Ermakovite (original) (raw)

A valid IMA mineral species

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About ErmakoviteHide

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Name:

Named in honor of Nikolai Porfirievich Ermakov (Николай Порфирьевич Ермаков) (16 November 1913, Kondurchinskaya fortress, Samara province, Russia - 25 September 1993, Moscow , Russia), professor of mineralogy, head of the thermobarogeochemistry lab and founder of the Earth Science Museum at Moscow State University (Russia).

The Br analogue of mauriziodiniite. Known synthetic analogue.

Additional associate: amorphous As2S3.

Details of the sandwich-type structure that has three types of layers
(1) a honeycomb [As2O3] arsenite layer
(2) an NH4+ layer
(3) a Br-layer;
The layer stacking sequence is NH4-As2O3-Br-As2O3-NH4.

Also compare lucabindiite, torrecillasite, and russoite.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:55233:2

8b8eec8d-5b00-4c8a-8bb8-0289d67e34ba

IMA Classification of ErmakoviteHide

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Type description reference:

Karpenko, Vladimir Yu., Pautov, Leonid A., Siidra, Oleg I., Mirakov, Mirak A., Zaitsev, Anatoly N., Plechov, Pavel Yu., Makhmadsharif, Saimudasir (2023) Ermakovite (NH4)(As2O3)2Br, a new exhalative arsenite bromide mineral from the Fan-Yagnob coal deposit, Tajikistan. Mineralogical Magazine, 87 (1) 69-78 doi:10.1180/mgm.2022.116

Classification of ErmakoviteHide

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3.C0.

3 : HALIDES
C : Complex halides
0 :

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Ekv IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of ErmakoviteHide

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Comment:

Zoned with a transparent yellowish core and semi-transparent yellow rim.

Streak:

White with a yellowish tint

Hardness:

VHN20=40 kg/mm2 - Vickers

Fracture:

Irregular/Uneven

Density:

3.64(2) g/cm3 (Measured) 3.747 g/cm3 (Calculated)

Optical Data of ErmakoviteHide

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RI values:

_n_ω = 1.960(5) _n_ε = 1.716(3)

δ = 0.244

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Pleochroism:

Non-pleochroic

Chemistry of ErmakoviteHide

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Mindat Formula:

(NH4)(As2O3)2Br

Crystallography of ErmakoviteHide

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Class (H-M):

6/m m m _(_6/_m_2/_m_2/m ) - Dihexagonal Dipyramidal

Cell Parameters:

a = 5.271(3) Å, c = 9.157(6) Å

Unit Cell V:

220.33 ų (Calculated from Unit Cell)

Morphology:

Tabular or prismatic, hexagonal crystals, up to 200 μm, with the c (001), m (010), and p (014) forms; commonly as spherolitic and multi-twinned intergrowths.

Twinning:

Multi-twinned intergrowths.

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
9.160 Å (80)
4.560 Å (90)
3.228 Å (100)
2.629 Å (80)
2.522 Å (60)
2.276 Å (40)
1.817 Å (40)
1.608 Å (40)

Comments:

From Type Description.

Type Occurrence of ErmakoviteHide

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General Appearance of Type Material:

Tabular or prismatic, hexagonal crystals, up to 200 μm, with the c (001), m (010), and p (014) forms; commonly as spherolitic and multi-twinned intergrowths.

Place of Conservation of Type Material:

Type material is deposited in the collections of the Fersman Mineralogical Museum, Russian Academy of Sciences, Leninskiy Prospekt 18-2, Moscow 119071, Russia, registration number 5525/1.

Empirical Formula of Type Material:

[(NH4)0.92Na0.01]0.93(As3.94Sb0.06)4.00O6.02(Br0.97Cl0.08I0.01)1.06

Geological Setting of Type Material:

Coal-fire-driven exhalative processes within a fumarole.

Associated Minerals at Type Locality:

Synonyms of ErmakoviteHide

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Relationship of Ermakovite to other SpeciesHide

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Other Members of this group:

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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3.C0. Ammineite [CuCl2(NH3)2] Orth. m m m _(_2/_m_2/_m_2/m ) : C m c m

Other InformationHide

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Notes:

Insoluble in water, HCl, HNO3 or organic solvents.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for ErmakoviteHide

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Reference List:

Karpenko, Vladimir Yu., Pautov, Leonid A., Siidra, Oleg I., Mirakov, Mirak A., Zaitsev, Anatoly N., Plechov, Pavel Yu., Makhmadsharif, Saimudasir (2023) Ermakovite (NH4)(As2O3)2Br, a new exhalative arsenite bromide mineral from the Fan-Yagnob coal deposit, Tajikistan. Mineralogical Magazine, 87 (1) 69-78 doi:10.1180/mgm.2022.116

Localities for ErmakoviteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Tajikistan (TL)
Sughd Zeravshan Range Yagnob River Ravat village Kukhi-Malik area (Kuhi-malik) (TL) Miyawaki et al. (2020) +1 other reference