Osumilite (original) (raw)

A valid IMA mineral species - grandfathered

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About OsumiliteHide

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Formula:

K◻2Fe2+2Al3[Al2Si10O30]

some Na reported in the B site (dominated by ◻ in the end-member formula);
some Mg reported in the A site (dominated by Fe in the end-member formula)

Colour:

Black, dark blue, dark brown, pink, gray

Specific Gravity:

2.58 - 2.68

Name:

Named in 1953 by Akiho Miyashiro for the Osumi Peninsula, Japan, on which the type locality is found.

Osumilite Group.

Difficult to distinguish from Osumilite-(Mg).

Compare 'UM1984-35-SiO:AlCaFeKMg'.

From Belakovskiy (2013), summarizing Chukanov et al. (2013):
"Chemical data for osumilite in original paper (Miyashiro 1956) show that it is Mg‑dominant. However this analysis shows the sum of cations Si+Al+Fe+Mg+Mn (for O = 30) is 0.78 more then the theoretical value. The study of osumilite type locality material (Armbruster and Oberhänsli 1988; abstracted paper) show the significant Fe2+ prevalence over Mg. Anyway, the name osumilite had been assigned by IMA CNMNC Fe2+-dominant osumilite."

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:3039:3

134ee8fe-98fe-4468-a169-e88e227da07b

IMA Classification of OsumiliteHide

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Approved, 'Grandfathered' (first described prior to 1959)

IMA Formula:

KFe2(Al5Si10)O30

Type description reference:

Classification of OsumiliteHide

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9.CM.05

9 : SILICATES (Germanates)
C : Cyclosilicates
M : [Si6O18]12- 6-membered double rings (sechser-Doppelringe)

63.2.1a.6

63 : CYCLOSILICATES Condensed Rings
2 : Condensed Rings (Milarite - Osumilite group)

16.24.16

16 : Silicates Containing Aluminum and other Metals
24 : Aluminosilicates of Fe, Mg, Ca and alkalis

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

Symbol Source Reference
Osm IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
Osu Siivolam & Schmid (2007) Siivolam, J. and Schmid, R. (2007) Recommendations by the IUGS Subcommission on the Systematics of Metamorphic Rocks: List of mineral abbreviations. Web-version 01.02.07. IUGS Commission on the Systematics in Petrology. download
Osm Whitney & Evans (2010) Whitney, D.L. and Evans, B.W. (2010) Abbreviations for names of rock-forming minerals. American Mineralogist, 95, 185–187 doi:10.2138/am.2010.3371
Osm The Canadian Mineralogist (2019) The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download

Physical Properties of OsumiliteHide

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Transparency:

Transparent, Translucent

Colour:

Black, dark blue, dark brown, pink, gray

Comment:

Strongly pleochroic

Cleavage:

Poor/Indistinct
Indistinct, parallel and perpendicular {0001}

Density:

2.58 - 2.68 g/cm3 (Measured) 2.71 g/cm3 (Calculated)

Optical Data of OsumiliteHide

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RI values:

_n_ω = 1.539 - 1.547 _n_ε = 1.545 - 1.551

2V:

Measured: 28° to 45°, Calculated: 0.0° to 0.0°

δ = 0.006

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Optical Extinction:

Nominally uniaxial(+/-), but may be anomalously biaxial (+/-) with a 2V° from 0 (so true uniaxial) up to ~45°.

Comments:

O = light blue to bluish purple, pale pink, pale yellow-brown; E = colorless to brown.

Comments:

Anomalously biaxial.

Chemistry of OsumiliteHide

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Mindat Formula:

K◻2Fe2+2Al3[Al2Si10O30]

some Na reported in the B site (dominated by ◻ in the end-member formula);
some Mg reported in the A site (dominated by Fe in the end-member formula)

Common Impurities:

Ti,Mn,Ba,Na,Mg

Crystallography of OsumiliteHide

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Class (H-M):

6/m m m _(_6/_m_2/_m_2/m ) - Dihexagonal Dipyramidal

Cell Parameters:

a = 10.13(4) Å, c = 14.31(5) Å

Unit Cell V:

1,271.71 ų (Calculated from Unit Cell)

Morphology:

Hexagonal, tabular. Well developed {0001}, {1010}, {1120}. Also {2130}, {1011}, {1012}, {1122}.

Twinning:

Rarely, perpendicular to {0001}.

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0000078 Osumilite Miyashiro A (1956) Osumilite, a new silicate mineral, and its crystal structure American Mineralogist 41 104-116 1956 0 293
0000188 Osumilite Brown G E, Gibbs G V (1969) Refinement of the crystal structure of osumilite American Mineralogist 54 101-116 1969 0 293
0001149 Osumilite Armbruster T, Oberhansli R (1988) Crystal chemistry of double-ring silicates: Structural, chemical, and optical variation in osumilites American Mineralogist 73 585-594 1988 0 293
0001150 Osumilite Armbruster T, Oberhansli R (1988) Crystal chemistry of double-ring silicates: Structural, chemical, and optical variation in osumilites American Mineralogist 73 585-594 1988 0 293
0001151 Osumilite Armbruster T, Oberhansli R (1988) Crystal chemistry of double-ring silicates: Structural, chemical, and optical variation in osumilites American Mineralogist 73 585-594 1988 0 293
0001152 Osumilite Armbruster T, Oberhansli R (1988) Crystal chemistry of double-ring silicates: Structural, chemical, and optical variation in osumilites American Mineralogist 73 585-594 1988 0 293
0001153 Osumilite Armbruster T, Oberhansli R (1988) Crystal chemistry of double-ring silicates: Structural, chemical, and optical variation in osumilites American Mineralogist 73 585-594 1988 0 293
0001154 Osumilite Armbruster T, Oberhansli R (1988) Crystal chemistry of double-ring silicates: Structural, chemical, and optical variation in osumilites Japan-Hayasaki American Mineralogist 73 585-594 1988 0 293
0001155 Osumilite Armbruster T, Oberhansli R (1988) Crystal chemistry of double-ring silicates: Structural, chemical, and optical variation in osumilites American Mineralogist 73 585-594 1988 0 293
0001156 Osumilite Armbruster T, Oberhansli R (1988) Crystal chemistry of double-ring silicates: Structural, chemical, and optical variation in osumilites American Mineralogist 73 585-594 1988 0 293
0006584 Osumilite Winter W, Armbruster T, Lengauer C (1995) Crystal structure refinement of synthetic osumilite-type phases: BaMg2Al6Si9O30, SrMg2Al6Si9O30 and Mg2Al4Si11O30 European Journal of Mineralogy 7 277-286 1995 0 293
0006585 Osumilite Winter W, Armbruster T, Lengauer C (1995) Crystal structure refinement of synthetic osumilite-type phases: BaMg2Al6Si9O30, SrMg2Al6Si9O30 and Mg2Al4Si11O30 European Journal of Mineralogy 7 277-286 1995 0 293
0006586 Osumilite Winter W, Armbruster T, Lengauer C (1995) Crystal structure refinement of synthetic osumilite-type phases: BaMg2Al6Si9O30, SrMg2Al6Si9O30 and Mg2Al4Si11O30 European Journal of Mineralogy 7 277-286 1995 0 293
0007256 Osumilite Seryotkin Y V, Sokol E V, Bakakin V V, Likhacheva A Y (2008) Pyrometamorphic osumilite: occurrence, paragenesis, and crystal structure as compared to cordierite European Journal of Mineralogy 20 191-198 2008 South Urals, Russia 0 293
0007263 Osumilite Balassone G, Mormone A, Rossi M, Bernardi A, Fisch M, Armbruster T, Malsy K, Berger A (2008) Crystal chemical and structural characterization of an Mg-rich osumilite from Vesuvius volcano (Italy) European Journal of Mineralogy 20 713-720 2008 Vesuvius volcano, Italy 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
3.24 Å (very strong)
7.17 Å (strong)
5.08 Å (strong)
2.930 Å (strong)
4.41 Å (medium)
3.74 Å (medium)
2.776 Å (medium)

Comments:

Nearly identical to merrihueite.

Geological EnvironmentHide

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Type Occurrence of OsumiliteHide

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General Appearance of Type Material:

In crystals, a few millimeters or less in size, black to the unaided eye, and prismatic or tabular in habit. Previously mistaken for cordierite.

Place of Conservation of Type Material:

Harvard University, Cambridge, Massachusetts, USA, 104744.

Geological Setting of Type Material:

Biotite-bearing hypersthene-plagioliparite (rhyodacite).

Reference:

Miyashiro, A. (1953) Osumilite, a new mineral, and cordierite in volcanic rocks. Proceedings of the Japan Academy: 29(7): 321-323.

Synonyms of OsumiliteHide

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Other Language Names for OsumiliteHide

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Relationship of Osumilite to other SpeciesHide

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Other Members of this group:

Agakhanovite-(Y) K◻2(YCa)Be3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Almarudite K◻2Mn2+2(Be2Al)[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m m m
Aluminosugilite KNa2Al2Li3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Armenite Ba(H2O)2Ca2Al3[Al3Si9O30] Orth. m m m _(_2/_m_2/_m_2/m ) : P n n a
Berezanskite K◻2Ti2Li3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Brannockite K◻2Sn2Li3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Chayesite K◻2Mg2(Mg2Fe3+)[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Darapiosite KNa2Mn2(Zn2Li)[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Dusmatovite K(K◻)Mn2+2Zn3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Eifelite KNa2(MgNa)Mg3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Friedrichbeckeite K(◻Na)Mg2(Be2Mg)[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Klöchite K◻2(Fe2+Fe3+)Zn3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_63/m m c
Laurentthomasite K◻2Mg2(Be2Al)[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Merrihueite K(◻Na)Fe2+2Fe2+3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Milarite K(◻H2O)Ca2(Be2Al)[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Oftedalite K◻2(ScCa)Be3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Osumilite-(Mg) K◻2Mg2Al3[Al2Si10O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Poudretteite K◻2Na2B3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Roedderite K(◻Na)Mg2Mg3[Si12O30] Hex. 6_m_2 : P_62_c
Shibkovite K(◻K)Ca2Zn3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Sogdianite K◻2Zr2Li3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Sugilite KNa2Fe3+2Li3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Trattnerite ◻(◻)2Fe3+2Mg3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
UM1990-73-SiO:KMnNaZn K(KNa0.5◻0.5)(Mn1.5Na0.5)Zn3[Si12O30] Hex.
Unnamed (Mn3+-dominant analog of Sugilite) KNa2Mn3+2Li3[Si12O30]
Yagiite Na◻2Mg2Al3[Al2Si10O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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9.CM. Agakhanovite-(Y) K◻2(YCa)Be3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 Armenite Ba(H2O)2Ca2Al3[Al3Si9O30] Orth. m m m _(_2/_m_2/_m_2/m ) : P n n a
9.CM.05 Brannockite K◻2Sn2Li3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 Chayesite K◻2Mg2(Mg2Fe3+)[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 Darapiosite KNa2Mn2(Zn2Li)[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 Eifelite KNa2(MgNa)Mg3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 Merrihueite K(◻Na)Fe2+2Fe2+3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 Milarite K(◻H2O)Ca2(Be2Al)[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 Osumilite-(Mg) K◻2Mg2Al3[Al2Si10O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 Poudretteite K◻2Na2B3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 Roedderite K(◻Na)Mg2Mg3[Si12O30] Hex. 6_m_2 : P_62_c
9.CM.05 Sogdianite K◻2Zr2Li3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 Sugilite KNa2Fe3+2Li3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 Yagiite Na◻2Mg2Al3[Al2Si10O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 Berezanskite K◻2Ti2Li3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 Dusmatovite K(K◻)Mn2+2Zn3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 Shibkovite K(◻K)Ca2Zn3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 Almarudite K◻2Mn2+2(Be2Al)[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m m m
9.CM.05 Trattnerite ◻(◻)2Fe3+2Mg3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 Oftedalite K◻2(ScCa)Be3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 Klöchite K◻2(Fe2+Fe3+)Zn3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_63/m m c
9.CM.05 Friedrichbeckeite K(◻Na)Mg2(Be2Mg)[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 UM1990-73-SiO:KMnNaZn K(KNa0.5◻0.5)(Mn1.5Na0.5)Zn3[Si12O30] Hex.
9.CM.05 Laurentthomasite K◻2Mg2(Be2Al)[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.9.CM. Aluminosugilite KNa2Al2Li3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.10 Faizievite K2Na(Ca6Na)Ti4Li6[Si6O18]2[Si12O30]F2 Tric. 1 : _P_1

Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for OsumiliteHide

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Reference List:

Balassone, Giuseppina, Mormone, Angela, Rossi, Manuela, Bernardi, Alessandro, Fisch, Martin, Armbruster, Thomas, Malsy, Anna, Kathrin Berger, Alfons (2008) Crystal chemical and structural characterization of an Mg-rich osumilite from Vesuvius volcano (Italy) European Journal of Mineralogy, 20 (5) 713-720 doi:10.1127/0935-1221/2008/0020-1839

Chukanov, N. V., Pekov, I. V., Rastsvetaeva, R. K., Aksenov, S. M., Belakovskiy, D. I., Van, K. V., Schüller, W., Ternes, B. (2013) Osumilite-(Mg): Validation as a mineral species and new data. Geology of Ore Deposits, 55 (7) 587-593 doi:10.1134/s1075701513070064

Localities for OsumiliteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Antarctica
Eastern Antarctica Enderby Land Ellis et al. (1980) +1 other reference
Napier Complex Casey Bay Grew (1981) +1 other reference
Austria
Burgenland Oberpullendorf District Markt Sankt Martin Pauliberg Basalt quarry U. Kolitsch et al. (2009)
Georgia
Mtskheta-Mtianeti Kazbegi Municipality Kel’ volcanic area Cordieritovyi Volcano Станкевич Е.К. ...
Germany
Bavaria Upper Palatinate Tirschenreuth District Kulmain Zinster Kuppe Weiß (1990)
Hesse Giessen Region Vogelsbergkreis Mücke Ober-Ohmen Hainer Berg Betz (2019)
Rhineland-Palatinate Mayen-Koblenz Vordereifel Ettringen Caspar quarry Schreyer et al. (1983)
Saxony Mittelsachsen Waldheim Pfaffenberg peridotite Borghini et al. (2023) +1 other reference
Hungary
Szabolcs-Szatmár-Bereg County Tarpa Nagy Hill Koch (1985)
India
Andhra Pradesh Visakhapatnam District Diguva Sonaba Divya Prakash et al. (2015)
Italy
Campania Metropolitan City of Naples Ercolano Belvedere (Belvedere Vesuvio) Balassone G et al. (2004)
San Sebastiano al Vesuvio Balassone et al. (2013)
Sardinia Oristano Province Marrubiu Funtanafigu Quarry Olsen et al. (1970) +3 other references
Japan
Kagoshima Prefecture Kagoshima City Sakurajima Sakurajima volcano - (mistaken locality attribution occasionally seen on labels because osumilite's type locality is nearby, but not on Sakurajima)
Kirishima City Hayato Shimizu Kobayashi (1978)
Sakkabira (TL) Miyashiro (1953) +1 other reference
Tokyo Metropolis Ōshima Subprefecture Kozushima photo in: Koubutsu Doshikai (2017)
Yamaguchi Prefecture Yamaguchi City Yoshiki Nio meteorite Miura (2011)
Madagascar
Anosy Amboasary Sud District Behara Osumilite occurrence Holder et al. (2018)
Mahaly Osumilite occurrence 1 Holder et al. (2018)
Osumilite occurrence 2 Holder et al. (2018)
Tranomaro Osumilite occurrence Holder et al. (2018)
Taolagnaro District Mandromodromotra Osumilite occurrence 1 Holder et al. (2018)
Osumilite occurrence 2 Holder et al. (2018)
New Zealand
Waikato Region Taupo District Atiamuri Ongaroto Road Personal collection of Rod Martin
Norway
Rogaland Bjerkreim Vikeså Osumilite-bearing granulite Laurent (2016)
Russia
Chelyabinsk Oblast Chelyabinsk coal basin Cesnokov et al. (1998)
Sakha [World of Stones 12:49]
Tajikistan
Districts of Republican Subordination Dara-i-Pioz Massif Belakowski (1991)
USA
Nevada Pershing County Farrell Mining District Unnamed Locality Walstrom (n.d.)
Oregon Lane County McKenzie Pass North Sister Mountain Obsidian Cliffs Olsen et al. (1970) +1 other reference