Nanometergroße, rein organische Moleküle mit unterschiedlichen Oxidationsstufen an den Enden und langreichweitigem Elektronentransfer — Synthese sowie optische und EPR-Untersuchungen des Radikalanions eines Bis(triarylmethyl)-Diradikals (original) (raw)

Radikalionen, 47. Notiz: Die Strukturänderung während der Einelektronen‐Oxidation von Bis(dimethylamino)disulfid

Chemische Berichte, 1981

Radical Ions, 47. Note on the Structural Change during the One‐Electron Oxidation of Bis(dimethylamino) DisulfideOn one‐electron oxidation, (H3C)2NSSN(CH3)2 considerably changes its structure: where as the neutral molecule according to the ionization band pattern of the PE spectrum displays N and S lone pairs perpendicular to each other, as ESR spectroscopic comparison suggests a planarized skeleton for the radical cation. INDO closed and open shell total energy hypersurfaces for the model compounds H2NSSNH2 and support the discussion of the spectra.