B-Substituted Carboranyl Thio- and Selenophosphites. Synthesis and Chemical Properties (original) (raw)

1996, Phosphorus, Sulfur, and Silicon and the Related Elements

AI-generated Abstract

The study reports the synthesis of B-substituted carboranyl thio- and selenophosphites, highlighting their chemical properties. These compounds were derived from the reactions of diethylchlorphosphites with mercapto- or selenocarboranes in the presence of triethylamine. The research reveals that the synthesized thiophosphites exhibit enhanced reactivity due to the electron donor properties of the B-carborane-Pyl group, facilitating interactions with oxygen, sulfur, and selenium.

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