Acetamide (original) (raw)

A valid IMA mineral species

08346380017271920743792.jpg

08346380017271920743792.jpg

08346380017271920743792.jpg

About AcetamideHide

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Name:

Named for the chemical compound it represents: Acetic acid amide. Acetamide is the common short name (trivial name) of this compound.

Naturally occurring acetamide (acetic acid amide).

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:13:6

IMA Classification of AcetamideHide

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Type description reference:

Classification of AcetamideHide

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10.AA.20

10 : ORGANIC COMPOUNDS
A : Salts of organic acids
A : Formates, Acetates, etc.

50.4.7.1

50 : ORGANIC COMPOUNDS
4 : Miscellaneous

32.11

32 : Hydrocarbons, Resins and other Organic Compounds

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Ace IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of AcetamideHide

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Comment:

Grey if included with carbonaceous material

Optical Data of AcetamideHide

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RI values:

_n_ω = 1.495 _n_ε = 1.460

δ = 0.035

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Chemistry of AcetamideHide

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Crystallography of AcetamideHide

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Class (H-M):

3_m_ - Ditrigonal Pyramidal

Cell Parameters:

a = 11.44 Å, c = 13.5 Å

Unit Cell V:

1,530.09 ų (Calculated from Unit Cell)

Morphology:

Crystals are prismatic, to 5 mm, with prominent {1120}; as small stalactites and in granular aggregates.

Crystal StructureHide

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X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
5.7 Å (100)
3.98 Å (90)
3.83 Å (10)
3.54 Å (90)
3.32 Å (30)
2.86 Å (80)
2.17 Å (10)

Geological EnvironmentHide

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Geological Setting:

In burning waste coal heaps, formed between 50 degrees C and 150 degrees C. Also at At Shamokin, near Burnside, Northumberland Co., Pennsylvania, USA.

Type Occurrence of AcetamideHide

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Place of Conservation of Type Material:

Mining Museum, St. Petersburg Mining Institute, St. Petersberg, Russia;
A.E.Fersman Mineralogical Museum, Academy of Sciences, Moscow, Russia

Geological Setting of Type Material:

In waste piles of a coal shaft. A seasonal mineral, appearing only in periods of dry weather.

Synonyms of AcetamideHide

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Other Language Names for AcetamideHide

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Other InformationHide

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Notes:

Melting point: 81°C
Boiling point: 221°C (at 1.013 bar)
Acetamide is readily soluble in water (solubility: 2 g/ml at ambient temperature). Taste very bitter; volatilises on exposure to air and sunlight.
Decomposes to ammonium acetate in contact with acids or alkali.

Health Risks:

Acetamide is classified as a potentially carcinogenic substance. It also is a mild irritant.

Industrial Uses:

In the past, acetamide was used as a plasticiser and as a stabiliser. Molten acetamide was frequently used as a solvent in chemical synthesis. It also acts as a solubiliser; its mere addition renders many sparingly soluble compounds more soluble in water.

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References for AcetamideHide

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Reference List:

Windholz, M., Budavari, S., Blumetti, R.F., Otterbein, E.S., editors (1983) The Merck Index, 10th ed., Merck & Co., Inc., Rahway (NJ, USA).

Localities for AcetamideHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Poland
Silesian Voivodeship Wodzisław County Radlin Marcel mine heap ? Łukasz Kruszewski (2012) +1 other reference
Ukraine (TL)
Lviv Oblast L'viv-Volynskii Coal Basin (L'vov-Volynskii Coal Basin) Chervonograd Coal Mine (TL) [ZVMO 104 (1975) +3 other references
USA
Pennsylvania Northumberland County Shamokin Mineralogical Society of America - ...