Exploration of photocatalytic properties of microbially designed silver nanoparticles on Victoria blue B (original) (raw)

Rapid degradative effect of microbially synthesized silver nanoparticles on textile dye in presence of sunlight

Biocatalysis and Agricultural Biotechnology, 2018

In the study, the dye collected from industry was identified as methyl violet by LC-MS/MS analysis. The biosynthesized silver nanoparticles (AgNPs) used were characterized by UV-Visible spectrometry, HR-TEM and FT-IR analysis. Further, the AgNPs were used to evaluate the photocatalytic degradation of methyl violet. The results showed rapid degradation (85.56%) of methyl violet within a period of 20 minutes in presence of AgNPs. The superior photocatalytic activity of AgNPs observed in the study indicates its application for dye degradation.

Spectral Studies of UV and Solar Photocatalytic Degradation of AZO Dye and Textile Dye Effluents Using Green Synthesized Silver Nanoparticles

Bioinorganic Chemistry and Applications, 2016

The photocatalytic degradation of the chemical dye AZO and dye effluents in different time duration has been investigated using biologically synthesized silver nanoparticles. Dye industry effluents and AZO dye undergo degradation to form harmless intermediate and colourless products following irradiation by UV and solar light in the presence of green synthesized silver nanoparticles. The degree of degradation was tested under the experimental conditions such asPH, temperature, and absorbance of the dye in UV and solar light was measured. The degradation was higher in the UV light source than in the solar light source. Green synthesized silver nanoparticles in the UV light source were found to expedite the dye degradation process.

Sustainable and energy-efficient photocatalytic degradation of textile dye assisted by ecofriendly synthesized silver nanoparticles

Scientific Reports

In this study, we have touched on two goals of sustainable development, namely, the provision of clean water and sanitation and clean energy at acceptable prices, hoping for good health for all ages. A green economical method was used to prepare silver nanoparticles from chitosan biopolymer. AgNPs were fully characterized using UV–Vis, FTIR, XRD, HR-TEM, and EDX analysis. Different concentrations (0.02–0.18 g/L) of the nanoparticles were integrated into a mixture of heterogeneous nano photocatalysts TiO2 and ZnO (1:1 weight ratio) under UV irradiation for the photocatalytic degradation of Acid Red 37 textile dye to obtain clean water. The kinetic description of the performed photocatalytic process was presented assuming a pseudo-first-order reaction. The data revealed that increasing the concentration of AgNPs in the catalytic mixture showed a high apparent rate constant (kapp) accompanied by an increase in the apparent quantum yield (%Qapp), followed by dye destruction after a very...

Green synthesis of silver nanoparticles transformed synthetic textile dye into less toxic intermediate molecules through LC-MS analysis and treated the actual wastewater

Environmental Research, 2020

The illegal disposal of waste from textile industries having recalcitrant pollutants is a worldwide problem with more severity in developing nations. We used an ecofriendly method to synthesize silver nanoparticles (AgNPs) from a locally-isolated bacterial strain Bacillus marisflavi TEZ7 and employed them as photocatalysts to degrade not only synthetic azo dyes but also actual textile effluents followed by phytotoxicity evaluation and identification of degradation molecules. The strain TEZ7 was taxonomically identified through the 16S rRNA gene sequence analysis. Biogenic AgNPs were characterized for stabilizing molecules, crystal structure, size, shape and elemental composition by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) analysis, transmission electron microscopy (TEM), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS), respectively. The photocatalytic degradation efficiency of biogenic AgNPs for three azo dyes such as Direct Blue-1, Methyl Red, and Reactive Black-5 ranged between 54.14 and 96.92% after 5 h of sunlight exposure at a concentration of 100 mg/L. Moreover, the actual wastewater treatment analysis revealed that the 100 mg/L dose of AgNPs significantly decreased the concentration of various physico-chemical parameters of textile effluents such as pH, EC, chlorides, sulphates, hardness, BOD, COD, TSS and TDS. Furthermore, six intermediate molecules of methyl red degradation were identified by LC-MS and it was established by a pot study that these degradation molecules have no phytotoxic effects on rice plants. It was concluded that the AgNPs can be used as an efficient and low-cost strategy for the degradation of azo dyes containing textile wastewaters.

Silver nanoparticles for enhanced dye degradation

Current Research in Green and Sustainable Chemistry, 2021

Dye wastewater discharged after improper treatment is very harmful for environment and living creatures. As per mandate, the dye wastewater should be treated well in order to prevent any negative effects after discharge. Although there are various methods which are in use, however most of these methods have some or the other associated disadvantages i.e., high cost, generation of secondary pollutants, low efficiency, complexity etc. The objective of this study is to identify the dye degradation (orange and blue dye-individually/mixture) potential of chemically synthesized silver nanoparticles (CH-AgNPs) along with NaBH 4. Literature studies highlighted the efficacy of AgNPs for individual dye degradation, however it is very important to study the degradation potential of nanoparticles in presence of dye mixture (to mimic the natural wastewater condition). In the present study, the rapid synthesis of silver nanoparticles (CH-AgNPs) was obtained by using trisodium citrate solution. The developed CH-AgNPs were examined for UV-vis Spectrophotometry (maxima-422 nm), Zeta Potential (À6.70 mV), and Transmission Electron Microscopy (spherical shape with size range of 8-40 nm), highlighting the nano-size and stability of synthesized CH-AgNPs. For catalytic activity, CH-AgNPs and NaBH 4 were tested for dye degradation potential for Orange and Blue dyes individually and in mixture (orange þ blue dye). It was observed that with increase in dye concentration from 50 ppm to 200 ppm, NaBH 4 showed 28% and 25% removal for blue and orange dyes, respectively. However, when CH-AgNPs þ NaBH 4 was used, up to 100% degradation was obtained from blue dye, however the degradation of orange dye has shown 97.4% degradation. Further, as the wastewater contains multiple dyes, therefore in dye mixture studies (orange þ blue dye-50 ppm), 100% degradation was achieved with NaBH 4 þCH-AgNPs in just 5 min, highlighting the efficient catalytic ability of NaBH 4 þAgNPs. The results clearly highlighted the potential of CH-AgNPs in enhancing the dye degradation of orange and blue dyesindividually and in mixture, therefore the present study is relevant for further research to identify the best dye degradation agents, especially in presence of dyes mixture.

Microbial Synthesized Silver Nanoparticles for Decolorization and Biodegradation of Azo Dye Compound

Journal of Environmental Nanotechnology, 2015

Biological approach for silver nanoparticle synthesis using microorganisms like Bacteria, Fungi, algae and plants have received profound interest because of their potential to synthesize nanoparticles of various size, shape and morphology. The present research work focus on bacterial synthesis of silver nanoparticles their efficiency forbioremediation of Congo red dye. Twenty one types of different bacterial species have been isolatedfrom the different industrial waste effluent and bacterial consortium was prepared. Potential silver resistant bacteria were isolated from bacterial consortium using scale up method and identified as Bacillus pumillus by Gram staining, biochemical tests and genome sequencing method. After that Silver nanoparticles were synthesized using potential silver resistant bacteria. Silver nitrate and silver sulfate were used as precursor at different concentration for silver nanoparticle synthesis. Color change from colorless to brownwas observed synthesis of silver nanoparticles was further confirmed by UV Visible spectroscopy. The silver nanoparticles formation was (5-93 nm in size) also confirmed by Transmission electron microscopy, Particle size analyzer, Dynamic light scattering depending on the concentration of silver precursor.In this research, we have shown for the first time the use of Bacillus pumillis for synthesis of silver nanoparticles. Dye decolorization and biodegradation was studiedusing silver nanoparticles, silver resistant bacteria and silver resistant bacteria influced by silver nanoparticles separately. Nano based bioremediation was found 13 % efficient than the microbial remediation. Thus the developed nano-bioremediation technology is biocompatible, simple and reliable method and can be applied to decolorize dye as well as antimicrobial agent.

Biosynthesized silver nanoparticles as antimicrobial agents and photocatalytic degradation of methylene blue

DESALINATION AND WATER TREATMENT, 2019

In recent days there is a growing need for biosynthesized nanoparticles (NPs) as they are one of the most promising and novel therapeutic agents. Silver nanoparticles (BSNPs) were synthesized through bio-reduction of silver ions using Pongamia pinnata, Green tea extract and Spirulina platensis. The phytochemicals of marine algae that include hydroxyl, carboxyl, and amino functional groups can serve as effective metal reducing agents and as capping agents to provide a robust coating on the metal NPs. BSNPs were characterized using UV-visible spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM) and Fourier transform infra-red (FTIR). These nanoparticles indicated an absorption peak at 430 nm in the UV-visible spectrum. The antimicrobial activity of BSNPs has been tested by measuring the inhibition zone (minimum inhibitory concentration). Photocatalytic degradation of organic dyes using these nanoparticles has been also carried out and they prove to be highly suitable for environmental applications. The biosynthesis of BSNPs using green resources is a simple, environmentally friendly, pollutant-free and low-cost approach.

Degradation of Methylene Blue Using Biologically Synthesized Silver Nanoparticles

Nowadays plant mediated synthesis of nanoparticles has great interest and achievement due to its eco-benign and low time consuming properties. In this study silver nanoparticles were successfully synthesized by using Morinda tinctoria leaf extract under different pH. The aqueous leaf extract was added to silver nitrate solution; the color of the reaction medium was changed from pale yellow to brown and that indicates reduction of silver ions to silver nanoparticles. Thus synthesized silver nanoparticles were characterized by UV-Vis spectrophotometer. Dispersity and morphology was characterized by scanning electron microscope (SEM); crystalline nature and purity of synthesized silver nanoparticles were revealed by X-ray diffraction (XRD) and energy dispersive X-ray spectroscopy (EDX). FTIR spectrum was examined to identify the effective functional molecules responsible for the reduction and stabilization of silver nanoparticles synthesized by leaf extract. The photocatalytic activity of the synthesized silver nanoparticles was examined by degradation of methylene blue under sunlight irradiation. Green synthesized silver nanoparticles were effectively degrading the dye nearly 95% at 72 h of exposure time.

Photocatalytic degradation of Methylene Blue Using Citrate-stabilized Silver Nanoparticles

Philippine Science Letters, 2020

Annually, large volumes of synthetic textile dyes are released in effluent into natural streams causing damage to human health and environment. Conventional methods have been proven inefficient due to the stability of these dyes. An alternative emerging approach is the use of nanocatalysts in photocatalytic dye degradation. In this study, the ability of citrate-stabilized silver nanoparticles (cit-AgNP) to degrade methylene blue (MB) dye was investigated. Cit-AgNP was successfully synthesized using chemical reduction method and stabilized by sodium citrate. The resulting solution was yellow in color with absorbance peak at 393 nm. The particles were spherical in shape with average diameter of 9.19 ± 4.91 nm. In the degradation study, the photocatalytic degradation of MB is visually manifested by its reduction in color when exposed to light and the eventual reduction in absorbance at peak 663 nm. The percent degradation was quantified by calculating the amount of MB that remained in the solution and showed 94.45% after 10 minutes of exposure to light. Four different setups were also compared and analyzed based on color changes, absorbance curve profiles, and percent degradation to prove the catalytic activity of cit-AgNP and it was found out that the highest and fastest degradation was the setup with MB, NaBH4, and cit-AgNP. River water samples were also utilized to evaluate the effectivity of degradation in real water applications. It has showed no significant difference compared to the setup prepared with distilled water after statistical tests. Hence, this study showed the potential of cit-AgNP for dye degradation.