Ryabchikovite (original) (raw)

A valid IMA mineral species

00074450017058794019461.jpg

Colour:

Light brown to reddish-brown

Crystal System:

Monoclinic

Name:

Named in honor of Igor Dmitrievich Ryabchikov (Игорь Дмитриевич Рябчиков) (5 September 1937, Moscow , USSR – 27 November 2017), Russian geochemist, petrologist, and professor at the Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry of the Russian Academy of Sciences (IGEM RAS), Moscow. He made significant contributions in areas related to magmatic rocks and systems.

The first pyroxene with Cu as an essential component. The Cu analogue of diopside. Second silicate mineral with Cu and Mg as essential cations after cyprine.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:55453:4

2c4bbad4-aec8-4e5e-8f5e-1a96a9ba44f0

IMA Classification of RyabchikoviteHide

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Type description reference:

Shchipalkina, Nadezhda V., Vereshchagin, Oleg S., Pekov, Igor V., Belakovskiy, Dmitry I., Koshlyakova, Natalia N., Shilovskikh, Vladimir V., Pankin, Dmitriy V., Britvin, Sergey N., Sandalov, Fedor D., Sidorov, Evgeny G. (2023) Ryabchikovite, CuMg(Si2O6), a new pyroxene group mineral, and some genetic features of natural anhydrous copper silicates. American Mineralogist, 108 (7) 1399-1408 doi:10.2138/am-2022-8620

Classification of RyabchikoviteHide

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9.DA.

9 : SILICATES (Germanates)
D : Inosilicates
A : Inosilicates with 2-periodic single chains, Si2O6; pyroxene family

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Ryb IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of RyabchikoviteHide

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Colour:

Light brown to reddish-brown

Optical Data of RyabchikoviteHide

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RI values:

_n_α = 1.685(5) _n_β = 1.690(5) _n_γ = 1.703(4)

2V:

Measured: 60° (15), Calculated: 64°

δ = 0.018

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Dispersion:

None observed.

Optical Extinction:

Z ∧ c = 47° (where [001] is considered to be parallel to [001] of the underlying diopside crystal of the type material).

Pleochroism:

Non-pleochroic

Chemistry of RyabchikoviteHide

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Chemical AnalysisHide

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Empirical formulas:

Sample ID Empirical Formula
1 (Mg1.05Cu0.78Zn0.06Fe3+0.06Ca0.03)(Si1.96Al0.04O6)

Crystallography of RyabchikoviteHide

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Crystal System:

Monoclinic

Class (H-M):

2/m - Prismatic

Cell Parameters:

a = 9.731(9) Å, b = 8.929(8) Å, c = 5.221(4) Å
β = 110.00(6)°

Ratio:

a:b:c = 1.09 : 1 : 0.585

Unit Cell V:

426.28 ų (Calculated from Unit Cell)

Epitaxial Relationships of RyabchikoviteHide

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X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
4.403 Å (38)
4.307 Å (27)
3.746 Å (32)
3.291 Å (27)
3.177 Å (100)
2.876 Å (75)
2.456 Å (26)
2.215 Å (26)

Type Occurrence of RyabchikoviteHide

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General Appearance of Type Material:

Thin (25 μm max, typically < 10 μm) epitactic crusts on well-formed prismatic diopside crystals.

Place of Conservation of Type Material:

Collections of the Fersman Mineralogical Museum, Russian Academy of Sciences, Leninskiy Prospekt 18-2, Moscow 119071, Russia, registration number 5642/1.

Geological Setting of Type Material:

Fumarole, at temperatures higher than 400–450ºC, likely due to an interaction between Cu-bearing fumarolic gas and earlier formed diopside.

Associated Minerals at Type Locality:

Synonyms of RyabchikoviteHide

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Relationship of Ryabchikovite to other SpeciesHide

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Other Members of this group:

Aegirine NaFe3+Si2O6 Mon. 2/m : _B_2/b
Aegirine-augite (NaaCabFe2+cMgd)(Fe3+eAlfFe2+gMgh)Si2O6 Mon. 2/m : _B_2/b
Augite (CaxMgyFez)(Mgy1Fez1)Si2O6 Mon. 2/m : _B_2/b
Burnettite CaVAlSiO6 Mon. 2/m : _B_2/b
Clinoenstatite MgSiO3 Mon. 2/m : _P_21/b
Clinoferrosilite Fe2+2Si2O6 Mon. 2/m : _P_21/b
Colomeraite NaTi3+Si2O6 Mon. 2/m : _B_2/b
Davisite CaScAlSiO6 Mon. 2/m : _B_2/b
Diopside CaMgSi2O6 Mon. 2/m : _B_2/b
Esseneite CaFe3+[AlSiO6] Mon. 2/m : _B_2/b
Grossmanite CaTi3+ AlSiO6 Mon. 2/m : _B_2/b
Hedenbergite CaFe2+Si2O6 Mon. 2/m : _B_2/b
Jadeite Na(Al,Fe3+)Si2O6 Mon. 2/m : _B_2/b
Jervisite NaSc3+Si2O6 Mon. 2/m : _B_2/b
Johannsenite CaMn2+Si2O6 Mon. 2/m : _B_2/b
Kanoite Mn2+(Mg,Mn2+)Si2O6 Mon. 2/m : _P_21/b
Kosmochlor NaCrSi2O6 Mon. 2/m : _B_2/b
Kushiroite CaAl[AlSiO6] Mon. 2/m : _B_2/b
Namansilite NaMn3+Si2O6 Mon. 2/m : _B_2/b
Natalyite NaV3+Si2O6 Mon. 2/m : _B_2/b
Omphacite (NaaCabFe2+cMgd)(AleFe3+fFe2+gMgh)Si2O6 Mon. 2/m
Petedunnite Ca(Zn,Mn2+,Mg,Fe2+)Si2O6 Mon. 2/m : _B_2/b
Pigeonite (CaxMgyFez)(Mgy1Fez1)Si2O6 Mon. 2/m : _P_21/b
Spodumene LiAlSi2O6 Mon. 2/m : _B_2/b
Tissintite (Ca,Na,◻)AlSi2O6 Mon. 2/m : _B_2/b
UM2001-19-SiO:AlCaMgNa (Na,Mg,Ca)(Mg,Al)Si2O6 Mon. 2/m : _B_2/b
UM2003-36-SiO:CaNa NaCrSi2O6 - CaMgSi2O6 Mon. 2/m : _B_2/b

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9.DA. Protoenstatite Mg2Si2O6 Orth. m m m _(_2/_m_2/_m_2/m ) : P b c n
9.DA. Colomeraite NaTi3+Si2O6 Mon. 2/m : _B_2/b
9.DA.05 Donpeacorite (Mn,Mg)MgSi2O6 Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
9.DA.05 Enstatite Mg2Si2O6 Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
9.DA.05 Ferrosilite Fe2+2Si2O6 Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
9.DA.10 Clinoenstatite MgSiO3 Mon. 2/m : _P_21/b
9.DA.10 Clinoferrosilite Fe2+2Si2O6 Mon. 2/m : _P_21/b
9.DA.10 Kanoite Mn2+(Mg,Mn2+)Si2O6 Mon. 2/m : _P_21/b
9.DA.10 Pigeonite (CaxMgyFez)(Mgy1Fez1)Si2O6 Mon. 2/m : _P_21/b
9.DA.15 Augite (CaxMgyFez)(Mgy1Fez1)Si2O6 Mon. 2/m : _B_2/b
9.DA.15 Diopside CaMgSi2O6 Mon. 2/m : _B_2/b
9.DA.15 Esseneite CaFe3+[AlSiO6] Mon. 2/m : _B_2/b
9.DA.15 Hedenbergite CaFe2+Si2O6 Mon. 2/m : _B_2/b
9.DA.15 va Jeffersonite Ca(Mn,Zn,Fe)Si2O6
9.DA.15 Johannsenite CaMn2+Si2O6 Mon. 2/m : _B_2/b
9.DA.15 Petedunnite Ca(Zn,Mn2+,Mg,Fe2+)Si2O6 Mon. 2/m : _B_2/b
9.DA.15 Davisite CaScAlSiO6 Mon. 2/m : _B_2/b
9.DA.15 Kushiroite CaAl[AlSiO6] Mon. 2/m : _B_2/b
9.DA.15 Grossmanite CaTi3+ AlSiO6 Mon. 2/m : _B_2/b
9.DA.20 Aegirine-augite (NaaCabFe2+cMgd)(Fe3+eAlfFe2+gMgh)Si2O6 Mon. 2/m : _B_2/b
9.DA.20 Omphacite (NaaCabFe2+cMgd)(AleFe3+fFe2+gMgh)Si2O6 Mon. 2/m
9.DA.25 Aegirine NaFe3+Si2O6 Mon. 2/m : _B_2/b
9.DA.25 Jadeite Na(Al,Fe3+)Si2O6 Mon. 2/m : _B_2/b
9.DA.25 Jervisite NaSc3+Si2O6 Mon. 2/m : _B_2/b
9.DA.25 Kosmochlor NaCrSi2O6 Mon. 2/m : _B_2/b
9.DA.25 Namansilite NaMn3+Si2O6 Mon. 2/m : _B_2/b
9.DA.25 Natalyite NaV3+Si2O6 Mon. 2/m : _B_2/b
9.DA.25 Tissintite (Ca,Na,◻)AlSi2O6 Mon. 2/m : _B_2/b
9.DA.30 Spodumene LiAlSi2O6 Mon. 2/m : _B_2/b
9.DA.35 Hiroseite FeSiO3 Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a

Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for RyabchikoviteHide

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Reference List:

Shchipalkina, Nadezhda V., Vereshchagin, Oleg S., Pekov, Igor V., Belakovskiy, Dmitry I., Koshlyakova, Natalia N., Shilovskikh, Vladimir V., Pankin, Dmitriy V., Britvin, Sergey N., Sandalov, Fedor D., Sidorov, Evgeny G. (2023) Ryabchikovite, CuMg(Si2O6), a new pyroxene group mineral, and some genetic features of natural anhydrous copper silicates. American Mineralogist, 108 (7) 1399-1408 doi:10.2138/am-2022-8620

Localities for RyabchikoviteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Russia (TL)
Kamchatka Krai Milkovsky District Tolbachik Volcanic field Great Fissure eruption (Main Fracture) Northern Breakthrough (North Breach) Second scoria cone Arsenatnaya fumarole (TL) Miyawaki et al. (2021) +1 other reference