Labuntsovite-Mn (original) (raw)

A valid IMA mineral species - grandfathered

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About Labuntsovite-MnHide

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Formula:

Na4K4(Ba,K)2Mn2+(Ti,Nb)8(Si4O12)4(O,OH)8 · 10-12H2O

Colour:

Brownish-yellow, bright orange, dark-red

Specific Gravity:

2.89 - 3.02

Crystal System:

Monoclinic

Name:

Originally named labuntsovite after the Russian mineralogists Aleksander Nikolaevich Labuntsov and Ekaterina Eutiikkieva Labuntsov-Kostyleva (for whom the mineral kostylevite is also named). Aleksander Labuntsov had earlier discovered the mineral and described it as titaniferous elpidite. The suffix/modifier was added in 2000.

This is the original labuntsovite. It is now designated labuntsovite-Mn for the dominance of manganese among the divalent cations.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:2309:8

a2f67a1b-c669-4cf1-822f-22298a93fc28

IMA Classification of Labuntsovite-MnHide

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Approved, 'Grandfathered' (first described prior to 1959)

IMA status notes:

Renamed by the IMA

IMA Formula:

Na4K4Mn2+2Ti8O4(Si4O12)4(OH)4 · 10-12H2O

Approval history:

IMA Case 00–A - Renamed (Grice and Ferraris, 2003).

Classification of Labuntsovite-MnHide

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9.CE.30e

9 : SILICATES (Germanates)
C : Cyclosilicates
E : [Si4O12]8- 4-membered single rings (vierer-Einfachringe), without insular complex anions

16.14.8

16 : Silicates Containing Aluminum and other Metals
14 : Aluminosilicates of Ti, Zr, Sn and Pb

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Lab-Mn IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of Labuntsovite-MnHide

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Transparency:

Transparent, Translucent

Colour:

Brownish-yellow, bright orange, dark-red

Cleavage:

Perfect
On (100).

Density:

2.89 - 3.02 g/cm3 (Measured)

Optical Data of Labuntsovite-MnHide

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RI values:

_n_α = 1.684 - 1.695 _n_β = 1.693 - 1.702 _n_γ = 1.792 - 1.814

2V:

Measured: 20° to 44°, Calculated: 30° to 36°

δ = 0.108 - 0.119

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Optical Extinction:

X = b; Y = c; Z = a.

Comments:

Z = brownish-yellow; X = yellowish.

Chemistry of Labuntsovite-MnHide

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Mindat Formula:

Na4K4(Ba,K)2Mn2+(Ti,Nb)8(Si4O12)4(O,OH)8 · 10-12H2O

Common Impurities:

Fe,Mn,Mg,Ca

Crystallography of Labuntsovite-MnHide

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Crystal System:

Monoclinic

Class (H-M):

2/m - Prismatic

Cell Parameters:

a = 14.18 Å, b = 13.70 Å, c = 7.74 Å
β = 117°

Ratio:

a:b:c = 1.035 : 1 : 0.565

Unit Cell V:

1,339.73 ų (Calculated from Unit Cell)

Morphology:

Prismatic crystals. Forms include c{001}, b{010}, m{110}, d{011}, and s{111}.

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0012358 Labuntsovite-Mn Rastsvetaeva R K, Chukanov N V, Pekov I V, Shlyukova Z V, Khomyakov A P (1998) Structures of two potassium-rich labuntsovites in relation to the crystal chemistry of minerals of the labuntsovite-nenadkevichite family Crystallography Reports 43 820-827 1998 0 293
0015562 Labuntsovite-Mn Golovastikov N I (1973) Crystal structure of the alkali titanosilicate labuntsovite Soviet Physics Crystallography 18 950-955 1973 0 293
0015563 Labuntsovite-Mn Golovastikov N I (1974) Crystal structure of the alkali titanosilicate labuntsovite Soviet Physics Crystallography 18 596-599 1974 0 293

CIF Raw Data - click here to close

Geological EnvironmentHide

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Type Occurrence of Labuntsovite-MnHide

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General Appearance of Type Material:

Columnar aggregates of brownish-yellow crystals. The crystals are prismatic to 12x3x2 mm.

Place of Conservation of Type Material:

Ecole Nationale Supérieure des Mines, Paris, France, (cotype).
National Museum of Natural History, Washington, D.C., USA, number 113995 (type).
Vernadsky State Geological Museum, Moscow, Russia, number 46311 (type).

Geological Setting of Type Material:

In voids in nepheline syenite.

Associated Minerals at Type Locality:

Synonyms of Labuntsovite-MnHide

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Other Language Names for Labuntsovite-MnHide

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Relationship of Labuntsovite-Mn to other SpeciesHide

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Other Members of this group:

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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9.CE. Dutkevichite-(Ce) NaZnBa2Ce2Ti2Si8O26F · H2O Orth. m _m_2 : A m _a_2
9.CE. Niobobaotite Ba4(Ti2.5Fe2+1.5)Nb4Si4O28Cl Tet. 4/m : _I_41/a
9.CE. Steiningerite Ba2Zr2(Si4O12)O2 Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _P_4/m b m
9.CE.05 Papagoite CaCu[H3AlSi2O9] Mon. 2/m : _B_2/m
9.CE.10 Verplanckite Ba4Mn2+2Si4O12(OH,H2O)3Cl3 Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m m m
9.CE.15 Baotite Ba4(Ti,Nb,W)8O16(SiO3)4Cl Tet. 4/m : _I_41/a
9.CE.20 Nagashimalite Ba4(V,Ti)4B2Si8O27(O,OH)2Cl Orth. m m m _(_2/_m_2/_m_2/m ) : P m m n
9.CE.20 Taramellite Ba4(Fe3+,Ti,Fe2+,Mg)4(B2Si8O27)O2Clx Orth. m m m _(_2/_m_2/_m_2/m ) : P m m n
9.CE.20 Titantaramellite Ba4(Ti,Fe3+,Fe2+,Mg)4(B2Si8O27)O2Clx Orth. m m m _(_2/_m_2/_m_2/m )
9.CE.25 Bario-orthojoaquinite (Ba,Sr)4Fe2Ti2[Si4O12]2O2 · H2O Orth.
9.CE.25 Byelorussite-(Ce) NaBa2Ce2MnTi2[Si4O12]2O2(F,OH) · H2O Orth. m _m_2 : A m _a_2
9.CE.25 Joaquinite-(Ce) NaBa2Ce2FeTi2[Si4O12]2O2(OH,F) · H2O Mon. 2 : _B_2
9.CE.25 Orthojoaquinite-(Ce) NaBa2Ce2FeTi2[Si4O12]2O2(O,OH) · H2O Orth.
9.CE.25 Strontiojoaquinite Sr2Ba2(Na,Fe)2Ti2[Si4O12]2O2(O,OH)2 · H2O Mon.
9.CE.25 Strontio-orthojoaquinite (Na,Fe)2Sr2Ba2Ti2[Si4O12]2O2(O,OH)2 · H2O Orth.
9.CE.25 Orthojoaquinite-(La) NaBa2La2Fe2+Ti2[Si4O12]2O2(O,OH) · H2O Orth. m m m _(_2/_m_2/_m_2/m )
9.CE.30a Unnamed (Ca-Na-ordered analogue of Korobitsynite) (Ca,Na)2(Ti,Nb)2(Si4O12)(OH,O)2 · 3-4H2O Orth. 222 : _P_21212
9.CE.30a Nenadkevichite (Na,◻)8Nb4(Si4O12)2(O,OH)4 · 8H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b a m
9.CE.30d Lemmleinite-K K2(Ti,Nb)2(Si4O12)(OH,O)2 · 4H2O Orth.
9.CE.30a Korobitsynite Na2(Ti,Nb)2(Si4O12)(OH,O)2 · 3-4H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b a m
9.CE.30c Kuzmenkoite-Mn K2Mn2+(Ti,Nb)4(Si4O12)2(OH,O)4 · 5-6H2O Mon. 2/m : _B_2/m
9.CE.30b Vuoriyarvite-K K2(Nb,Ti)2(Si4O12)(O,OH)2 · 4H2O Mon. m : B m
9.CE.30b Tsepinite-Na Na2(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2O Mon. m : B m
9.CE.30c Karupmøllerite-Ca (Na,Ca,K)2Ca(Nb,Ti)4(Si4O12)2(O,OH)4 · 7H2O Mon. 2/m : _B_2/m
9.CE.30e Labuntsovite-Mg Na4K4(Ba,K)2Mg(Ti,Nb)8(Si4O12)4(O,OH)8 · 10H2O Mon. 2/m : _B_2/m
9.CE.30e Labuntsovite-Fe Na4K4(Ba,K)2Fe2+(Ti,Nb)8(Si4O12)4(O,OH)8 · 10H2O Mon. 2/m : _B_2/m
9.CE.30d Lemmleinite-Ba Na2K2Ba(Ti,Nb)4(Si4O12)2(O,OH)4 · 5H2O Mon. 2/m : _B_2/m
9.CE.30c Gjerdingenite-Fe K2Fe2+(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2O Mon. 2/m : _B_2/m
9.CE.30h Neskevaaraite-Fe K3Na2Fe2+(Ti,Nb)4(Si4O12)2(O,OH)4 · 5-6 H2O Mon. m : B m
9.CE.30b Tsepinite-K K2(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2O Mon. m : B m
9.CE.30b Paratsepinite-Ba Ba4(Ti,Nb)8(Si4O12)4(OH,O)8 · 8H2O Mon. 2/m : _B_2/m
9.CE.30b Tsepinite-Ca Ca(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2O Mon. 2/m : _B_2/m
9.CE.30h Alsakharovite-Zn NaSrKZn(Ti,Nb)4(Si4O12)2(O,OH)4 · 7H2O Mon. m : B m
9.CE.30c Gjerdingenite-Mn K2Mn2+(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2O Mon. 2/m : _B_2/m
9.CE.30c Lepkhenelmite-Zn (Ba,K)2Zn(Ti,Nb)4(Si4O12)2(O,OH)4 · 7H2O Mon. m : B m
9.CE.30b Tsepinite-Sr Sr(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2O Mon. m : B m
9.CE.30b Paratsepinite-Na (Na,Sr,K,Ca)7(Ti,Nb)8(Si4O12)4(O,OH)8 · nH2O n ~ 8 Mon. 2/m : _B_2/m
9.CE.30f Paralabuntsovite-Mg Na8K8Mg4Ti16(Si4O12)8(OH,O)16 · 20-24H2O Mon. 2/m : _B_2/m
9.CE.30c Gjerdingenite-Ca K2Ca(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2O Mon. 2/m : _B_2/m
9.CE.30c Gjerdingenite-Na K2Na(Nb,Ti)4(Si4O12)2(OH,O)4 · 5H2O Mon. 2/m : _B_2/m
9.CE.30h Gutkovaite-Mn K2CaMn(Ti,Nb)4(Si4O12)2(O,OH)4 · 5H2O Mon. m : B m
9.CE.30c Kuzmenkoite-Zn K2Zn(Ti,Nb)4(Si4O12)2(OH,O)4 · 6-8H2O Mon. m : B m
9.CE.30g Organovaite-Mn K2Mn(Nb,Ti)4(Si4O12)2(O,OH)4 · 5-7H2O Mon. 2/m : _B_2/m
9.CE.30g Organovaite-Zn K2Zn(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2O Mon. 2/m : _B_2/m
9.CE.30g Parakuzmenkoite-Fe (K,Ba)4Fe(Ti,Nb)8(Si4O12)4(O,OH)8 · 14H2O Mon. 2/m : _B_2/m
9.CE.30c Burovaite-Ca (Na,K)4Ca2(Ti,Nb)8(Si4O12)4(OH,O)8 · 12H2O Mon. 2/m : _B_2/m
9.CE.45 Komarovite (Ca,Mn)(Nb,Ti)2[Si2O7](O,F)3 · 3.5H2O Orth. m m m _(_2/_m_2/_m_2/m ) : C m m m
9.CE.45 Natrokomarovite (Na,Ca,H)2Nb2Si2O10(OH,F)2 · H2O Orth.

Other InformationHide

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Thermal Behaviour:

Easily fusible before the blowpipe to a bluish enamel.

Notes:

Dissolves with difficulty in HCl, HNO3, or H2SO4.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for Labuntsovite-MnHide

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Localities for Labuntsovite-MnHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Canada
Québec Montérégie La Vallée-du-Richelieu RCM Mont Saint-Hilaire Poudrette quarry (De-Mix quarry; Demix quarry; Uni-Mix quarry; Carrière Mont Saint-Hilaire; MSH) Grice (1989) +2 other references
Lajemmerais RCM Varennes & St-Amable Saint-Amable sill Horváth et al. (1998)
Demix-Varennes quarry Horváth et al. (1998)
Namibia
Khomas Region Windhoek Rural Aris Aris Quarries Petersen +2 other references
Norway
Vestland Askvoll Dalsfjorden Heilefjellet dikes Furnes et al. (1982)
Russia
Aldan Shield Chara and Tokko Rivers Confluence Murunskii Massif [Lapis 1993:4 p.13-20]
Murmansk Oblast Khibiny Massif Khibinpakhkchorr Mountain Pekov et al (2005) +1 other reference
Koashva Mt Koashva Open Pit [World of Stones 95:5-6
Kukisvumchorr Mt Kirovskii apatite mine [World of Stones 95:5-6
252 m level Hilairitovoye pegmatite Pekov et al. (2006)
Vein no. 40 Yakovenchuk et al. (2005)
N'orkpakhk Mt Arzamastsev et al. (2008) +1 other reference
Rasvumchorr Mt
Yukspor Mt Mikhailova et al. (2007)
Vein no. 26 Yakovenchuk et al. (2005)
Vein no. 29 Yakovenchuk et al. (2005)
Yum'egor Pass (TL) Pekov (1998) +1 other reference
Kovdorsky District Kovdor Massif Kovdor Zheleznyi Mine [World of Stones 95:5-6
Lovozersky District Karnasurt Mountain Pekov et al. (1999) +1 other reference
Kuftnyun Mountain Pegmatite No. 19 (TL) Pekov (1998)
Selsurt Mountain [AmMin 85:1562] +1 other reference
Northern Karelia Vuoriyarvi alkaline-ultrabasic massif ...
Turii Cape Turii alkaline massif (Turiy massif)
USA
Arkansas Hot Spring County Magnet Cove Diamond Jo Quarry Smith (1989)