Debye model (original) (raw)
In thermodynamics and solid state physics, the Debye model is a method developed by Peter Debye in 1912 for estimating the phonon contribution to the specific heat (heat capacity) in a solid. It treats the vibrations of the atomic lattice (heat) as phonons in a box, in contrast to the Einstein model, which treats the solid as many individual, non-interacting quantum harmonic oscillators. The Debye model correctly predicts the low temperature dependence of the heat capacity, which is proportional to T 3 -the Debye T 3 law. Just like the Einstein model, it also recovers the Dulong-Petit law at high temperatures. But due to simplifying assumptions, its accuracy suffers at intermediate temperatures.
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