Porous Supramolecular Architectures Based on π-Stacking Interactions between Discrete Metal-Adenine Entities and the Non-DNA Theobromine/Caffeine Nucleobases (original) (raw)

2018, Crystal Growth & Design

AI-generated Abstract

The study investigates the creation of porous supramolecular architectures formed by π-stacking interactions among discrete metal-adenine complexes and non-DNA nucleobases such as theobromine and caffeine. Through careful manipulation of non-covalent interactions, various compounds are synthesized, showcasing distinct structural characteristics and magnetic properties. Notably, one compound demonstrated permanent porosity, allowing for significant CO2 adsorption, hinting at potential applications for gas storage and separation.

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Porous Supramolecular Architectures Based on π-Stacking Interactions between Discrete Metal-Adenine Entities and the Non-DNA Theobromine/Caffeine Nucleobases (original) (raw)

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