Hierarchical Self-Assembly of Lactams into Supramolecular CO-Spiked “Sea Urchins” and Then into a Channeled Crystal (original) (raw)

Abstract

AI

This paper presents the hierarchical self-assembly process of lactams into supramolecular structures resembling sea urchins, followed by the formation of a novel channeled crystal. Detailed synthesis methods and theoretical computations using DFT B3LYP/SBKJC reveal energetic stabilization through hydrogen bonds and molecular interactions. Visualization techniques like 3D Molecular Electrostatic Potential (MEP) mapping are employed to assess structural characteristics, indicating minimal disorder within the crystal lattice and highlighting the unique properties of the synthesized compounds.

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References (254)

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2. C(1)-C(2)-Co(02)-C(3) -146(4)
3. Co(01)-C(2)-Co(02)-C(3)
4. Co(01)-C(2)-Co(02)-C(21) 60.0(19)
5. C(3)-C(2)-Co(02)-Co(01) -78.2(19)
6. C(1)-C(2)-Co(02)-Co(01) 136(3) C(17)-Co(01)-Co(02)-C(22) 12(3) C(19)-Co(01)-Co(02)-C(22) 142(2) C(18)-Co(01)-Co(02)-C(22) -112(2)
7. C(2)-Co(01)-Co(02)-C(22) -4(2) C(3)-Co(01)-Co(02)-C(22) 42(2) C(17)-Co(01)-Co(02)-C(20) 134(3) C(19)-Co(01)-Co(02)-C(20) -95.9(15)
8. C(18)-Co(01)-Co(02)-C(20) 9.7(15)
9. C(2)-Co(01)-Co(02)-C(20) 117.4(15)
10. C(3)-Co(01)-Co(02)-C(20) 163.3(16)
11. C(17)-Co(01)-Co(02)-C(3) -30(3) C(19)-Co(01)-Co(02)-C(3) 100.9(16)
12. C(18)-Co(01)-Co(02)-C(3) -153.6(16)
13. C(2)-Co(01)-Co(02)-C(3) -45.9(12)
14. C(17)-Co(01)-Co(02)-C(21) -124(3)
15. C(19)-Co(01)-Co(02)-C(21) 7.0(16)
16. C(18)-Co(01)-Co(02)-C(21) 112.5(16)
17. C(2)-Co(01)-Co(02)-C(21) -139.7(15)
18. C(3)-Co(01)-Co(02)-C(21) -93.9(16)
19. C(17)-Co(01)-Co(02)-C(2) 16(2) C(19)-Co(01)-Co(02)-C(2) 146.7(15)
20. C(18)-Co(01)-Co(02)-C(2) -107.7(15)
21. C(3)-Co(01)-Co(02)-C(2) 45.9(12)
22. O(24)-C(24)-Co(03)-C(25) -9(23) O(24)-C(24)-Co(03)-C(23) -110(23)
23. O(24)-C(24)-Co(03)-C(9) 129(22)
24. O(24)-C(24)-Co(03)-C(8) 146(23)
25. O(24)-C(24)-Co(03)-Co(04) 93(23) O(25)-C(25)-Co(03)-C(24) -6(19) O(25)-C(25)-Co(03)-C(23) 97(19) O(25)-C(25)-Co(03)-C(9) -163(18)
26. O(25)-C(25)-Co(03)-C(8) -149(18)
27. O(25)-C(25)-Co(03)-Co(04) -108(18)
28. O(23)-C(23)-Co(03)-C(24) -72(31)
29. O(23)-C(23)-Co(03)-C(25) 179(100)
30. O(23)-C(23)-Co(03)-C(9) 78(31) O(23)-C(23)-Co(03)-C(8) 38(31) O(23)-C(23)-Co(03)-Co(04)
31. C(10)-C(9)-Co(03)-C(24) -177(3)
32. Co(04)-C(9)-Co(03)-C(24) -46(3) C(8)-C(9)-Co(03)-C(25) 165(2) C(10)-C(9)-Co(03)-C(25) -37(4) Co(04)-C(9)-Co(03)-C(25)
33. C(10)-C(9)-Co(03)-C(23) 62(4) Co(04)-C(9)-Co(03)-C(23) -167.
34. Co(04)-C(9)-Co(03)-C(8) -71.1(17)
35. C(8)-C(9)-Co(03)-Co(04) 71.1(17)
36. C(10)-C(9)-Co(03)-Co(04) -131(4)
37. Co(04)-C(8)-Co(03)-C(24) -87.
38. Co(04)-C(8)-Co(03)-C(25)
39. Co(04)-C(8)-Co(03)-C(23) 168.5(12)
40. C(7)-C(8)-Co(03)-C(9) -162(3)
41. Co(04)-C(8)-Co(03)-C(9) 77.2(18)
42. C(9)-C(8)-Co(03)-Co(04) -77.2(18)
43. C(7)-C(8)-Co(03)-Co(04) 121(2) O(28)-C(28)-Co(04)-C(27) -33(47)
44. O(28)-C(28)-Co(04)-C(26) -150(46)
45. O(28)-C(28)-Co(04)-C(8) 104(46)
46. O(28)-C(28)-Co(04)-C(9) 67(47) O(28)-C(28)-Co(04)-Co(03) 101(46)
47. O(27)-C(27)-Co(04)-C(28) -43(51)
48. O(27)-C(27)-Co(04)-C(26) 63(51) O(27)-C(27)-Co(04)-C(8) -154(50)
49. O(27)-C(27)-Co(04)-C(9) -149(50)
50. O(27)-C(27)-Co(04)-Co(03) 162(50)
51. O(26)-C(26)-Co(04)-C(28) 87(17) O(26)-C(26)-Co(04)-C(27) -25(17)
52. O(26)-C(26)-Co(04)-C(8) -179(100)
53. O(26)-C(26)-Co(04)-C(9) -154(16)
54. O(26)-C(26)-Co(04)-Co(03) -126(16)
55. Co(03)-C(8)-Co(04)-C(28) -177.4(13)
56. Co(03)-C(8)-Co(04)-C(27) -61(2)
57. Co(03)-C(8)-Co(04)-C(26)
58. Co(03)-C(8)-Co(04)-C(9) -68.2(17)
59. C(9)-C(8)-Co(04)-Co(03) 68.2(17)
60. C(7)-C(8)-Co(04)-Co(03) -121(2)
61. C(10)-C(9)-Co(04)-C(28) -59(3) Co(03)-C(9)-Co(04)-C(28) 155.0(13)
62. C(8)-C(9)-Co(04)-C(27) -175(2)
63. C(10)-C(9)-Co(04)-C(27) 50(3) Co(03)-C(9)-Co(04)-C(27) -96.
64. C(10)-C(9)-Co(04)-C(26) -177(3)
65. Co(03)-C(9)-Co(04)-C(26) 37(2) C(10)-C(9)-Co(04)-C(8) -136(4)
66. Co(03)-C(9)-Co(04)-C(8) 78.5(18)
67. C(8)-C(9)-Co(04)-Co(03) -78.5(18)
68. C(10)-C(9)-Co(04)-Co(03) 146(3) C(24)-Co(03)-Co(04)-C(28) 110(2) C(25)-Co(03)-Co(04)-C(28) -141(2)
69. C(23)-Co(03)-Co(04)-C(28) -19(3) C(9)-Co(03)-Co(04)-C(28) -46(2) C(8)-Co(03)-Co(04)-C(28) 5(2) C(24)-Co(03)-Co(04)-C(27) -114.8(17)
70. C(25)-Co(03)-Co(04)-C(27) -4.9(17)
71. C(23)-Co(03)-Co(04)-C(27) 117(2) C(9)-Co(03)-Co(04)-C(27) 89.9(17)
72. C(8)-Co(03)-Co(04)-C(27) 140.2(16)
73. C(24)-Co(03)-Co(04)-C(26) -0.5(16)
74. C(25)-Co(03)-Co(04)-C(26) 109.4(16)
75. C(23)-Co(03)-Co(04)-C(26) -129(2)
76. C(9)-Co(03)-Co(04)-C(26) -155.8(16)
77. C(8)-Co(03)-Co(04)-C(26) -105.6(15)
78. C(24)-Co(03)-Co(04)-C(8) 105.1(16)
79. C(25)-Co(03)-Co(04)-C(8) -145.0(16)
80. C(23)-Co(03)-Co(04)-C(8) -23(2) C(9)-Co(03)-Co(04)-C(8) -50.2(12)
81. C(24)-Co(03)-Co(04)-C(9) 155.3(17)
82. C(25)-Co(03)-Co(04)-C(9) -94.8(17)
83. C(23)-Co(03)-Co(04)-C(9) 27(2) C(8)-Co(03)-Co(04)-C(9)
84. H(15A)-C(15)-H(15B)
85. H(15A)-C(15)-H(15C)
86. H(15B)-C(15)-H(15C)
87. H(12B) -2729 7176 3990 66
88. H(14B) -1006 6417 5028
89. H(14C) -388 7105 4577
90. H(15B) -1500 5354 2994
91. H(15C) -1388 5108 4050
92. H(17B) 1190 7503 2246 66
93. H(20B) 4396 7133 1938 66
94. H(22B) 4434 5774 -259 112
95. H(22C) 4470 5261 724
96. H(23B) 4098 8186 311
97. H(23C) 4167 7392 -443 112
98. H(1) 2110 8553 88
99. H(2) 879 6525 3583 88
100. H(3) -1856 8033 1448 88 ________________________________________________________________________________
101. C(17)-C(18)-C(19)-C(20) -12(6) Co(6)-C(18)-C(19)-C(20) 135(3) Co(5)-C(18)-C(19)-C(20) -143(3)
102. C(17)-C(18)-C(19)-Co(5) 131(4) Co(6)-C(18)-C(19)-Co(5) -82.0(5)
103. C(17)-C(18)-C(19)-Co(6) -147(4) Co(5)-C(18)-C(19)-Co(6) 82.0(5)
104. C(18)-C(19)-C(20)-C(21) -10(4) Co(5)-C(19)-C(20)-C(21) -139.4(16) Co(6)-C(19)-C(20)-C(21) 106(2) C(19)-C(20)-C(21)-C(23) 162.7(18)
105. C(19)-C(20)-C(21)-C(24) 4(2) C(19)-C(20)-C(21)-C(22) -103.
106. O(17)-C(26)-Co(1)-C(27) -139(7)
107. O(17)-C(26)-Co(1)-C(25)
108. O(17)-C(26)-Co(1)-Co(2) 116(7) O(18)-C(27)-Co(1)-C(26) 152(14)
109. O(18)-C(27)-Co(1)-C(25) 50(14) O(18)-C(27)-Co(1)-C(2) -65(14)
110. O(18)-C(27)-Co(1)-C(3) -62(14)
111. O(18)-C(27)-Co(1)-Co(2) -112(14)
112. O(16)-C(25)-Co(1)-C(26) 68(72) O(16)-C(25)-Co(1)-C(27) 176(100)
113. O(16)-C(25)-Co(1)-C(2) -45(72)
114. O(16)-C(25)-Co(1)-C(3) -89(72)
115. O(16)-C(25)-Co(1)-Co(2) -36(72)
116. O(20)-C(29)-Co(2)-C(30) -164(13)
117. O(20)-C(29)-Co(2)-C(28) 87(13) O(20)-C(29)-Co(2)-C(2) -66(13)
118. O(20)-C(29)-Co(2)-C(3) -22(13)
119. O(20)-C(29)-Co(2)-Co(1) -29(14)
120. O(21)-C(30)-Co(2)-C(29) -57(41)
121. O(21)-C(30)-Co(2)-C(28) 47(41) O(21)-C(30)-Co(2)-C(2) -164(40)
122. O(21)-C(30)-Co(2)-C(3) -171(40)
123. O(21)-C(30)-Co(2)-Co(1) 145(40)
124. O(19)-C(28)-Co(2)-C(29) -114(14)
125. O(19)-C(28)-Co(2)-C(30) 140(14)
126. O(19)-C(28)-Co(2)-Co(1)
127. C(26)-Co(1)-Co(2)-C(29) -167.2(16)
128. C(27)-Co(1)-Co(2)-C(29) 86.7(16)
129. C(25)-Co(1)-Co(2)-C(29) -61.
130. C(26)-Co(1)-Co(2)-C(30) -31.2(10)
131. C(27)-Co(1)-Co(2)-C(30) -137.3(9)
132. C(25)-Co(1)-Co(2)-C(30)
133. C(26)-Co(1)-Co(2)-C(28) 75.7(10)
134. C(27)-Co(1)-Co(2)-C(28) -30.4(9)
135. C(25)-Co(1)-Co(2)-C(28) -178.
136. O(13)-C(31)-Co(3)-C(32) -167(76)
137. O(13)-C(31)-Co(3)-C(33) 95(76) O(13)-C(31)-Co(3)-C(11) -6(77) O(13)-C(31)-Co(3)-C(10) -11(77)
138. O(13)-C(31)-Co(3)-Co(4) -57(76)
139. O(14)-C(32)-Co(3)-C(31) 75(6) O(14)-C(32)-Co(3)-C(33) 177(
140. O(14)-C(32)-Co(3)-C(11) -68(7) O(14)-C(32)-Co(3)-C(10) -88(6) O(14)-C(32)-Co(3)-Co(4) -32(6) O(15)-C(33)-Co(3)-C(31) -51(8) O(15)-C(33)-Co(3)-C(32) -161(8)
141. O(15)-C(33)-Co(3)-C(11) 49(8) O(15)-C(33)-Co(3)-C(10) 89(8) O(15)-C(33)-Co(3)-Co(4) 74(9) C(10)-C(11)-Co(3)-C(31) -175.1(13)
142. C(12)-C(11)-Co(3)-C(31) 48.6(17) Co(4)-C(11)-Co(3)-C(31) -97.3(8) C(10)-C(11)-Co(3)-C(32) -30(2) C(12)-C(11)-Co(3)-C(32) -166.6(16) Co(4)-C(11)-Co(3)-C(32) 47.5(18) C(10)-C(11)-Co(3)-C(33) 84.1(13)
143. C(12)-C(11)-Co(3)-C(33) -52.1(17) Co(4)-C(11)-Co(3)-C(33) 162.0(7)
144. C(12)-C(11)-Co(3)-C(10) -136(2) Co(4)-C(11)-Co(3)-C(10) 77.9(12) C(10)-C(11)-Co(3)-Co(4) -77.9(12)
145. C(12)-C(11)-Co(3)-Co(4) 145.9(18)
146. C(11)-C(10)-Co(3)-C(31)
147. Co(4)-C(10)-Co(3)-C(31) -61.8(13)
148. C(11)-C(10)-Co(3)-C(32) 163.3(13)
149. C(9)-C(10)-Co(3)-C(32) -38(2) Co(4)-C(10)-Co(3)-C(32) 94.3(9)
150. C(11)-C(10)-Co(3)-C(33) -100.6(13)
151. C(9)-C(10)-Co(3)-C(33) 58(2) Co(4)-C(10)-Co(3)-C(33) -169.6(7)
152. C(9)-C(10)-Co(3)-C(11) 158(3) Co(4)-C(10)-Co(3)-C(11) -68.9(11)
153. C(11)-C(10)-Co(3)-Co(4) 68.9(11)
154. C(9)-C(10)-Co(3)-Co(4) -133(2)
155. O(11)-C(35)-Co(4)-C(34) 18(18) O(11)-C(35)-Co(4)-C(36) -85(18)
156. O(11)-C(35)-Co(4)-C(11) 132(18)
157. O(11)-C(35)-Co(4)-C(10) 143(17)
158. O(11)-C(35)-Co(4)-Co(3) -178(100)
159. O(10)-C(34)-Co(4)-C(35) 142(7) O(10)-C(34)-Co(4)-C(36) -110(7)
160. O(10)-C(34)-Co(4)-C(11) 40(8) O(10)-C(34)-Co(4)-C(10) -1(8) O(10)-C(34)-Co(4)-Co(3) 3(9) O(12)-C(36)-Co(4)-C(35) 80(
161. O(12)-C(36)-Co(4)-C(34) -25(7) O(12)-C(36)-Co(4)-C(11) -161(6)
162. O(12)-C(36)-Co(4)-C(10) -133(7)
163. O(12)-C(36)-Co(4)-Co(3) 178(7) C(10)-C(11)-Co(4)-C(35) 167.8(11)
164. C(12)-C(11)-Co(4)-C(35) -39(2) Co(3)-C(11)-Co(4)-C(35) 94.1(8) C(10)-C(11)-Co(4)-C(34) -87.0(12)
165. C(12)-C(11)-Co(4)-C(34) 66(2) Co(3)-C(11)-Co(4)-C(34) -160.7(8) C(10)-C(11)-Co(4)-C(36) 46.0(15)
166. C(12)-C(11)-Co(4)-C(36) -160.7(17) Co(3)-C(11)-Co(4)-C(36) -27.7(13)
167. C(12)-C(11)-Co(4)-C(10) 153(2) Co(3)-C(11)-Co(4)-C(10) -73.7(10)
168. C(10)-C(11)-Co(4)-Co(3) 73.7(10)
169. C(12)-C(11)-Co(4)-Co(3) -133(2)
170. C(11)-C(10)-Co(4)-C(35) -17.1(15)
171. C(9)-C(10)-Co(4)-C(35) -161.6(15) Co(3)-C(10)-Co(4)-C(35) 54.8(11)
172. C(11)-C(10)-Co(4)-C(34) 106.1(11)
173. C(9)-C(10)-Co(4)-C(34) -38.4(16) Co(3)-C(10)-Co(4)-C(34) 178.1(7)
174. C(11)-C(10)-Co(4)-C(36) -149.5(11)
175. C(9)-C(10)-Co(4)-C(36) 66.1(16) Co(3)-C(10)-Co(4)-C(36) -77.5(8)
176. C(9)-C(10)-Co(4)-C(11) -144(2) Co(3)-C(10)-Co(4)-C(11) 72.0(10)
177. C(11)-C(10)-Co(4)-Co(3) -72.0(10)
178. C(9)-C(10)-Co(4)-Co(3) 143.5(17)
179. C(31)-Co(3)-Co(4)-C(35) -1.2(8)
180. C(32)-Co(3)-Co(4)-C(35) 111.6(8)
181. C(33)-Co(3)-Co(4)-C(35) -125.3(13)
182. C(11)-Co(3)-Co(4)-C(35) -92.5(8) C(10)-Co(3)-Co(4)-C(35) -144.1(8)
183. C(31)-Co(3)-Co(4)-C(34) 138.4(15)
184. C(32)-Co(3)-Co(4)-C(34) -108.7(16)
185. C(33)-Co(3)-Co(4)-C(34) 14.3(19)
186. C(11)-Co(3)-Co(4)-C(34) 47.2(16) C(10)-Co(3)-Co(4)-C(34) -4.5(15)
187. C(31)-Co(3)-Co(4)-C(36) -107.1(8)
188. C(32)-Co(3)-Co(4)-C(36)
189. C(33)-Co(3)-Co(4)-C(36) 128.7(13)
190. C(11)-Co(3)-Co(4)-C(36) 161.6(9) C(10)-Co(3)-Co(4)-C(36) 110.0(9)
191. C(31)-Co(3)-Co(4)-C(11) 91.3(8)
192. C(32)-Co(3)-Co(4)-C(11) -155.9(9)
193. C(33)-Co(3)-Co(4)-C(11) -32.9(13)
194. C(10)-Co(3)-Co(4)-C(11) -51.6(8)
195. C(31)-Co(3)-Co(4)-C(10) 142.9(8)
196. C(32)-Co(3)-Co(4)-C(10) -104.3(9)
197. C(33)-Co(3)-Co(4)-C(10) 18.8(13)
198. C(11)-Co(3)-Co(4)-C(10)
199. C(18)-C(19)-Co(5)-C(37) 164.0(11)
200. C(20)-C(19)-Co(5)-C(37) -44.6(17) Co(6)-C(19)-Co(5)-C(37) 91.4(7)
201. C(18)-C(19)-Co(5)-C(38) 28.3(17)
202. C(20)-C(19)-Co(5)-C(38) 179.7(15) Co(6)-C(19)-Co(5)-C(38) -44.3(13)
203. C(18)-C(19)-Co(5)-C(39) -92.3(12)
204. C(20)-C(19)-Co(5)-C(39) 59.1(17) Co(6)-C(19)-Co(5)-C(39) -164.9(7)
205. C(20)-C(19)-Co(5)-C(18) 151(2) Co(6)-C(19)-Co(5)-C(18) -72.6(10)
206. C(18)-C(19)-Co(5)-Co(6) 72.6(10)
207. C(20)-C(19)-Co(5)-Co(6) -136.1(18)
208. C(19)-C(18)-Co(5)-C(37) -23.2(16)
209. C(17)-C(18)-Co(5)-C(37) -173.1(15) Co(6)-C(18)-Co(5)-C(37) 52.2(12)
210. C(19)-C(18)-Co(5)-C(38) -161.7(11)
211. C(17)-C(18)-Co(5)-C(38) 48.4(16) Co(6)-C(18)-Co(5)-C(38) -86.3(7)
212. C(19)-C(18)-Co(5)-C(39) 95.8(12)
213. C(17)-C(18)-Co(5)-C(39) -54.1(16) Co(6)-C(18)-Co(5)-C(39) 171.2(7)
214. C(17)-C(18)-Co(5)-C(19) -150(2) Co(6)-C(18)-Co(5)-C(19) 75.4(10)
215. C(19)-C(18)-Co(5)-Co(6) -75.4(10)
216. C(17)-C(18)-Co(5)-Co(6)
217. C(19)-C(18)-Co(6)-C(42) 165.0(14)
218. C(17)-C(18)-Co(6)-C(42) -37(2) Co(5)-C(18)-Co(6)-C(42) 95.1(9)
219. C(19)-C(18)-Co(6)-C(41) 20(2) C(17)-C(18)-Co(6)-C(41) 178.1(18) Co(5)-C(18)-Co(6)-C(41) -49.6(15)
220. C(19)-C(18)-Co(6)-C(40) -100.8(14)
221. C(17)-C(18)-Co(6)-C(40) 57(2) Co(5)-C(18)-Co(6)-C(40) -170.7(7)
222. C(17)-C(18)-Co(6)-C(19) 158(3) Co(5)-C(18)-Co(6)-C(19) -69.9(12)
223. C(19)-C(18)-Co(6)-Co(5) 69.9(12)
224. C(17)-C(18)-Co(6)-Co(5) -132(2)
225. C(18)-C(19)-Co(6)-C(42) -24(2) C(20)-C(19)-Co(6)-C(42) -169.8(18) Co(5)-C(19)-Co(6)-C(42) 54.6(17)
226. C(18)-C(19)-Co(6)-C(41) -167.2(13)
227. C(20)-C(19)-Co(6)-C(41) 47(2) Co(5)-C(19)-Co(6)-C(41) -88.4(8)
228. C(18)-C(19)-Co(6)-C(40) 85.2(14)
229. C(20)-C(19)-Co(6)-C(40) -60(2) Co(5)-C(19)-Co(6)-C(40) 164.0(7)
230. C(20)-C(19)-Co(6)-C(18) -146(3) Co(5)-C(19)-Co(6)-C(18) 78.8(12)
231. C(18)-C(19)-Co(6)-Co(5) -78.8(12)
232. C(20)-C(19)-Co(6)-Co(5) 136(2) C(37)-Co(5)-Co(6)-C(42) 112.7(11)
233. C(38)-Co(5)-Co(6)-C(42) 3.8(11)
234. C(39)-Co(5)-Co(6)-C(42) -118.3(14)
235. C(19)-Co(5)-Co(6)-C(42) -149.6(10)
236. C(18)-Co(5)-Co(6)-C(42) -100.5(10)
237. C(37)-Co(5)-Co(6)-C(41) 4.9(10)
238. C(38)-Co(5)-Co(6)-C(41) -104.0(10)
239. C(39)-Co(5)-Co(6)-C(41) 133.9(14)
240. C(19)-Co(5)-Co(6)-C(41) 102.7(9)
241. C(18)-Co(5)-Co(6)-C(41) 151.7(9)
242. C(37)-Co(5)-Co(6)-C(40) -128.9(14)
243. C(38)-Co(5)-Co(6)-C(40) 122.2(14)
244. C(39)-Co(5)-Co(6)-C(40) 0.1(17)
245. C(19)-Co(5)-Co(6)-C(40) -31.2(13)
246. C(18)-Co(5)-Co(6)-C(40) 17.9(13)
247. C(37)-Co(5)-Co(6)-C(18) -146.8(10)
248. C(38)-Co(5)-Co(6)-C(18) 104.3(10)
249. C(39)-Co(5)-Co(6)-C(18) -17.8(13)
250. C(19)-Co(5)-Co(6)-C(18) -49.1(8)
251. C(37)-Co(5)-Co(6)-C(19) -97.7(10)
252. C(38)-Co(5)-Co(6)-C(19) 153.3(10)
253. C(39)-Co(5)-Co(6)-C(19) 31.2(14)
254. C(18)-Co(5)-Co(6)-C(19)