Destinezite (original) (raw)

A valid IMA mineral species - grandfathered

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About DestineziteHide

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Formula:

Fe3+2(PO4)(SO4)(OH) · 6H2O

Colour:

Yellow, brownish yellow, brown, reddish brown, greenish yellow, pale green, pale yellow; pale yellow to yellowish brown in transmitted light

Name:

Named by H. Forir and A. Jorissen in 1880 in honor of Mr. Pierre Destinez [died 7 April 1911 in Liège], a laboratory assistant at the University of Liège, Liège, Belgium. Destinez was a member of the Société Géologique de Belgique as early as 1886 and published a number of articles on paleontological subjects as late as 1904.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:5222:7

314de84b-d75c-48e9-a405-9a408704d4c9

IMA Classification of DestineziteHide

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Approved, 'Grandfathered' (first described prior to 1959)

IMA status notes:

Redefined by the IMA

Approval history:

Redefined (IMA Code 00-E).

Classification of DestineziteHide

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8.DB.05

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
B : With only medium-sized cations, (OH, etc.):RO4< 1:1

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Dtz IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of DestineziteHide

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Colour:

Yellow, brownish yellow, brown, reddish brown, greenish yellow, pale green, pale yellow; pale yellow to yellowish brown in transmitted light

Density:

2.2 g/cm3 (Measured) 2.33 g/cm3 (Calculated)

Optical Data of DestineziteHide

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RI values:

_n_α = 1.615 _n_β = 1.625 _n_γ = 1.665

2V:

Measured: 55° , Calculated: 56°

δ = 0.050

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Chemistry of DestineziteHide

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Mindat Formula:

Fe3+2(PO4)(SO4)(OH) · 6H2O

Crystallography of DestineziteHide

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Class (H-M):

1 - Pinacoidal

Cell Parameters:

a = 9.584 Å, b = 9.748 Å, c = 7.338 Å
α = 93.07°, β = 95.78°, γ = 105.32°

Ratio:

a:b:c = 0.983 : 1 : 0.753

Unit Cell V:

655.53 ų (Calculated from Unit Cell)

Morphology:

Rarely microcrystalline comprised of six-sided platy crystals.

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0012239 Destinezite Peacor D R, Rouse R C, Coskren T D, Essene E J (1999) Destinezite ("diadochite"), Fe2(PO4)(SO4)(OH)*6(H2O): its crystal structure and role as a soil mineral at Alum Cave Bluff,Tennessee Clays and Clay Minerals 47 1-11 1999 Alum Cave Bluff, Tennessee, USA 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
8.77 Å (90)
8.27 Å (80)
4.28 Å (100)
4.08 Å (70)
3.93 Å (100)
3.21 Å (40)
2.94 Å (80)

Geological EnvironmentHide

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Type Occurrence of DestineziteHide

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Place of Conservation of Type Material:

No designated type material.

Other Language Names for DestineziteHide

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Relationship of Destinezite to other SpeciesHide

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Other Members of this group:

Sanjuanite Al2(PO4)(SO4)(OH) · 9H2O Tric.
Sarmientite Fe3+2(AsO4)(SO4)(OH) · 5H2O Mon. 2/m : _P_21/b
Zýkaite Fe3+4(AsO4)3(SO4)(OH) · 15H2O Orth. 222 : _P_222

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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8.DB. Arangasite Al2F(PO4)(SO4) · 9H2O Mon. 2/m : _P_2/b
8.DB. Camaronesite [Fe3+(H2O)2(PO3OH)]2(SO4) · 1-2H2O Trig. 32 : _R_32
8.DB. Höslite Fe3+3(VO4)2(SO4)(OH)(H2O)4 · 3H2O Mon. 2/m : _P_21/b
8.DB.05 Diadochite Fe3+2(PO4)(SO4)(OH) · 6H2O Amor.
8.DB.05 Pitticite (Fe, AsO4, H2O) (?) Amor.
8.DB.07 Wilhelmgümbelite ZnFe2+Fe3+3(PO4)3(OH)4(H2O)5 · 2H2O Orth. m m m _(_2/_m_2/_m_2/m )
8.DB.07 Schmidite [Zn2(Fe3+,Mn2+)2Fe3+(PO4)3(OH)3(H2O)6] · 2H2O Orth.
8.DB.07 Wildenauerite Zn(Fe3+,Mn2+)2MnFe3+(PO4)3(OH)3(H2O)6 · 2H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b a m
8.DB.10 Vashegyite Al11(PO4)9(OH)6 · 38H2O Orth. m m m _(_2/_m_2/_m_2/m )
8.DB.15 Schoonerite ZnMn2+Fe2+2Fe3+(PO4)3(OH)2 · 9H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b a m
8.DB.20 Sinkankasite Mn2+Al(PO3OH)2(OH) · 6H2O Tric. 1 : _P_1
8.DB.25 Mitryaevaite Al6(PO4)((P,S)O3(OH,O))2F2(OH)2 · 14.5H2O Tric. 1 : _P_1
8.DB.30 Sanjuanite Al2(PO4)(SO4)(OH) · 9H2O Tric.
8.DB.35 Sarmientite Fe3+2(AsO4)(SO4)(OH) · 5H2O Mon. 2/m : _P_21/b
8.DB.40 Bukovskýite Fe3+2(AsO4)(SO4)(OH) · 9H2O Tric. 1 : _P_1
8.DB.40 Flurlite Zn3Mn2+Fe3+(PO4)3(OH)2 · 9H2O Mon. 2/m : _P_21/m
8.DB.40 Manganflurlite ZnMn2+3Fe3+(PO4)3(OH)2(H2O)7 · 2H2O Mon. 2/m : _P_21/m
8.DB.42 Bohuslavite Fe3+4(PO4)3(SO4)(OH) · nH2O Tric. 1 : _P_1
8.DB.45 Zýkaite Fe3+4(AsO4)3(SO4)(OH) · 15H2O Orth. 222 : _P_222
8.DB.47 Lapeyreite Cu3O[AsO3(OH)]2 · 0.75H2O Mon. 2/m : _B_2/m
8.DB.50 Giniite Fe2+Fe3+4(PO4)3(OH)5 · 2H2O Mon. 2/m : _P_2/b
8.DB.50 Rossiantonite Al3(PO4)(SO4)2(OH)2(H2O)14 Tric. 1 : _P_1
8.DB.52 Arctowskite Al9(PO4)8(OH)3 · 27H2O Orth.
8.DB.55 Sasaite (Al,Fe3+)14(PO4)11(SO4)(OH)7 · 83H2O Orth.
8.DB.60 Mcauslanite Fe3Al2(PO4)3(PO3OH)F · 18H2O Tric.
8.DB.65 Goldquarryite CuCd2Al3(PO4)4F2(H2O,F)2 · 10H2O Tric. 1 : _P_1
8.DB.70 Birchite Cd2Cu2(PO4)2(SO4) · 5H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
8.DB.75 Braithwaiteite NaCu5(Ti4+Sb5+)(AsO4)4(HAsO4)2O2 · 8H2O Tric. 1 : _P_1

Other InformationHide

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Notes:

Readily soluble in acids.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for DestineziteHide

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Reference List:

Gritsenko, Yu.D., Ogorodova, L.P., Vigasina, M.F., Melchakova, L.V., Ksenofontov, D.A., Dedushenko, S.K. (2024): Destinezite: A Physicochemical and Calorimetric Study. Geochemistry International, 62, 274-283.

**Palache, Charles, Berman, Harry, Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Ect. John Wiley and Sons, New York.**pp.1011-1013

Peacor, Donald R., Rouse, R. C., Coskren, T. D., Essene, E. J. (1999) Destinezite (“Diadochite”), Fe2(PO4)(SO4)(OH)·6H2O: Its Crystal Structure and Role as a Soil Mineral at Alum Cave Bluff, Tennessee†. Clays and Clay Minerals, 47 (1) 1-11 doi:10.1346/ccmn.1999.0470101

Mills, S.J., Kampf, A.R., Dini, M., Molina, A. (2012) Die weltbesten Destinezit-Kristalle und andere seltene Sulfate von Mejillones, Chile. Mineralien-Welt, 23(2), 73–81 (in German).

Localities for DestineziteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Austria
Styria Leoben District Trofaiach Rötzgraben Treffning Brandstätter et al. (2008)
Belgium
Wallonia Hainaut Bernissart Blaton Mont-des-Groseillers Van Tassel (1956) +7 other references
Liège Amay Ampsin Hatert et al. (2002)
Dalhem Berneau Hatert et al. (2002)
Château de Berneau Hatert et al. (2002)
Héron Couthuin Marsinne Hatert et al. (2002)
Liège Angleur Hatert et al. (2002)
Visé Jorissen (1880) +2 other references
Argenteau (TL) Cesàro (1885) +4 other references
Richelle Mélon et al. (1976)
Namur Anhée Haut-le-Wastia Van Tassel (1985) +1 other reference
Namur Beez quarry Blondieau (2012)
Vedrin Dewalque (1880) +1 other reference
Chile
Antofagasta Antofagasta Province Mejillones Mejillones peninsula Coronel Manuel Rodríguez mine Some of the Sulphates has been ...
Unnamed Cu mine [1] SEM-EDS by Igor V. Pekov
El Loa Province San Pedro de Atacama El Laco Fe deposit Francisco Velasco et al. (2020)
Czech Republic
Central Bohemian Region Beroun District Zdice (Zditz) Vtělenský J. (1959)
Pardubice Region Pardubice District Chvaletice Prachař +6 other references
Prague Hloubětín Cihelna v Bažantnici Chlupáč (1988)
Germany
Thuringia Greiz District Kauern Lichtenberg Absetzer dump T. Witzke & F. Rüger: Lapis 1998 (7/8)
Saalfeld-Rudolstadt District Saalfeld Garnsdorf Jeremias Glück Mine (Fairy Grotto) F. Rüger (1)
Hungary
Heves County Parádfürdő Fülemüle valley collector: János Nyúl
Italy
Tuscany Lucca Province Stazzema Pontestazzemese Buca della Vena Mine Orlandi et al. (2004) +1 other reference
Sant'Anna di Stazzema Monte Arsiccio Mine Mauro (2020)
Japan
Yamaguchi Prefecture Abu District Abu town Hinomaru-Nako mine (Hinomaru-Nago mine) Matsubara et al. (1999)
Russia
Orenburg Oblast Mednogorsk District Sakmara Zone Blyava Cu deposit German (1956)
Slovakia
Bratislava Region Pezinok District Pezinok Kolársky vrch deposit
Spain
Catalonia Barcelona Baix Llobregat Cervelló Riera de Cervelló Mines Joan Rosell (2022)
Tarragona Priorat La Vilella Alta Alum mines Joan Abella i Creus (Joanabellacreus@gmail.com)
USA (TL)
Tennessee Sevier County Alum Cave Bluff (TL) Peacor et al. (1999) +3 other references