Least Square and Gauss Jordan Methods applied to fit the Dielectric data Vs. Concentration of Ionic Liquids (original) (raw)

2013

Abstract

Ionic liquids are not only prominent for life but also important in chemical and biological industry. Starting from DebyeHuckel theory of electrolytes, a rich progress in theoretical and experimental studies was made over the past hundred years. K.S.Pitzer developed a set of equations for six coefficients on the basis of virial theorem and Statistical thermodynamics , starting from the Debye-Huckel model .He adopted calculations of Guggenheim ,with the modification of Scatchard ,Hammer and Bronsted to incorporate specific interactions, for electrolytic state ,in which terms related to short range forces between ions were partly accounted. However the very significant lowering of Dielectric constant of solvent continuum on addition of electrolyte, as modeled by Glueckauff was not considered in their work. We report a better & more general method of possible correction starting with the dielectric data of Brahmajirao, P.S.K.M.Rao and Sastry by using Least Square and Gauss Jordan Techn...

shahnaz bathul hasn't uploaded this paper.

Let shahnaz know you want this paper to be uploaded.

Ask for this paper to be uploaded.