Balkanite (original) (raw)
A valid IMA mineral species
About BalkaniteHide
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alternatively (Cu9−xMe2+x)Ag5−xHgS8 (x = 0.3) (Biagioni & Bindi, 2017)
Crystal System:
Monoclinic
Name:
For the medieval and popular name of the Stara Planina (Balkan Mountains), the type locality.
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Balkanite's structure is not layered, but may be desribed by (1) alternation (along a) of Cu-rich and Ag-rich layers or (2) as the one based on two alternating atomic (010) layers: [Cu4Ag3HgS4]+ and [Cu5Ag2S4]−, or (3) alternation of two polyhedral layers: [Cu7Ag3S4]2+ and [Cu2Ag2HgS4]2−. Coordination of Hg is linear, Ag - tetrahedral or a distorted octahedral, and that of Cu - linear or planar triangular.
Unique IdentifiersHide
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Long-form identifier:
mindat:1:1:496:9
14879f3d-1a10-4fc6-bbd5-f8ce0f737b28
IMA Classification of BalkaniteHide
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Classification of BalkaniteHide
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2.BD.15
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
B : Metal Sulfides, M: S > 1: 1 (mainly 2: 1)
D : With Hg, Tl
2.16.7.1
2 : SULFIDES
16 : Miscellaneous
3.5.6
3 : Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)
5 : Sulphides etc. of Hg and Tl
Mineral SymbolsHide
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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Bkn | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of BalkaniteHide
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Hardness:
VHN100=79.4 - 91.6 kg/mm2 - Vickers
Density:
6.318 g/cm3 (Measured) 6.421 g/cm3 (Calculated)
Comment:
Measured on synthetic material
Optical Data of BalkaniteHide
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Reflectivity:
Wavelength | R1 | R2 |
---|---|---|
440nm | 35.4% | 30.6% |
460nm | 35.6% | 31.0% |
480nm | 35.4% | 31.0% |
500nm | 35.0% | 30.2% |
520nm | 34.0% | 28.9% |
540nm | 34.0% | 28.0% |
560nm | 33.4% | 27.2% |
580nm | 32.8% | 26.5% |
600nm | 32.4% | 26.0% |
620nm | 32.1% | 25.6% |
640nm | 31.8% | 25.1% |
660nm | 31.5% | 24.9% |
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 35.6%.
R1 shown in black, R2 shown in red
Colour in reflected light:
White-grey
Chemistry of BalkaniteHide
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Mindat Formula:
Cu9Ag5HgS8
alternatively (Cu9−xMe2+x)Ag5−xHgS8 (x = 0.3) (Biagioni & Bindi, 2017)
Crystallography of BalkaniteHide
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Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Cell Parameters:
a = 9.5539(11) Å, b = 3.9150(4) Å, c = 10.6424(12) Å
β = 90.047(9)°
Ratio:
a:b:c = 2.44 : 1 : 2.718
Morphology:
Rod-like prismatic crystals.
Twinning:
Lamellar in several directions
Comment:
Pseudo-orthorhombic. Originall assumed to be orthorhombic, with space group P222, Pmm2 or Pmmm.
X-Ray Powder DiffractionHide
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Powder Diffraction Data:
d-spacing | Intensity |
---|---|
3.09 Å | (7) |
2.98 Å | (10) |
2.61 Å | (8) |
2.55 Å | (10) |
2.45 Å | (8) |
1.985 Å | (8) |
1.955 Å | (9) |
Comments:
Sedmochislenitsi deposit, Bulgaria.
Geological EnvironmentHide
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Type Occurrence of BalkaniteHide
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Place of Conservation of Type Material:
Mineralogical Museum of the Higher Institute of Mining and Geology, 619; Museum of the University of Sofia “Kliment Ohridsky”, Sofia, 1351; National Museum of Natural History, Sofia, Bulgaria, 2339.
Geological Setting of Type Material:
High-grade copper ores in stratiform deposit.
Synonyms of BalkaniteHide
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Other Language Names for BalkaniteHide
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Common AssociatesHide
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Associated Minerals Based on Photo Data:
Related Minerals - Strunz-mindat GroupingHide
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Other InformationHide
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Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for BalkaniteHide
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References for BalkaniteHide
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Localities for BalkaniteHide
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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
Locality ListHide
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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
Australia | |
---|---|
New South Wales Yancowinna Co. Broken Hill district ⓘ Broken Hill | Analysed at Australian Museum |
Austria | |
Salzburg Zell am See District Leogang Hütten Schwarzleograben Schwarzleo mining district ⓘ Erasmus adit | Paar et al. (1985) +1 other reference |
Tyrol Kitzbühel District Oberndorf in Tirol ⓘ Röhrerbühel (Rohrer Berg; Röhrerbichel; Röhrerbichl; Röhrerbüchel; Rerobichl) | CD with abstracts +3 other references |
Belgium | |
Wallonia Luxembourg Vielsalm Salmchâteau ⓘ Copper-tellurium-mineralization ? | perso.infonie.be (2004) |
Bulgaria (TL) | |
Vratsa Province Balkan Mts (Stara Planina) ⓘ Sedmochislenitsi Mine (Sedmocislenici Mine) (TL) | ATANASSOVA +2 other references |
China | |
Guangxi Baise Leye Co. ⓘ Langquan Au deposit | Lin Niu (1994) |
Czech Republic | |
Central Bohemian Region Příbram District Háje ⓘ Uranium Mine No. 9 (Shaft No. 9) | SEJKORA et al. (2022) |
Italy | |
Sardinia South Sardinia Province Iglesias Bindua ⓘ San Giovanni Mine | Orlandi et al. (2005) |
Mexico | |
Sonora ⓘ Agua Prieta Municipality | Mineralogical Society of America - ... |
Naco Municipality Cerro Morita ⓘ Unnamed prospect | Mineralogical Society of America - ... |
Morocco | |
Drâa-Tafilalet Region Zagora Province Agdz Cercle Tansifte Caïdat Aït Ahmane ⓘ Vein No. 53 | D. Topa |
Poland | |
Lower Silesian Voivodeship Lwówek Śląski County Gmina Mirsk ⓘ Krowia Kopa Mt. | Kozłowski et al. (2022) |
Russia | |
Chelyabinsk Oblast ⓘ Miass River | Zaykov et al. (2017) |
Zabaykalsky Krai Kalarsky District Kodar–Udokan ore district Udokan ⓘ Unkur deposit | Novoselov et al. (2020) |
USA | |
Nevada Nye County Toquima Range ⓘ Manhattan Mining District | Castor et al. (2004) |