Afwillite (original) (raw)

A valid IMA mineral species - grandfathered

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About AfwilliteHide

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Formula:

Ca3[SiO4][SiO2(OH)2] · 2H2O

Colour:

Colourless, white; rarely blue

Crystal System:

Monoclinic

Name:

Named in 1925 by John Parry and Frederick Eugene Wright in honor of Alpheus Fuller Williams [June 21, 1874 Oakland Alameda County California, USA - January 6, 1953 Cape Town, Western Cape, South Africa] of the De Beers Consolidated Mines of South Africa.

This page provides mineralogical data about Afwillite.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:42:6

2a5adcc3-a29a-4403-8101-7da960705a4a

IMA Classification of AfwilliteHide

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Approved, 'Grandfathered' (first described prior to 1959)

Type description reference:

Classification of AfwilliteHide

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9.AG.75

9 : SILICATES (Germanates)
A : Nesosilicates
G : Nesosilicates with additional anions; cations in > [6] +- [6] coordination

52.4.7.1

52 : NESOSILICATES Insular SiO4 Groups and O,OH,F,H2O
4 : Insular SiO4 Groups and O, OH, F, and H2O with cations in [6] and/or >[6] coordination

14.5.11

14 : Silicates not Containing Aluminum
5 : Silicates of Ca

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Afw IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of AfwilliteHide

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Colour:

Colourless, white; rarely blue

Cleavage:

Perfect
Perfect on {101}, good on {100}

Density:

2.630 g/cm3 (Measured) 2.643(5) g/cm3 (Calculated)

Optical Data of AfwilliteHide

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RI values:

_n_α = 1.617 _n_β = 1.620 _n_γ = 1.634

δ = 0.017

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Optical Extinction:

Y = b; X ∧ c = 31.2°.

Chemistry of AfwilliteHide

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Mindat Formula:

Ca3[SiO4][SiO2(OH)2] · 2H2O

Common Impurities:

Al,Fe,Mg,F

Crystallography of AfwilliteHide

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Crystal System:

Monoclinic

Cell Parameters:

a = 16.278(1) Å, b = 5.6321(4) Å, c = 13.236(1) Å
β = 134.9°

Ratio:

a:b:c = 2.89 : 1 : 2.35

Unit Cell V:

859.55 ų (Calculated from Unit Cell)

Morphology:

Crystals are prismatic, tabular, radial fibrous spherulites, massive.

Known forms include {001}, {100}, {110}, {310}, {011}, {045}, {013}, {101}, {101}, {302}, {112}, {121}, {211}, {213}, {312}.

Crystal StructureHide

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CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
2.83 Å (100)
6.61 Å (90)
3.18 Å (90)
2.73 Å (90)
3.28 Å (70)
2.15 Å (70)
2.34 Å (60)

Comments:

Dutoitspan mine, Kimberley, South Africa. Data from Switzer and Bailey (1953).

Geological EnvironmentHide

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Geological Setting:

Contact metamorphism of limestones.

Type Occurrence of AfwilliteHide

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General Appearance of Type Material:

Large crystals (11 x 4 x 1.5 cm) composed of sub-parallel individuals.

Place of Conservation of Type Material:

The Natural History Museum, London, England, number 1925,80 (cotype).
National Museum of Natural History, Washington, D.C., USA, number 95237 (type).

Geological Setting of Type Material:

In a large dolerite inclusion in kimberlite.

Associated Minerals at Type Locality:

Reference:

Parry, J., Wright, F.E. (1925) Afwillite, a new hydrous calcium silicate, from Dutoitspan mine, Kimberley, South Africa. Mineralogical Magazine: 20: 277-285.

Other Language Names for AfwilliteHide

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Common AssociatesHide

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Associated Minerals Based on Photo Data:

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Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for AfwilliteHide

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Localities for AfwilliteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Austria
Styria Südoststeiermark District Klöch Basalt quarry Walter Trattner collection
France
Auvergne-Rhône-Alpes Puy-de-Dôme Clermont-Ferrand Beaumont Boisséjour Grünhagen H and Mergoil J (1963)
Germany
Bavaria Lower Franconia Haßberge District Maroldsweisach Zeilberg Quarry Pöllmann (1991)
Rhineland-Palatinate Ahrweiler Brohltal Brenk Schellkopf Mineralogical Society of America - ...
Mayen-Koblenz Mayen Seekante Xenolith CS-020 Skrzyńska et al. (2023)
Mendig Bell Rothenberg Quarry Blass et al. (2005)
Vordereifel Ettringen Caspar quarry Hentschel (1987)
Xenolith CS-050 in the collection of Christof Schäfer
Kottenheim Hufnagel Hentschel (1983)
Vulkaneifel Daun Üdersdorf Emmelberg Schüller et al. (1986)
Gerolstein Hohenfels-Essingen Feuerberg Blass et al. (2006)
Ireland
Connacht Sligo County Killala Bay Inishcrone Nawaz (1974) +1 other reference
Israel
Southern District (HaDarom District) Tamar Regional Council Hatrurim Basin Galuskin et al. (2015)
Aravaite type locality Britvin et al. (2021) +1 other reference
Mazorite type locality Krzątała et al. (2023)
Nahal Morag Canyon Sharygin +7 other references
Tel Aviv District Ayalon River (Nahal Ayalon) GROSS et al. (1967)
Italy
Lazio Metropolitan City of Rome Capital Alban Hills Caponera et al. (2007)
Rome Valleranello Vallerano Quarries Fiori et al. (2002) +2 other references
Viterbo Province Montalto di Castro Pietra Massa Locality Campomorto Quarry Passaglia et al. (1982)
Umbria Perugia Province Spoleto Colle Fabbri Stoppa F. et al. (2010)
Veneto Vicenza Province Cornedo Vicentino Spagnago Grolla quarry 50 +2 other references
Japan
Hiroshima Prefecture Shoubara City Kushiro Uenotani Yamada (2004)
Okayama Prefecture Ibara City Higashi-Mihara Mihara mine Kusachi et al. (1989)
Takahashi City Bitchū Fuka Fuka mine Kusachi et al. (1989) +1 other reference
Jordan
Amman Governorate Transjordan Plateau Daba-Siwaqa complex Daba Pitty et al. (2010)
Hashem region Lisdan-Siwaga Fault Jordan Areva Resources Fleurance et al. (2013)
Siwaga Qatranaite locality Vapnik et al. (2019)
Irbid Governorate Maqarin area Yarmouk river Khoury et al. (1985)
Middle East
Hatrurim Formation Gross (1977)
New Zealand
Northland Region Kaipara District Tokatoka Golden Gully Railton et al. (1990)
Palestine
West Bank Jericho Governorate Nabi Musa Galuskina IO
Quds Governorate Jebel Harmun (Jabel Harum) Galuskin et al. (2015)
Ma'ale Adumim Krüger +5 other references
Romania
Brașov County Racoş (Racoşul de Jos) Szakáll
Basalt quarry Szakáll et al. (2010)
Caraş-Severin County Oraviţa Skarns Marincea et al. (2011)
Hunedoara County Cornet Hill Marincea et al. (2013)
Russia
Buryatia Severo-Baykalsky District Dovyren Highlands Yoko-Dovyrensky Massif American Mineralogist
Kabardino-Balkaria Chegemsky District Upper Chegem volcanic caldera (Verkhnechegemskaya caldera) Bailau +1 other reference
Lakargi Mountain Xenolith no. 1 Galuskina et al. (2015)
Xenolith no. 3 Galuskin et al. (2011)
Krasnoyarsk Krai Evenkiysky District Nizhnyaya Tunguska River Basin Anakit Creek
South Africa (TL)
Northern Cape Frances Baard District Municipality Sol Plaatje Local Municipality Kimberley KEM JV Mine (Kimberley Ekapa Mining Joint Venture mine; Kimberley Underground mine) Dutoitspan Mine (TL) Parry et al. (1925) +1 other reference
John Taolo Gaetsewe District Municipality Joe Morolong Local Municipality N'Chwaning Mines N'Chwaning I Mine Pohl et al. (1991)
N'Chwaning II Mine Cairncross et al. (1995)
Wessels Mine Cairncross et al. (1995)
UK
Northern Ireland Co. Antrim Larne Glenoe Carneal Nawaz (1977)
Scawt Hill Tilley (1930) +3 other references
USA
California Riverside County Jurupa Valley Crestmore Crestmore quarries Sky Blue Hill Commercial Quarry Switzer et al. (1953) +2 other references
Missouri Washington County Pea Ridge Mine Sherwood et al. (1998)