The Impact of the Degree of Urbanization on Spatial Distribution, Sources and Levels of Heavy Metals Pollution in Urban Soils—A Case Study of the City of Belgrade (Serbia) (original) (raw)
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In urban areas, the presence of toxic microelements in the environment due to the anthropogenic impact (primarily of traffic) poses a serious problem. The negative impact of pollution on populated urban areas is particularly manifest in children. To establish the level of microelement pollution, at 40 localities in the municipality of Stari grad in Belgrade we sampled surface soil near kindergartens and schools during 2013. By applying remote sensing and GIS, small green areas were selected and the spatial distribution of microelements was determined. Because of their different origins and anthropogenic impact, three heavy metals, Cd, Ni and Zn, were examined; the level of soil pollution was assessed by determining their total content, pollution index (Pi), enrichment factor (EF), single risk factor (Ei) and ecological risk index (RI). The highest concentration established was that of Zn, with a mean value of 223.11 mg/kg. The Pi values for Zn (2.96) and Cd (2.98) were similar. Due to the prevailing geological substrate, Ni had the lowest EF (0.75) and Ei (3.09). The effect of the geological substrate on the Ni content was also confirmed by its very high concentration along the banks of the rivers Sava and Danube, while the total contents and factors for Cd and Zn indicated that they were concentrated in the city center. Our results show that 30.72% of the green areas in the city center have a moderate RI, which indicates that the examined pollutants do not present a danger to children.
Archives of environmental contamination and toxicology, 2018
The main soil properties, concentrations of selected elements (As, Cd, Cr, Cu, Fe, Mn, Ni, Pb, and Zn), and the chemical speciation of each element were determined in urban soil samples taken from urban parks in four Serbian cities (Belgrade, Pančevo, Obrenovac, and Smederevo) exposed to different sources of pollution. Pollution indices (PI, PI) and factors (MF, ICF, GCF) also were evaluated. The study revealed As and Cd concentrations below the detection limit, whereas the content of Cr, Cu, Fe, Mn, Ni, Pb, and Zn at some sites exceeded the limits established by local regulations, as well as the background values, which may represent an environmental threat. Sequential extraction results show that Fe, Cr, Cu, and Ni were predominantly in the residual fraction at most sites; however, Ni from Pančevo and Smederevo also was bound to the reducible fraction. The presence of Pb at all sites and Zn in Smederevo and Belgrade was mainly associated with the reducible and residual fractions. ...
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Characterization of spatial variation of heavy metals in urban soils is essential to identify pollution sources and potential risks to humans and the environment. While heavy metals concentration in soils depends also on the nature of bedrock and on abiotic and biotic factors, it can be argued that nowadays, due to increasing human activities, it is determined mainly by anthropogenic sources. We determined concentrations and spatial distribution of heavy metals, with particular focus on those potentially toxic (As, Cr, Pb, V, and Zn), in urban and peri-urban soils of Cosenza-Rende (southern Italy). One hundred forty-nine samples of topsoil (0-10 cm) were collected and analyzed for 36 elements by X-ray fluorescence spectrometry and inductively coupled plasma mass spectrometry (ICP-MS). In addition, 18 samples of rocks were collected on outcrops of whole area and analyzed by ICP-ES and ICP-MS. Geostatistical methods were used to map the concentrations of major oxides and several minor elements. Heavy metals in the analyzed samples showed a wide range of concentrations, primarily controlled by the geochemical composition of bedrock, with the notable exceptions of Cu, Pb, and Zn, whose concentrations are heavily affected by land use and anthropogenic pollution in urban areas. Geochemical analysis and spatial distribution showed that high concentrations of potentially toxic elements are found in soils near major roads, indicating that anthropogenic factors determine the anomalies in these areas.
Heavy metals distribution in agricultural topsoils in urban area
Environmental Earth Sciences, 2003
Intensive urbanisation of the Croatian capital of Zagreb has led to a situation where very good agricultural soils, developed mostly on Pleistocene eolian sediments and alluvial and proluvian Holocene sediments are entrapped within urban and suburban areas. Therefore the influence of urban and industrialised environments on the accumulation of metals in agricultural topsoils has been investigated. On an area of 860 km2 of the wider Zagreb region, 331 samples were taken according to a regular 1×1 km square mesh. Samples were dissolved in aqua regia and analysed for Cd, Cu, Fe, Mn, Ni, Pb and Zn with flame atomic aqua regia absorption spectroscopy. The following concentration ranges have been determined: Cd 0.25–3.85 mg kg–1 (average 0.66 mg kg–1), Cu 4.30–183 mg kg–1 (average 20.8 mg kg–1), Fe 5.8–51.8 g kg–1 (average 27 g kg–1), Mn 79.2–1282 mg kg–1 (average 613 mg kg–1), Ni 0.70–282 mg kg–1 (average 49.5 mg kg–1), Pb 1.50–139 mg kg–1 (average 25.9 mg kg–1), and Zn 15.2–277 mg kg–1 (average 77.9 mg kg–1). Visualisation of the spatial data is made by the aid of GIS, and selected maps of the heavy metal concentrations in topsoils are displayed. Statistical multivariate analysis was carried out for quantitative study and data were processed by means of R-mode factor analysis, applying the varimax-raw rotational technique. F1, which grouped Cd, Pb, Cu, Zn and partially Ni, is characterized as a factor with strongly scattered anthropogenic influence. The elements in F2, Fe, Mn and partially Ni are mainly of geogenic, i.e. pedogenic, origin. The variations in concentrations of the investigated elements are thus of both natural and anthropogenic origins. The variations in the main soil constituents, particularly Fe and Mn, are determined primarily by the composition of different regolithic substrates of the fluvial origin in recent pedogenesis. High concentrations of nickel are also related to morphogenetic characteristics of the wider region, primarily basic and ultrabasic magmatic rocks of the surrounding mountain range. It is, however, assumed that the anomalous nickel concentrations in the vicinity of the highway and the airport are of anthropogenic origin, i.e. caused by fuel combustion. Copper is characterized by strongly scattered anthropogenic influence, which is related particularly to uncontrolled solid waste disposals or discharges of liquid waste from households or agricultural enterprises. With Zn, Pb and Cd, there are two possible ways of diffuse pollution. The Sava River, which drains the area and feeds the abundant Quaternary aquifer spreading below the major part of the investigated agricultural areas, has been exposed to intensive pollution by mining, industry and cities in the recent history. The part of the area with the highest determined concentrations of Zn, Pb and Cd was repeatedly flooded as recently as the previous decade; therefore, the recent sedimentation of the river deposits exposed to pollution is a very probable cause of the accumulation of metals in this until recently inundation area. The other way is atmospheric deposition of particles from urban sources (industrial emission, traffic, waste disposals, heating plants, etc.). In addition to agricultural enterprises, several economically important, but ecologically risky, facilities are situated in the vicinity of the water-protection area. The area is intersected by a very busy ring road, while a marshalling yard, the city dump, pharmaceutical and chemical industry, the district-heating plant and the airport are all located in close proximity. The geochemical maps show a clear relationship between human activities and metal concentration gradients.
Molecules, 2020
The pollution of urban soils by metals is a global problem. Prolonged exposure of habitants who are in contact with metals retained in soil poses a health risk. This particularly applies to industrialized cities with developed transport networks. The aim of the study was to determine the content and spatial distribution of mobile metal fractions in soils of the city of Łódź and to identify their load and sources. Multivariate statistical analysis (principal component analysis (PCA), cluster analysis (CA)), combined with GIS, were used to make a comprehensive evaluation of the soil contamination. Hot-spots and differences between urban and suburban areas were also investigated. Metals were determined by atomic absorption spectrometry (AAS) after soil extraction with 1 mol L−1 HCl. In most sites, the metal content changes in the following order: Zn > Pb > Cu > Ni > Cd. About one-third of the samples are considerably (or very highly) contaminated, (contamination factor, CF ...
Heavy metals in urban soils: a case study from the city of Palermo (Sicily), Italy
The Science of the Total …, 2002
Concentrations of V, Mn, Cd, Zn, Ni, Cr, Co, Cu, Pb, Hg and Sb were measured on 70 topsoil samples collected from green areas and parks in the city of Palermo (Sicily) in order to: (1) assess the distribution of these heavy metals in the urban environment; (2) discriminate natural and anthropic contributions; and (3) identify possible sources of pollution. Mineralogy, physico-chemical parameters, and major element contents of the topsoils were determined to highlight the influence of 'natural' features on the heavy metal concentrations and their distribution. Medians of Pb, Zn, Cu and Hg concentrations of the investigated urban soils are 202, 138, 63 and 0.68 mg kg , y1 respectively. These values are higher, in some case by different orders of size, than those of unpolluted soils in Sicily that average 44, 122, 34 and 0.07 mg kg . An ensemble of basic and multivariate statistical analyses (cluster y1 analysis and principal component analysis) was performed to reduce the multidimensional space of variables and samples, thus defining two sets of heavy metals as tracers of natural and anthropic influences. Results demonstrate that Pb, Zn, Cu, Sb and Hg can be inferred to be tracers of anthropic pollution, whereas Mn, Ni, Co, Cr, V and Cd were interpreted to be mainly inherited from parent materials. Maps of pollutant distribution were constructed for the whole urban area pointing to vehicle traffic as the main source of diffuse pollution and also showing the contribution of point sources of pollution to urban topsoils. ᮊ
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Science of the Total …, 2006
Urban soils differ from the rural ones by the fact that they are more strongly influenced by anthropogenic activities. This influence is often reflected by a high degree of contamination. To investigate the influence a large city can have on its soils and on the surrounding ones, samples within the city of Torino, Italy were compared with a set of surrounding soils developed from the same alluvial parent material. City-country trends were investigated by spatially managing the samples. Results show that the city plays a key role in concentrating some pollutants, such as Pb, Zn, and Cu within its borders. Lead is the element most enriched in the city, presenting a pollution index of 7.5 calculated comparing the two sets of samples. Ni and Cr appear to have a strong natural contribution. The spatial distributions for Pb, Cu and Zn present an abrupt division between urban and rural samples. Unexpectedly, the transport of pollutants from the city to the surrounding areas seems to be limited as no city-country trends with distance are identified. The pH and the sand fraction result also influenced by the city, showing high values. The investigation of possible city-country distance trends has shown to be effective in evaluating the impact a city can have on its soils and on the transport and deposition of contaminants on the surrounding ones. D
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Trace element concentrations in soils along urbanization gradients in the city of Wien, Austria
Environmental Science and Pollution Research, 2013
Urban soil is an important component of urban ecosystems. This study focuses on heavy metal contamination in soils of Wien (Austria) and results are compared to those for a few large European cities. We analysed the elemental contents of 96 samples of topsoil from urban, suburban and rural areas in Wien along a dynamic (floodplain forest) and a stable (oak-hornbeam forest) urbanization gradient. The following elements were quantified using ICP-OES technique: Al, As, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Pb, P, S and Zn. For heavy metals PI (pollution index) values were used to assess the level of pollution. The PI values indicated high level of pollution by Pb in the suburban and rural area of stable gradient and in the urban area of dynamic gradient; moderate level of pollution was indicated for Cd in the urban area of stable gradient. The level of pollution was moderate for Co in the suburban and rural area of the stable gradient, and for Cu in suburban area of stable gradient, and urban area of dynamic gradient. The pollution level of Zn was moderate in all areas. Urban soils, especially in urban parks and green areas may have a direct influence on human health. Thus, the elemental analysis of soil samples is one of the best ways to study the effects of urbanization. Our results indicated that the heavy metal contamination was higher in Wien than in a few large European cities.