Gaidonnayite (original) (raw)

A valid IMA mineral species

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About GaidonnayiteHide

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Formula:

Na2Zr(Si3O9) · 2H2O

Colour:

Colourless, may be pale yellow, pale brown to brown, pale grey, gray green.

Crystal System:

Orthorhombic

Name:

Named in honor of Gabrielle/Gaibrielle "Gai" Donnay (née Hamburger) (1920, Landeshut, Silesi, Germany (now Poland) - 4 April 1987, Mont St. Hilaire, Quebec, Canada), chemist, mineralogist and crystallographer. She worked for twenty years at the Geophysical Laboratory, Carnegie Institution of Washington and later at McGill University, Montreal, Canada. For her Ph.D. thesis she solved the complex structure of tourmaline, and later solved numerous other structures. The mineral donnayite-(Y) is also named for her, as well as her husband.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:1634:2

f75a0b2b-af98-479c-9041-6599c69f3f22

IMA Classification of GaidonnayiteHide

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IMA Formula:

Na2ZrSi3O9 · 2H2O

Classification of GaidonnayiteHide

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9.DM.15

9 : SILICATES (Germanates)
D : Inosilicates
M : Inosilicates with 6-periodic single chains

59.2.2.3

59 : CYCLOSILICATES Three-Membered Rings
2 : Three-Membered Rings, hydrated

14.10.7

14 : Silicates not Containing Aluminum
10 : Silicates of Zr or Hf

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Gdn IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of GaidonnayiteHide

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Colour:

Colourless, may be pale yellow, pale brown to brown, pale grey, gray green.

Fracture:

Irregular/Uneven

Density:

2.67 g/cm3 (Measured) 2.70 g/cm3 (Calculated)

Optical Data of GaidonnayiteHide

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RI values:

_n_α = 1.570 - 1.575 _n_β = 1.590 - 1.593 _n_γ = 1.596 - 1.605

δ = 0.026 - 0.030

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Optical Extinction:

Parallel. X = a; Y = b; Z = c.

Pleochroism:

Non-pleochroic

Chemistry of GaidonnayiteHide

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Mindat Formula:

Na2Zr(Si3O9) · 2H2O

Common Impurities:

Ti,Nb,Ca,K

Chemical AnalysisHide

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Empirical formulas:

Sample ID Empirical Formula
1 (Na1.52K0.40)Σ1.92(Zr0.92Ti0.07Nb0.02)Σ1.01Si3.00O9 · 2H2O

Sample references:

ID Locality Reference Notes
1 Brønnebukta, Siktesøya, Porsgrunn, Telemark, Norway Larsen, Alf Olav, Raade, Gunnar (1991) Gaidonnayite from nepheline syenite pegmatite on Siktesøya in the southern part of the Oslo Region, Norway. Norsk Geologisk Tidsskrift [Norwegian Journal of Geology], 71 (4) 303-306 Electron microprobe. H2O by stoichiometry. Empirical formula: Average of 18 electron microprobe analyses, based on 9 O atoms in the hydrous part

Crystallography of GaidonnayiteHide

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Crystal System:

Orthorhombic

Class (H-M):

m m m _(_2/_m_2/_m_2/m ) - Dipyramidal

Cell Parameters:

a = 11.740 Å, b = 12.820 Å, c = 6.691 Å

Ratio:

a:b:c = 0.916 : 1 : 0.522

Unit Cell V:

1,007.04 ų (Calculated from Unit Cell)

Morphology:

Equant to slightly elongated crystals with wedge-like forms. {010}, {120}, {011}, {100}, {001}. Striated || [001].

Comment:

Non-standard setting P21nb.

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0005201 Gaidonnayite Chao G Y (1985) The crystal structure of gaidonnayite Na2ZrSi3O9.2H2O The Canadian Mineralogist 23 11-15 1985 Mont St. Hilaire, Quebec, Canada 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
6.45 Å (40)
5.90 Å (80)
5.64 Å (60)
3.12 Å (100)
2.95 Å (70)
2.83 Å (40)
2.50 Å (40)
1.90 Å (40)

Geological EnvironmentHide

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Type Occurrence of GaidonnayiteHide

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General Appearance of Type Material:

Place of Conservation of Type Material:

Canadian Museum of Nature, Ottawa, Ontario, Canada, numbers T73/2-1, T73/2-2.
Royal Ontario Museum, Toronto, Ontario, Canada, number 34803.

Geological Setting of Type Material:

In miaroles in nepheline syenite and in sltered pegmatite dykes.

Associated Minerals at Type Locality:

Synonyms of GaidonnayiteHide

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Other Language Names for GaidonnayiteHide

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Relationship of Gaidonnayite to other SpeciesHide

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Other Members of this group:

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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Fluorescence of GaidonnayiteHide

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Bright green SW and LW (Mt. St-Hilaire and Norway)

Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for GaidonnayiteHide

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Localities for GaidonnayiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Australia
New South Wales Gordon Co. Toongi deposit Spandler et al. (2016) +1 other reference
Brazil
Minas Gerais Poços de Caldas Bortolan quarry Azzi (2019)
Prefeitura quarry Horváth
Poços de Caldas alkaline complex Atencio et al. (1999) +2 other references
Canada
Québec Abitibi-Témiscamingue Témiscamingue RCM Les Lacs-du-Témiscamingue Kipawa alkaline complex Roberts et al. (1983)
Montérégie La Vallée-du-Richelieu RCM Mont Saint-Hilaire Poudrette quarry (De-Mix quarry; Demix quarry; Uni-Mix quarry; Carrière Mont Saint-Hilaire; MSH) (TL) CHAO (1973) +4 other references
Lajemmerais RCM Varennes & St-Amable Saint-Amable sill Horváth et al. (1998)
Demix-Varennes quarry Horváth et al. (1998)
Montréal Montréal-Est Lafarge Montreal East quarry (Carrière Lafarge Montréal-Est; Francon Montréal-Est quarry; Canada Cement quarry) Canadian Museum of Nature collection
Greenland
Kujalleq Igaliku Narsaarsuk Plateau Narssârssuk pegmatite Gordon (1924) +1 other reference
India
West Bengal Purulia District Sushina Hill Chakrabarty et al. (2011) +1 other reference
Norway
Telemark Porsgrunn Siktesøya Brønnebukta Larsen et al. (1991)
Vestfold Larvik Malerød Midtfjellet Quarry Larsen et al. (2010) +1 other reference
Vardåsen Quarry Berge (1993) +1 other reference
Tjølling Håkestad Håkestad Quarry Larsen (2021)
Tvedalen Almenningen Quarry (Treschow-Fritzøe Quarry) Peter Andresen collection
Østskogen Quarry Collection of Peter Andresen. +1 other reference
Saga Pearl Quarry MAC depository of Unpublished Data et al. (Piilonen et al 2013)
Tuften A/S Granit Quarry Collected by Roy Kristiansen August ... +1 other reference
Portugal
Faro Monchique Monchique Palmeira No. 2 quarry Alves et al. (2010)
Russia
Murmansk Oblast Khibiny Massif Eveslogchorr Mt Pekov (1998)
Wadeite point Arzamastsev et al. (2008)
Kukisvumchorr Mt Pekov et al. (2004)
Kirovskii apatite mine Pekov (1998) +1 other reference
252 m level Hilairitovoye pegmatite Pekov (2003)
Rasvumchorr Mt
Lovozero Massif ...
Lovozersky District Alluaiv Mountain Pekov (2003)
Umbozero mine Shkatulka pegmatite Pavel M. Kartashov analytical data (2004)
USA
Arkansas Hot Spring County Magnet Cove Jones Mill Quarry (Martin Marietta Quarry; Highway 51 Quarry; Mid-State Quarry) Henry Barwood - unpublished (2010)
Pulaski County Little Rock Granite Mountain area Smith (1988) +1 other reference
Big Rock Quarry (3M Quarry; Arch Street Pike Quarry) Min News (2000)
California Kern County Boron Kramer Borate deposit Rio Tinto Borax Mine Rio Tinto Borax open pit MarekC (2018)
New Mexico Otero County Cornudas Mountains Wind Mountain W. Stoll - L. Horváth pers. comm. 2004 +1 other reference