Tailoring of Fe-ferrierite for N2O decomposition: On the decisive role of framework Al distribution for catalytic activity of Fe species in Fe-ferrierite (original) (raw)
Microporous and Mesoporous Materials, 2011
Abstract
Two parent ferrierites with similar Si/Al ratio (8.5 and 10.5), a commercial and a laboratory specimen with different distribution of Al atoms in the framework, were used for the preparation of model Fe-ferrierite catalysts for N2O decomposition. As proven by UV–Vis analysis of the fully exchanged Co(II)-ferrierites, the two ferrierites differ in the distribution of framework Al between Al–O–(Si–O)2–Al sequences
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