bearing barytes (radiobarytes) have been known since the beginning of the 20th century. They are mainly found as precipitates of low-temperature hydrothermal solutions. In anthropogenic environments, they frequently occur as crusts on oil industry equipment used for borehole extraction, in leachates from uranium mill tailings, and as a by-product of phosphoric acid manufacturing. Recently, we recognized Ra-rich baryte as a precipitate in the water drainage system of a bituminous coal mine in the Czech part of the Upper Silesian Basin. The precipitate is a relatively pure baryte, with the empirical formula (Ba0.934Sr0.058Ca0.051Mg0.003)Σ1.046S0.985O4.000. The mean specific activity of 226Ra was investigated by the two-sample method and it equals 39.62(22) Bq/g, a level that exceeds known natural occurrences. The values for 228Ra and 224Ra are 23.39(26) Bq/g and 11.03(25) Bq/g. The radium content in the baryte is 1.071 ng/g. It is clear that the Ra-rich baryte results from the ...