Atomic Weight of Copper | Commission on Isotopic Abundances and Atomic Weights (original) (raw)

Isotope Atomic mass (Da) Isotopic abundance (amount fraction)
63Cu 62.929 597(3) 0.6915(15)
65Cu 64.927 790(5) 0.3085(15)

In 1961, the Commission recommended _A_r(Cu) = 63.54 based on the recent chemical determinations. In 1967, the Commission recommended _A_r(Cu) = 63.546(1) based on the mass-spectrometric measurements. The recommended uncertainty was increased to 0.003 in 1969 to include natural variations of up to approx. 0.15 % in the isotopic abundances of copper isotopes, and given the annotation "r" to indicate that the precision was limited by natural variability.

In the compilation by the Commission, the lowest reported _δ_65Cu value in a naturally occurring sample is −7.65 ‰ (x(65Cu) = 0.3066 and _A_r(Cu) = 63.542) for a specimen of a Cu-chloride mineral (atacamite) from Chile. The highest reported _δ_65Cu is +9 ‰ (x(65Cu) = 0.3102 and _A_r(Cu) = 63.549) for a Cu-carbonate mineral (aurichalcite) from Arizona. Some of these values are outside the range of the stated atomic-weight uncertainty and may justify a re-evaluation by the Commission of the atomic-weight uncertainty or annotations

SOURCE Atomic weights of the elements: Review 2000 by John R de Laeter et al. Pure Appl. Chem. 2003 (75) 683-800
© IUPAC 2003

CIAAW

Copper
_A_r(Cu) = 63.546(3) since 1969

The name derives from the Latin cuprum for Cyprus, the island where the Romans first obtained copper. The symbol Cu also comes from the Latin cuprum. The element has been known since prehistoric times.

Isotopic reference materials of copper.