Temperature, pressure and solvent isotope effects on the precursor formation constant and reorganization dynamics in outer-sphere charge transfer between free mobile [Fe(CN)6]3? and [Fe(CN)6]4? ions (original) (raw)

Journal of the Chemical Society, Faraday Transactions, 1995

Abstract

The kinetics of thermal self-exchange and cross reactions between cyanometallate ions have been studied by various techniques.'-8 The rate constants were observed to depend strongly on the nature and concentrations of cations present in solution. This catalytic activity of ...

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