Tunnel Magnetoresistance in Self-Assemblies of Exchange-Coupled Core/Shell Nanoparticles (original) (raw)

Magnetotransport in core-shell Fe–Fe oxide nanostructures

Journal of Magnetism and Magnetic Materials, 2003

Magnetic and magnetotransport measurements were performed on gas-phase synthesized Fe nanoparticles subjected to surface oxidation and cold consolidation. Two samples were investigated with a-Fe volume fraction of 0.15 and 0.60. The sample with smaller metallic fraction is below the percolation threshold for metallic conduction and the conduction mechanism is dominated by thermally activated processes across the oxide. In this case, by lowering the temperature, an increase of the negative magnetoresistance is observed up to 5% at 50 K in a magnetic field of 70 kOe. The magnetoresistance dependence on the sample magnetization, temperature and sample composition is discussed considering the magnetic correlations present in these nanostrucuterd systems. r

Controlled synthesis and enhanced tunnelling magnetoresistance in oriented Fe 3 O 4 nanorod assemblies

This paper focuses on the effect of shape anisotropy on the magnetic and tunnelling magnetoresistance (TMR) properties of oleylamine-coated magnetite (Fe 3 O 4 ) nanorod assemblies. Fe 3 O 4 nanorods with a wide variation in length (35-180 nm) and diameter (5.5-24 nm) are obtained by a facile two-step process where β-FeOOH nanorods are first prepared hydrothermally, followed by a transformation to the Fe 3 O 4 phase in an oleylamine medium via a solvo-thermal reaction. An observation of the Verwey transition at 120 K and analyses of Mössbauer spectra indicate that the as-synthesized Fe 3 O 4 nanorods are highly stoichiometric. In an assembly of nanorods, a surface-functionalizing oleylamine layer acts as the insulating dielectric layer to form multiple tunnel junctions between the semi-metallic nanorods, and intergrain tunnelling takes place. A 14% TMR is recorded in the nanorod assemblies at room temperature, which interestingly increases by a factor of 1.4 when the nanorods are pre-aligned under an external magnetic field. For aligned nanorods, the magnetic moments stay in parallel to each other and result in higher spin-polarized current. The observed TMR value increases with a decrease in temperature, and attains a maximum value of 31% at the Verwey transition temperature. Spin polarization of the nanorod assemblies is estimated to be 46% at room temperature.

Spatially Modulated Tunnel Magnetoresistance on the Nanoscale

Physical Review Letters, 2011

We investigate the local tunnel magnetoresistance (TMR) effect within a single Co nanoisland using spinpolarized scanning tunneling microscopy. We observe a clear spatial modulation of the TMR ratio with an amplitude of 2020% and a spacing of 201:3 nm between maxima and minima around the Fermi level. This result can be ascribed to a spatially modulated spin polarization within the Co island due to spin-dependent quantum interference. Our combined experimental and theoretical study reveals that spin-dependent electron confinement affects all transport properties such as differential conductance, conductance, and TMR. We demonstrate that the TMR within a nanostructured magnetic tunnel junction can be controlled on a length scale of 1 nm through spin-dependent quantum interference.

Asymmetric hysteresis and its dependence on magnetic anisotropy in exchange biased Co/CoO core-shell nanoparticles

Applied Physics Letters

Defect mediated reversible ferromagnetism in Co and Mn doped zinc oxide epitaxial films J. Appl. Phys. 112, 113917 (2012) Spacer-less, decoupled granular L10 FePt magnetic media using Ar-He sputtering gas J. Appl. Phys. 112, 113916 (2012) Magnetic moment manipulation by triplet Josephson current Appl. Phys. Lett. 101, 242602 An improved magnetic field detection unit based on length-magnetized Terfenol-D and width-polarized ternary 0.35Pb(In1/2Nb1/2)O3-0.35Pb(Mg1/3Nb2/3)O3-0.30PbTiO3 Appl. Phys. Lett. 101, 232906 (2012) Exchange bias effect in CoFe2O4-Cr2O3 nanocomposite embedded in SiO2 matrix

Correlation between tunneling magnetoresistance and magnetization in dipolar-coupled nanoparticle arrays

Physical Review B, 2005

The tunneling magnetoresistance (TMR) of a hexagonal array of dipolar coupled anisotropic magnetic nanoparticles is studied using a resistor network model and a realistic micromagnetic configuration obtained by Monte Carlo simulations. Analysis of the field-dependent TMR and the corresponding magnetization curve shows that dipolar interactions suppress the maximum TMR effect, increase or decrease the field-sensitivity depending on the direction of applied field and introduce strong dependence of the TMR on the direction of the applied magnetic field. For off-plane magnetic fields, maximum values in the TMR signal are associated with the critical field for irreversible rotation of the magnetization. This behavior is more pronounced in strongly interacting systems (magnetically soft), while for weakly interacting systems (magnetically hard) the maximum of TMR ( ) occurs below the coercive field ( ), in contrast to the situation for non-interacting nanoparticles (

Fabrication and Characterization of Hybrid Tunnel Magnetoresistance Structures with Embedded Self-Assembled Nanoparticle Templates

2009

We report on an incorporation of self-assembled templates of superparamagnetic Fe-O nanoparticles into tunnel magnetoresistance devices. We fabricated a multilayer stack composed of the following layer sequence: Cr/Au/Co/NP/Co/Cu on Si(100) substrate where NP stands for a self-assembled layer of nanoparticles deposited by the Langmuir-Blodgett technique. The X-ray reflectivity and grazing-incidence small angle X-ray scattering were employed to study the layers thicknesses and interface morphology in each preparation step. In particular, the grazing-incidence small angle X-ray scattering was measured before and after the nanoparticle incorporation as well as on the complete tunnel magnetoresistance stack. In this way, in-depth morphology profile during subsequent preparation steps was obtained. We demonstrate that X-ray analysis of the deposited tunnel magnetoresistance stack is essential for successful fabrication of novel hybrid devices consisting of self-assembled nanoparticles.

Structural and Magnetic Response in Bimetallic Core/Shell Magnetic Nanoparticles

Nanomaterials, 2016

Bimagnetic monodisperse CoFe 2 O 4 /Fe 3 O 4 core/shell nanoparticles have been prepared by solution evaporation route. To demonstrate preferential coating of iron oxide onto the surface of ferrite nanoparticles X-ray diffraction (XRD), High resolution transmission electron microscope (HR-TEM) and Raman spectroscopy have been performed. XRD analysis using Rietveld refinement technique confirms single phase nanoparticles with average seed size of about 18 nm and thickness of shell is 3 nm, which corroborates with transmission electron microscopy (TEM) analysis. Low temperature magnetic hysteresis loops showed interesting behavior. We have observed large coercivity 15.8 kOe at T = 5 K, whereas maximum saturation magnetization (125 emu/g) is attained at T = 100 K for CoFe 2 O 4 /Fe 3 O 4 core/shell nanoparticles. Saturation magnetization decreases due to structural distortions at the surface of shell below 100 K. Zero field cooled (ZFC) and Field cooled (FC) plots show that synthesized nanoparticles are ferromagnetic till room temperature and it has been noticed that core/shell sample possess high blocking temperature than Cobalt Ferrite. Results indicate that presence of iron oxide shell significantly increases magnetic parameters as compared to the simple cobalt ferrite.

Room-Temperature Tunnel Magnetoresistance in Self-Assembled Chemically Synthesized Metallic Iron Nanoparticles

Nano Letters, 2011

In this complementary section, we first present en enlarged view of cross section TEM picture of sample II (Fig.S1). 50 nm Figure S1. Enlarged view of cross section TEM of sample II. In fig.S2, we show TMR measurements of sample I performed on two devices different from the one presented in the main text. In Fig.S2.a, the variation of the resistance for the high-field regime, at T = 1.7 K, 5.1 K and 113.2 K are shown. To investigate a possible oxidation of the NPs, which could occur during the time of transferring the samples from the glove box to the cryostat (~ few minutes), we have performed magnetoresistance measurements after a fieldcooled (FC) under 3 T. The results are shown in S2.b. No shift of the maxima in the R(H) curves is noticeable.