Influence of Surface Chemistry on the Electrochemical Performance of Biomass-Derived Carbon Electrodes for its Use as Supercapacitors (original) (raw)
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Renewable and Sustainable Energy Reviews, 2015
An overview of the recent development in the production of activated carbon electrodes from agricultural waste biomass for application in supercapacitors is presented. The use of agricultural waste biomass as precursor for the production of activated carbons has been on the increase lately because it is cheap, readily available and also viewed as a veritable way of combating waste disposal problem in the agricultural industries. The effects of activating methods (physical, chemical and microwave-induced) and conditions on the properties of activated carbons are reviewed. The survey of articles published in the last decade indicates the viability of biomass active carbons being used as electrodes in supercapacitors. Under optimum process conditions, active carbons with specific capacitance as high as 374 F g À 1 and high-rate long-cycle stability at 4 A g À 1 have been produced. In this review, the influence of surface modification on activated carbon properties is also discussed. From the survey literature, it can be seen that the changes in surface chemistry and the introduction of specific surface functionalities on the surface of activated carbons impacted more on the electrochemical properties than the physiochemical properties of the activated carbons.
Wood-based activated carbons for supercapacitor electrodes with a sulfuric acid electrolyte
Carbon, 2017
The thermocatalytical synthesis conditions required for the activation of wood charcoal with NaOH in terms of the formation of pores in its structure were investigated. The present study was conducted to explore the potential application of activated carbons as electrodes in supercapacitors with organic electrolyte. The total pore volume and micro-and mesopore ratio were controlled by the activation temperature and alkali addition rate. The working characteristics of carbon electrodes (e.g., specific capacity and ohmic losses) in supercapacitors are strongly influenced by the properties of the pores in their structures. Herein, the optimal ratio of raw material to activator and activation temperature are established: an increase in the ratio of NaOH to carbonizate rate by a factor of 2 and setting the synthesis temperature at 700 ° C positively influence the electrochemical characteristics of supercapacitors and provide them with specific capacities of up to 160 F g-1 .
Wood-based activated carbons for supercapacitors with organic electrolyte
Holzforschung, 2015
The thermocatalytical synthesis conditions required for the activation of wood charcoal with NaOH in terms of the formation of pores in its structure were investigated. The present study was conducted to explore the potential application of activated carbons as electrodes in supercapacitors with organic electrolyte. The total pore volume and micro- and mesopore ratio were controlled by the activation temperature and alkali addition rate. The working characteristics of carbon electrodes (e.g., specific capacity and ohmic losses) in supercapacitors are strongly influenced by the properties of the pores in their structures. Herein, the optimal ratio of raw material to activator and activation temperature are established: an increase in the ratio of NaOH to carbonizate rate by a factor of 2 and setting the synthesis temperature at 700°C positively influence the electrochemical characteristics of supercapacitors and provide them with specific capacities of up to 160 F g-1.
Biomass- Derived Carbon Electrodes for Electrochemical Double- Layer Capacitors
Advances and Applications, 2014
Waste biomass from agricultural and food production processes can be used to prepare activated carbons with high surface area for energy storage in electrochemical double layer capacitors. The activation process and biomass carbon source can be selected to influence the pore structure and heteroatom content (for example, nitrogen and oxygen) of the activated carbon product. In this chapter, we review the effect of carbon pore structure and the effects of heteroatoms on the capacitance of carbon electrodes, and compare the electrochemical performance of activated carbons prepared from three biomass wastes: coffee waste, sawdust and sugar cane bagasse, popcorn and sucrose (as a refined carbon source). 5.1 CARBONS FOR ELECTROCHEMICAL DOUBLE LAYER CAPACITORS Electrochemical double layer capacitors (EDLCs), also known as supercapacitors, are a promising energy storage technology for applications where high power density and long-cycle life are required. These applications include auxiliary power supplies in fuel cell vehicles, systems to recover energy dissipated during a train braking, consumer electronics and memory backup systems, and energy
Binder-less activated carbon electrode from gelam wood for use in supercapacitors
Journal of Electrochemical Science and Engineering, 2013
This work focused on the relation between the porous structure of activated carbon and its capacitive properties. Three types of activated carbon monoliths were used as the electrodes in a half cell electrochemical system. One monolith was produced from activated carbon and considered to be a binder-less electrode. Two others were produced from acid and high pressure steam oxidized activated carbon. The micrographs clearly indicate that three electrodes have different porous structures. Both porosity and surface area of carbons increased due to the formation of grains during oxidation. This fact specified that an acid oxidized carbon monolith will have relatively higher capacitance compared to non-oxidized and steam oxidized monoliths. Maximum capacitance values for acid, steam oxidized and non-oxidized electrodes were 27.68, 2.23 and 1.20 F g-1 , respectively.
For supercapacitors with sulfuric acid electrolyte, a promising carbon material was suggested, namely, activated carbon from waste wood. It was shown how the synthesis conditions of activated carbon affect its porous structure and electrochemical characteristics of supercapacitors on its basis. The changes in the porous material under different synthesis conditions were controlled using the highly informative limited evaporation method, which allows us to obtain complete information about the porous structure of the micro-and mesopores of the material within a relatively short period of time. The negative effect of the excess volume of macropores in the electrode on the capacity and energy based on the dry mass of electrodes was shown experimentally and analyzed. The properties of the synthesized material were compared with those of other carbon materials. The best samples of the developed material possess a specific electric capacity of over 390 F/g.
Scientific Reports, 2019
With every moving day, the aspect that is going to be the most important for modern science and technology is the means to supply sufficient energy for all the scientific applications. As the resource of fossil fuel is draining out fast, an alternative is always required to satisfy the needs of the future world. Limited resources also force to innovate something that can utilize the resource more efficiently. This work is based on a simple synthesis route of biomass-derived hard carbon and to exploring the possibility of using it as electrochemical supercapacitors. A cheap, eco-friendly and easily synthesized carbon material is utilized as electrode for electrochemical energy-storage. Four diferent hard carbons were synthesized from KOH activated banana stem (KHC), phosphoric acid treated banana stem derived carbons (PHC), corn-cob derived hard carbon (CHC) and potato starch derived hard carbons (SHC) and tested as supercapacitor electrodes. KOH-activated hard carbon has provided 479.23F/g specific capacitance as calculated from its cycle voltammograms. A detailed analysis is done to correlate the results obtained with the material property. Overall, this work provides an in depth analysis of the science behind the components of an electrochemical energy-storage system as well as why the diferent characterization techniques are required to assess the quality and reliability of the material for electrochemical supercapacitor applications.
Nanomaterials
Activated carbons (ACs) have been the most widespread carbon materials used in supercapacitors (SCs) due to their easy processing methods, good electrical conductivity, and abundant porosity. For the manufacture of electrodes, the obtained activated carbon based on sawdust (karagash and pine) was mixed with conductive carbon and polyvinylidene fluoride as a binder, in ratios of 75% activated carbon, 10% conductive carbon black, and 15% polyvinylidene fluoride (PVDF) in an N-methyl pyrrolidinone solution, to form a slurry and applied to a titanium foil. The total mass of each electrode was limited to vary from 2.0 to 4.0 mg. After that, the electrodes fitted with the separator and electrolyte solution were symmetrically assembled into sandwich-type cell construction. The carbon’s electrochemical properties were evaluated using cyclic voltammetry (CV) and galvanostatic charge–discharge (CGD) studies in a two-electrode cell in 6M KOH. The CV and CGD measurements were realized at differ...
Modified Biomass Carbons for Electrochemical Capacitor Electrodes
2020
The demand for energy storage devices has led to the increased development of costeffective and sustainable electrode materials for electrochemical capacitors (ECs). This project investigated low-cost biomass waste pinecone to produce activated carbon (AC) and biochar in comparison with commercial coconut shell-based AC (YP-50F) as EC electrode materials. Pinecone-based AC produced via KOH chemical activation demonstrated a gravimetric capacitance of 214 F g-1 (at 50 mV s-1 in acidic media). Biochar (Flashed pinecone) synthesized without KOH showed a good capacitive performance at the same rate. Nitrogen doping was used to introduce pseudocapacitance in both ACs and led to an improvement in gravimetric capacitance at 50 mV s-1 for doped YP-50F (154 F g
Materials, 2020
The present work explores in detail the effect of alkaline-basic electrolytes on the capacitance performance of biomass-derived carbonaceous materials used as electrodes in symmetric supercapacitors. The proof-of-concept is demonstrated by two commercial carbon products (YP-50F and YP-80F, Kuraray Europe GmbH, Vantaa, Finland), obtained from coconuts. The capacitance performance of YP-50F and YP-80F was evaluated in three types of basic electrolytes: 6 M LiOH, 6 M NaOH and 6 M KOH. It was found that the capacitance performance of YP-50F improved in the following order: NaOH < LiOH < KOH; Meanwhile, for YP-80F, the order changes to LiOH < NaOH < KOH. After 1000 cycles, the cycling stability of both YP-50F and YP-80F increased in the order NaOH < LiOH < KOH. This order of performance improvement is determined by both the electrolyte conductivity and the interaction between the functional groups of carbonaceous materials and alkaline electrolytes. The reactivity of th...