Electrochemical evaluation of synthesized s-triazine derivatives for improving 316L stainless steel for biomedical applications (original) (raw)
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Egyptian Journal of Petroleum, 2017
The inhibition behavior of three different triazine based Schiff's bases, HMMT, DHMMT and MHMMT for mild steel corrosion in sulphuric acid has been investigated using weight loss, electrochemical studies, SEM, spectroscopic studies and basic computational studies. The inhibition efficiency increased with increase in inhibitor concentration but decreased with rise in temperature and acid concentration in the case of these three inhibitors. The order of inhibition efficiency expected from the values of band energy is in good agreement with the results obtained from weight loss and electrochemical studies. Polarization studies indicated the mixed type behavior of these inhibitors. Field emission scanning electron microscopic studies revealed that inhibitors protect the metal surface by the forming a protective film through adsorption of inhibitor molecules.
ACS Omega
We observed our newly developed tetrahydro-1,2,4triazines, including triazene moieties (THTA), namely, 6-((1E)-1-((2E)-(4-(((Z)-1-(2,4-diphenyl-2,3,4,5-tetrahydro-1,2,4-triazin-5yl) ethylidene) triaz-1-en-1-yl)piperazin-1-yl) triaz-2-en-1-ylidene) ethyl)-2,4-diphenyl-2,3,4,5-tetrahydro-1,2,4-triazine (THTA-I), and 1-((E)-((E)-1-(2,4-diphenyl-2,3,4,5-tetrahydro-1,2,4-triazin-6yl) ethylidene) triaz-1-en-1-yl) naphthalen-2-ol (THTA-II), as effective inhibitors for the corrosion protection of N80 carbon steel metal in 5% sulfamic acid as the corrosive medium via electrochemical approaches such as potentiodynamic polarization and electrochemical impedance spectroscopy. Furthermore, the tested steel exterior was monitored using X-ray photoelectron spectroscopy after the treatment with the investigated components to verify the establishment of the adsorbed shielding film. The investigated compounds acted as mixed-type inhibitors, as shown by Tafel diagrams. The compounds considered obey the Langmuir adsorption isotherm, and their adsorption on the steel surface was chemisorption. When the tested inhibitors were added, the double-layer capacitances, which can be determined by the adsorption of the tested inhibitors on N80 steel specimens, decreased compared with that of the blank solution. At 10 −4 M, the inhibitory efficacy of THTA-I and THTA-II achieved maximum values of 88.5 and 86.5%, respectively. Density-functional theory computations and Monte-Carlo simulation were applied to determine the adsorption attributes and inhibition mechanism through the studied components. Furthermore, the investigated inhibitors were considered to adsorb on the Fe (1 1 0) surface. The adsorption energy was then measured on steel specimens.
Adsorption and corrosion inhibiting behavior of a new S-triazine derivative
Protection of Metals and Physical Chemistry of Surfaces, 2015
Abstarct-The inhibiting effect of 4, 6 bis (5 mercapto 1, 3, 4 thiadiazol amine) 2 phenylamino 1,3,5 tri azine BMTDT on the corrosion of mild steel in acidic media has been investigated by weight loss and elec trochemical methods. Results obtained reveal that this organic compound is a very good inhibitor. BMTDT is able to reduce the corrosion of steel more effectively in 1M HCl than in 1M H 2 SO 4 . The effect of polariza tion studies show that the adsorption of BMTDT follows physical adsorption in both acids without changing the mechanism of the hydrogen evolution reaction. Surface analyses were also carried out to establish the mechanism of corrosion inhibition of mild steel in acidic media. The adsorption of this inhibitor on the mild steel surface in obeys the Langmuir absorption isotherm in 1M HCl and Frumkin adsorption isotherm in 1M H 2 SO 4 . The corrosion behavior of mild steel with addition of different concentration of BMTDT was studied in the temperature range 308-333 K. The associated activation parameters and adsorption free energies have been determined and discussed.
Although stainless steel is a material widely used for biomedical applications, its surface properties for long term application are still a serious concern. 316L stainless steel (SS 316L) is a material commonly used in dentistry for orthodontic braces, wires and in some cases as dental crowns. The pH value of natural saliva from the oral cavity can undergo sudden modification due to food products which are rich in citric acid. The electrochemical corrosion behavior of 316L stainless steel was evaluated in two simulated body fluid solutions, Fusayama-Mayer artificial saliva with pH=5 and Fusayama-Mayer artificial saliva adjusted with citric acid to a pH=1.58 which simulates the environmental conditions of the oral cavity. The surface of SS316L was investigated by optical microscope before and after corrosion assays. The electrochemical corrosion behavior was studied by open circuit potential, potenitodynamic polarization and linear polarization. Optical microscopy was used to charac...
The inhibition effect of four amino acids on the corrosion of 316L stainless steel in 1.0 M H2SO4 has been studied by open-circuit potential and potentiodynamic polarization measurements. Corrosion data such as corrosion rate, corrosion potential (ECorr.) and corrosion current (ICorr.) were determined by extrapolation of the cathodic and anodic Tafel region. Glycine, Leucine and Valine inhibit the corrosion process, but Arginine accelerate the corrosion phenomenon. Glycine has the highest inhibition efficiency, its efficiency increases with increasing the concentration to attain 84.2% at 0.1M. Different behaviours were observed, in case of Arginine, corrosion rate increase by increasing concentration. These results show that the presence of Arginine at high concentration turns the surface of 316L stainless steel electrochemically active, probably dissolving the passivation layer and promoting the stainless steel anodic dissolution. Results obtained from potentiodymaic and open-circuit potential measurements are in good agreement
Fuel and Energy Abstracts, 2011
Electrochemical corrosion behavior and hydrogen evolution reaction of 316L stainless steel has been investigated, in 0.5 M sulfuric acid solution containing four novel organic inhibitors as derivatives from one family, using potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) measurements and surface examination via scanning electron microscope (SEM) technique. The effect of corrosion inhibitors on the hydrogen evolution reaction was related to the chemical composition, concentration and structure of the inhibitor. The inhibition efficiency, for active centers of the four used compounds, was found to increase in the order: eCl < eBr < eCH 3 < eOCH 3. The corrosion rate and hydrogen evolution using the compound with methoxy group as a novel compound was found to increase with either increasing temperature or decreasing its concentration as observed by polarization technique and confirmed by EIS measurements. The compound with methoxy group (newly synthesized) has very good inhibition efficiency (IE) in 0.5 M sulfuric acid (98.3% for 1.0 mM concentration). EIS results were confirmed by surface examination. Also, antibacterial activity of these organic inhibitors was studied. The results showed that the highest inhibition efficiency was observed for the compound that posses the highest antibacterial activity.
Molecules, 2016
Triazine derivatives, namely, 2,4,6-tris(quinolin-8-yloxy)-1,3,5-triazine (T3Q), N 2 ,N 4 ,N 6-tris(pyridin-2-ylmethyl)-1,3,5-triazine-2,4,6-triamine (T3AMPy) and 2,2 1 ,2 11-[(1,3,5-triazine-2,4,6-triyl)tris(azanediyl)] tris(ethan-1-ol) (T3EA) were synthesized and their inhibition of steel corrosion in hydrochloric acid solution was investigated using electrochemical techniques. The corrosion protection of the prepared compounds increased with increasing concentration and reached up to 98% at 250 ppm. The adsorption of T3Q, T3AMPy, and T3EA on the steel surface was in accordance with the Langmuir adsorption isotherm. The electrochemical results revealed that T3Q, T3AMPy and T3EA act as excellent organic inhibitors and can labeled as mixed type inhibitors. The efficiencies of the tested compounds were affected by the nature of the side chain present in the triazine ring, where T3EA gave the least inhibition while T3Q and T3AMPy gave higher and almost the same inhibition effects. The inhibition efficiencies obtained from the different electrochemical techniques were in good agreement.
Materials Today: Proceedings, 2022
Austenitic 316L stainless steel is one of the most common biomaterials used for orthopedic implants. As a highly corrosive environment, the device continuously contacts the blood. The corrosion effects on the screw plates must be known. The material most frequently used in osteosynthesis is currently 316L stainless steel. A simulated body fluid (S.B.F.) with electrochemical impedance spectroscopy (E.I.S.) and potentiodynamic (P.D.) polarization techniques has studied the corrosion behavior of stainless steel 316L. Corrosion characteristics were tested on 316L stainless steel surfaces resulted in corrosion rate are obtained highest for 270 min and lowest for 60 min immersion in S.B.F. Polarization experiments have been performed in a simulated body fluid following 60 min, 90 min, 180 min, and 270 min, there were relatively low densities, indicating a passive layer formation. The impedance spectrum in the Nyquist plot showed the development of the layer as a single constant system. It has been found today that current orthopedic implants tend to fail after long periods of use, as implants in the human body suffer from corrosion. This article gives a simple overview of the corrosion behavior for 316L stainless steel in orthopedic implant applications.
Purpose – The purpose of this paper is to describe the behavior of 2-mercaptobenzothiazole (MBT) on the corrosion of 316 stainless steel (SS) in acidic media and the mechanism of its action. Design/methodology/approach – The inhibitive effect of MBT towards the corrosion of 316 SS in acid solution is studied by means of weight loss, potentiodynamic polarization, and electrochemical impedance spectroscopy. The effect of inhibitor concentration and temperature against inhibitor action is investigated. Adsorption isotherm and adsorption mechanism are also discussed. Findings – MBT acts as inhibitor for this type of steel in acidic medium. This compound is mixed-type inhibitor and inhibition efficiency increased with increasing inhibitor concentration. MBT retards the rate of both anodic and cathodic corrosion reactions by adsorbing and forming a layer on the steel surface and the adsorption obeys Temkin adsorption isotherms. The inhibition efficiency is temperature dependence in the range from 25 to 658C and some thermodynamic parameters were calculated and analyzed. Originality/value – The results shown in this paper are an insight to the understanding of the corrosion resistance and electrochemical behavior of 316 SS in the presence of MBT for future industrial applications and development. It is the first time that corrosion inhibition effects of MBT on 316 SS have been evaluated.