고속 전단 가공에서 페놀계와 인산계 산화방지제에 의한 PC/ABS 블렌드의 물성 변화 연구 (original) (raw)
Analysis of Peroxide Curing Agents in EVA Compounds and Vulcanizates
2020
Poly(ethylene-co-vinyl acetate) compounds and vulcanizates containing dicumyl peroxide (DCP) (HD) were prepared, and the curing agent and reaction products were analyzed using gas chromatography/mass spectrometry (GC/MS). Samples containing trially cyanurate (TAC) and DCP (HDT) were also prepared and analyzed. Some raw DCP were decomposed in the injector region of GC to produce acetophenone. DCP was detected in the HD compound but was not observed in the HD vulcanizate, and instead acetophenone and 2-phenyl-2-propanol were detected. Both DCP and TAC were observed in the HDT compound but not in the HDT vulcanizate, where acetophenone and 2-phenyl-2-propanol were detected. Thus, some of the DCP decomposed during the compounding process. The formation mechanism for acetophenone and 2-phenyl-2-propanol during the crosslinking reaction was identified, and differences in the crosslinking reactions of HD and HDT compounds were discussed.
저급 탄산리튬의 재결정화를 통한 고순도 탄산리튬 제조에 대한 연구
The Korea Association Of Crystal Growth, Inc., 2021
Lithium carbonate recovered from the waste solution generated during the lithium secondary battery manufacturing process contains heavy metals such as cobalt, nickel, and manganese. In this study, the recrystallization of lithium carbonate was performed to remove heavy metals contained in the powder and to increase the purity of lithium carbonate. First, the leaching efficiency of lithium carbonate according to pH in the aqueous hydrochloric acid solution was examined, and the effect on the recrystallization of lithium carbonate according to the equivalent and concentration of sodium carbonate was confirmed. As the equivalent and concentration of sodium carbonate increased, the recovery rate of lithium carbonate improved. And the SEM image showed that the crystal shape was changed depending on the reaction conditions with sodium carbonate. Finally, the high purity lithium carbonate of 99.9% or more was recovered by washing with water.
Journal of the Korean Ceramic Society, 2014
Air-cooled slag showed grindability approximately twice as good as that of water-cooled slag. While the studied water-cooled slag was composed of glass as constituent mineral, the air-cooled slag was mainly composed of melilite. It is assumed that the sulfur in air-cooled slag is mainly in the form of CaS, which is oxidized into CaS 2 O 3 when in contact with air. CaS 2 O 3 , then, is released mainly as S 2 O 3 2ion when in contact with water. However, the sulfur in water-cooled slag functioned as a constituent of the glass structure, so the S 2 O 3 2− ion was not released even when in contact with water. When no chemical admixture was added, the blended cement of aircooled slag showed higher fluidity and retention effect than those of the blended cement of the water-cooled slag. It seems that these discrepancies are caused by the initial hydration inhibition effect of cement by the S 2 O 3 2ion of air-cooled slag. When a superplasticizer is added, the air-cooled slag used more superplasticizer than did the blast furnace slag for the same flow because the air-cooled slag had higher specific surface area due to the presence of micro-pores. Meanwhile, the blended cement of the air-cooled slag showed a greater fluidity retention effect than that of the blended cement of the water-cooled slag. This may be a combined effect of the increased use of superplasticizer and the presence of released S 2 O 3 2ion; however, further, more detailed studies will need to be conducted.
Bi 1/2 (Na 0.8 K 0.2 ) 1/2 TiO 3 세라믹스의 유전 및 압전 특성에 대한 Bi(Mg 1/2 Sn 1/2 )O 3 변성 효과
Journal of the Korean Ceramic Society, 2012
The effect of Bi(Mg 1/2 Sn 1/2)O 3 (BMS) modification on the crystal structure, ferroelectric and piezoelectric properties of Bi 1/2 (Na 0.8 K 0.2) 1/2 TiO 3 (BNKT) ceramics has been investigated. The BMS-substitution induced a transition from a ferroelectric (FE) tetragonal to a nonpolar pseudocubic phase, leading to degradations in the remnant polarization, coercive field, and piezoelectric coefficient d 33. However, the electric-fieldinduced strain was significantly enhanced by the BMS substitution-induced phase transition and reached a highest value of S max /E max = 633 pm/V under an applied electric field of 6 kV/mm when the BMS content reached 6 mol%. The abnormal enhancement in strain was attributed to the field-induced transition of the pseudocubic symmetry to other asymmetrical structure, which was not clarified in this work.
고인성 섬유보강 무시멘트 복합체의 기초 배합 및 역학 실험
Journal of the Korea Concrete Institute, 2012
Cement has been traditionally used as a main binding material of high ductile fiber reinforced cementitious composites. The purpose of this paper is to investigate the feasibility of using alkali-activated slag and polyvinyl alcohol (PVA) fibers for manufacturing high ductile fiber reinforced cementless composites. Two mixture proportions with proper flowability and mortar viscosity for easy fiber mixing and uniform fiber dispersion were selected based on alkali activators. Then, the slump flow, compression, uniaxial tension and bending tests were performed on the mixes to evaluate the basic properties of the composites. The cementless composites showed an average slump flow of 465 mm and tensile strain capacity of approximately 2% of due to formation of multiple micro-cracks. Test results demonstrated a feasibility of manufacturing high ductile fiber reinforced composites without using cement.
Journal of the Society of Naval Architects of Korea, 2008
The design process becomes more difficult due to the increasing complexity of products. Thus, without any proper design experience, designer cannot handle his design problems systematically. Besides, the conventional optimal design method cannot be used effectively at the early design stage, since most design problems must be formulated in terms of objective and constraint functions based on the mathematical concepts of Operation Research. Thus, in this paper, new design concept based on FBS (Function-Behavior-Structure) design model is introduced to help the novice designer formulate the complex design problems systematically into a mathematical form. In this FBS model, function means the designer's new intents designer wants to create for, structure stand for a final product configuration and behaviour is a product's performance. FBS design model is thus rather totally different concept used for formulating design problem, compared with conventional optimal design method. To validate this new FBS model, 330K VLCC design case is performed, and we found, though it is one design example case, that this new design concept could be effectively used for future ship design problems since, during the formulating design problem, the only engineering terminology such as function, structure, and behaviour of design product is used based on the engineering concepts, instead of mathematical terminology such as objective and constraints.
Benzobicyclon 혼합제의 제형 및 처리시기가 제초활성 및 벼 생육에 미치는 영향
CNU Journal of Agricultural Science, 2013
This study was conducted to evaluate the efficacy of two different formulations and application timings of benzobicyclon+penoxsulam+pyrzaosulfuron-ethyl (BPP) in rice field. BPP granule (GR) and tablet (TB) controlled more than 90% of four weed species 10 and 15 days after sowing in direct seeding when compared with untreated control. BPP TB was highly effective to control herbicide resistant Scirpus juncoides and Monochoria vaginalis both 10 and 15 days after transplanting (DAT). BPP GR controlled 94.0 and 96.5% of S. juncoides and M. vaginalis, respectively 10 DAT, but its efficacy decreased to 88.5 and 49.8% respectively 15 DAT. When compared with untreated control, no visual injuries were detected at 255 and 510 g a.i./ha of BPP. The yield of rice increased in both BPP GR and TB in transplanting and direct seeding rice cultivation when compared with untreated control. Based on these data, early application (10 DAT) of BPP GR and TB can be applied to provide effective weed control, especially in the field infested with herbicide resistant weed species.
디젤엔진 배출가스 질소산화물 저감을 위한 Solid SCR용 Ammonium Carbonate 중간생성물인 재응고 물질의 분석 연구
Transactions of the Korean Society of Automotive Engineers, 2014
Urea solution as a reductant of SCR has been widely used to reduce NOx emissions from diesel engine. But it has lots of problems which are freezing at low temperature due to liquid state, deposition of solid formation in the exhaust, dosing device, and complex package such as mixers for uniform concentration of ammonia. In order to overcome these obstacle, ammonium carbonate which is one of solid ammonium materials to produce ammonia gas directly by sublimation process is considered. Simple reactor with visible widow was designed to predict equilibrium temperature and pressure of ammonium carbonate. To simulate real operation conditions under automobile environment, several cycles of heating and cooling condition were settled, two different re-solidification materials were extracted from the reactor and visible window. Analytical study is performed to characterize these unknown materials by XRD (X-Ray Diffraction), FT-IR(Fourier Transform Infrared Spectroscopy), and EA(Elemental Analyzer). From analytical results, re-solidification materials from heating and cooling cycles are very similar to original material of ammonium carbonate.
규제해제 대상 방사성 금속 폐기물 최종잔류방사능 측정법
Journal of Radiation Protection, 2013
It has been continuously generated the requirement for the replacement of the main components such as a steam generator due to the deterioration of the nuclear power plant all around the world. Also, a large amount of radioactive metal was generated during the decommissioning in a short period. It is required to make an accurate measurement of the residual radioactivity for recycling the metal waste for releasing from regulatory control. In planning the measurement procedures, the influence of geometry, self-absorption, density and other relevant factors on the representativeness of the measurements should be considered for the decommissioning metal waste. In this study, the method for measurement procedures, the source term evaluation, the ways to secure representative samples, the measurement device for wide area and the self-absorption correction factors for different density were evaluated. The metal samples for measurement were prepared for securing the simple geometry and representative by melting process. The developed correction method for measuring the radioactivity a variety density of metal waste could improve the reliability of the evaluation results for clearance.