First observation of the M 2Σ+ → E2Σ+ (0—0) transition in NO (original) (raw)

Chemical Physics Letters, 1981

Abstract

ABSTRACT The emission spectrum of NO excited by electric discharge has been recorded with a high-resolution Fourier transform interferometer. Strong perturbations are observed in the spectrum of the transition M2Σ+→ E2Σ+ (0—0), due to mixing of the Rydberg state M2Σ+(v = 0) with valence states B2Π(v = 22, 23) and L2Π(v = 3). Accurate energies for the M2Σ+ rotational levels are given.

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