Schiff base complexes of organotin(IV): infrared and mössbauer studies on the addition complexes of N-alkyl(aryl)salicylideneimines (original) (raw)

Journal of Organometallic Chemistry, 1979

Abstract

ABSTRACT Fourteen new addition complexes of the type R2SnCl2 · 2 HOC6H4CHNR′ have been synthesized by the reactions of diorganotin dichlorides, R2SnCl2 (where R = Me, Et, n-Bu and Ph), with N-alkyl(aryl)salicylideneimines, HOC6H4CHNR′ (where R′ = Me, Et, n-Bu and Ph), in non-aqueous solvents. The complexes are non-electrolytes in nitrobenzene. Infrared and Mössbauer spectroscopic studies indicate an all-trans octahedral geometry for the complexes.

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