Utilization of Silica Nanoparticles from Rice Husks for Improving the Mechanical Properties of Dental Materials: A Literature Review (original) (raw)
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Production and characterization of silica nanoparticles from rice husk
Advanced Materials Letters, 2018
The rice process generates a large amount of husk, which can become an environmental contaminant if it does not receive an adequate management. Because rice husk is a natural source of silica, in this work silica nanoparticles were obtained as an alternative use for this residue. The synthesis was carried out with the incineration, acid leaching process, and particle size reduction through high-energy mechanical ball milling. For its characterization, thermal, chemical, morphological, structural and superficial area analyses were performed with thermogravimetric analysis, X-ray fluorescence method, scanning electron microscopy, transmission electron microscopy, X-ray diffraction, and Nitrogen adsorption/desorption isotherm techniques. The results indicated that between 150-450°C the organic material of the rice husk was released, and above 550°C was obtained ash rich in silica. The silica purity was effectively increased to 98.48%, through acid leaching with acid nitric. The reduction of particle size by mechanical milling at 600 rpm for 3 h was achieved up to nanometer size. Most of the nanoparticles were spherical with a diameter between 14 and 28 nm. Silicon oxide was the principal structural phase of the nanoparticles corroborated by the broad peak corresponding to the (101) plane shown by XRD pattern. A substantial increase of two magnitude orders of the specific surface area of nanoparticles was reached in comparison with particles without milling. The nanosilica particles obtained from rice husk can be used for the production of high-performance silicon or they can be also used as supplementary cementitious materials.
Synthesis of silica nanoparticles from Vietnamese rice husk by sol–gel method
Nanoscale Research Letters, 2013
Silica powder at nanoscale was obtained by heat treatment of Vietnamese rice husk following the sol–gel method. The rice husk ash (RHA) is synthesized using rice husk which was thermally treated at optimal condition at 600°C for 4 h. The silica from RHA was extracted using sodium hydroxide solution to produce a sodium silicate solution and then precipitated by adding H2SO4 at pH = 4 in the mixture of water/butanol with cationic presence. In order to identify the optimal condition for producing the homogenous silica nanoparticles, the effects of surfactant surface coverage, aging temperature, and aging time were investigated. By analysis of X-ray diffraction, scanning electron microscopy, and transmission electron microscopy, the silica product obtained was amorphous and the uniformity of the nanosized sample was observed at an average size of 3 nm, and the BET result showed that the highest specific surface of the sample was about 340 m2/g. The results obtained in the mentioned meth...
2022
Background. Failure of dentures that are unable to withstand flexural forces is often a major problem in the use of metal-ceramic crowns. The use of rice husk nano-silica powder has been extensively researched in dentistry because of its ability to improve mechanical properties. This study aims to determine the effectiveness of nano-silica particles from rice husks on the flexural strength of the opaque layer on Co-Cr metal-ceramic crowns. Methods: The type of research is experimental laboratories in vitro with posttest only control group design. The research samples were rectangular Co-Cr metal and porcelain plated on top of the metal center totaling 25 samples which were divided into 5 treatment groups. Flexural strength measurement with three-point bending at UTM. Data were analyzed by independent T-test and one-way ANOVA. Results: flexural strength of Co-Cr metal ceramic crown with the addition of 0.25% rice husk silica; 0.5%; 0.75%.1% in the opaque layer is 70.431±4.168; 84.093±2.852; 100,672±4,182 and 115,092±3,821, respectively. Conclusion: There is an increase in the flexural strength of metal ceramic crowns with the addition of 0.25% silica; 0.5%; 0.75%,1% on opaque coating.
Padjadjaran Journal of Dentistry
ABSTRACTIntroduction: Rice husk silica has been studied as a filler in dental composite, however, the mechanical properties of the resulting composites are below the commercial due to the poor surface modification between silica and resin matrix. 3-methacryloxyprpyltrimethoxysilane (MPTS) is one of the coupling agents that are effective to modify the silica surface. The purpose of this study to analyze the effect of MPTS on the diametral tensile strength (DTS) of the self-made composite using rice husk silica. Methods: The research type of this study was an experimental research laboratory. The samples (26 samples) were divided into two groups, namely the test group (using MPTS-modified silica) and the control group (using non-modified silica). The samples were cylindrical in shape with a diameter of 6.0 ± 0.1 mm and a height of 3.0 ± 0.1 mm according to ANSI/ADAS No. 27, 1993 and ISO 4049, 1988. The Fourier Transform Infrared (FTIR), HORIBA, was used to characterize the MPTS graft...
Synthesis of silica nanoparticles from rice husk ash
Science and Technology Development Journal, 2018
Silica nanoparticles (SiO2 NPs) were synthesized from rice husk ash (RHA) by chemical treatment and calcination. The size of SiO2 NPs evaluated by transmission electron microscope (TEM) was of 20 - 50 nm and the size distribution of SiO2 NPs measured by dynamic laser scattering (DLS) was of Gaussian mode. The X-ray diffraction (XRD) pattern with only one peak at 2θ ~ 220 confirmed the amorphous phase of SiO2 NPs. The Fourier transform infrared (FTIR) and energydispersive X-ray (EDX) spectra were also used to evaluate the functional groups and the purity of SiO2 NPs. The SiO2 NPs powder with high purity could be suitably produced by calcination of acid treated RHA at 7000C for 2h. The obtained SiO2 NPs product can be potentially used for numerous purposes of application, especially as filler in paints.
The objective of this study is to investigate the effect of silica hybrid nanoparticles on the hardness of the dental nanocomposites. The silica hybrid nanoparticles were synthesized by sol-gel method. The powders were modified with 3-methacryloxy-propyltrimethoxy silane (γ-MPS) either by co-condensation method or one-pot method. The silanized silica were then mixed with a mixture of bisglycidyl methacrylate (BisGMA), triethylene glycol methacrylate (TEGDMA), camphorquinone (CQ) and dimethylaminoethyl methacrylate (DMAEMA) to form dental nanocomposites. The hardness of the nanocomposites were determined using vickers hardness. The results shown that hardness of the dental composites using silica hybrid nanoparticles synthesized via one-pot method was higher compared to the synthesized via co-condensation method. Transmission Electron Microscope (TEM), and Fourier Transform Infrared Spectroscopy (FTIR) were used for characterization.
Simple mixing and hot pressing methods were used to make nanocomposite of rice husk using PVAc as adhesive, silica nanoparticle as filler and Mg(OH) 2 particle . The compressive strength of the composite was examined. The optimum mass ratio composition of rice husk and PVAc was 13 : 2. A compressive strength of 63.95 MPa was obtained for the samples which were pressed at 75 MPa pressure, at 100 o C temperature and then held for 15 minutes in the hot pressing machine. The addition of silica nanoparticle increased the compressive strength to 74.65 MPa hence increasing the value by approximately 11%. The addition of Mg(OH) 2 particles then decreased the compressive strength to 61.23 MPa therefore decreasing the value about 13%. The compressive strength gained for the rice-husk/PVAc composite with nanosilica filler is stronger than the composite of Kumagai S making it feasible to be used in many applications, especially in furnishings.
European Journal of Dentistry
Objective Rice husk nanosilica has a porous, amorphous structure with a silica (SiO2) surface. Silica interacts with calcium ions to form hydroxyapatite and can induce the formation of reactive oxygen species (ROS), which harm microorganisms. This research determines the effect of rice husk nanosilica on the increase in dentin hydroxyapatite and its antimicrobial effects against Streptococcus mutans. Materials and Methods We divided 27 dental cavity samples into three groups (n = 9). Group 1: normal dentin, Group 2: demineralized dentin, Group 3: demineralized dentin treated with rice husk nanosilica. The samples were analyzed using X-ray diffraction (XRD) to evaluate the formation of dentin hydroxyapatite. To analyze the viability of S. mutans after exposure to 2% nanosilica rice husk, we conducted an antimicrobial MTT assay. Statistical Analysis The Kruskal–Wallis test evaluates the formation of dentin hydroxyapatite, and the t-test evaluates the viability of S. mutans. Results Th...
Journal of Engineering and Technological Sciences, 2021
Silica extracted from rice husk (silica nanoparticles, Si-NP RHA) has great potential for industrial use, particularly as filler in the rubber industry. However, silica is poorly dispersed in the matrix and needs to be modified by a silane linking agent (bis-(3-triethoxysilylpropyl) tetrasulfane (TESPT)) to improve its mixing properties. As a result, a large amount of used solvent containing silane TESPT is produced. This study aimed to evaluate the surface modification of silica nanoparticles from rice husk employing this used solvent and to characterize the particles’ physical properties. Silica nanoparticles were extracted from rice husk using a sol-gel method. FTIR spectography demonstrated that the TESPT on fresh solvent and the used solvent were successfully grafted onto the surface of Si-NP RHA. Si-NP RHA modified by Two Step Modification (TSM) employing used solvent had strong absorption peaks at wave numbers of 2927.94 cm-1 and 1446.61 cm-1, which are associated with vibrat...