Khaidarkanite (original) (raw)

A valid IMA mineral species

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About KhaidarkaniteHide

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Formula:

Cu4Al3(OH)14F3 · 2H2O

Originally given as Na0.34Cu4Al3(OH)14F3 · 2H2O.

Colour:

Light blue or bright sky-blue

Crystal System:

Monoclinic

Name:

Named after the discovery locality.

Cyanotrichite Group.
Visually similar to cyanotrichite and carbonatecyantrichite.

A small amount of sulphate may be present (or even necessary) in khaidarkanite; the Na content may be variable (Hager et al., 2009). Hager et al. (2009) attributed the Na content to impurities. The current (2022) IMA formula has no Na.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:7135:8

b9e88d11-cb4b-452a-add1-4105bfd07596

IMA Classification of KhaidarkaniteHide

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Type description reference:

Chukanov, N.V., Karpenko, V.Y., Rastsvetaeva, R.K., Zadov, A.E., Kuz'mina, O.V. (1999) Khaidarkanite Cu4Al3(OH)14F3·2H2O, new mineral from Khaidarkan deposit, Kyrgyzstan. Zapiski Vserossijskogo Mineralogicheskogo Obshchestva: 128(3): 58-63.

Classification of KhaidarkaniteHide

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3.DA.45

3 : HALIDES
D : Oxyhalides, hydroxyhalides and related double halides
A : With Cu, etc., without Pb

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Kdk IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of KhaidarkaniteHide

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Colour:

Light blue or bright sky-blue

Density:

2.84 g/cm3 (Measured) 3.00 g/cm3 (Calculated)

Optical Data of KhaidarkaniteHide

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RI values:

_n_α = 1.585(2) _n_β = 1.615(3) _n_γ = 1.648(2)

2V:

Calculated: 80° to 90°

δ = 0.063

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Comments:

X = colorless, Y = sky blue, Z = bright blue, Z > Y > X

Chemistry of KhaidarkaniteHide

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Mindat Formula:

Cu4Al3(OH)14F3 · 2H2O

Originally given as Na0.34Cu4Al3(OH)14F3 · 2H2O.

Crystallography of KhaidarkaniteHide

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Crystal System:

Monoclinic

Class (H-M):

2/m - Prismatic

Cell Parameters:

a = 12.346(3) Å, b = 2.907(3) Å, c = 10.369(7) Å
β = 97.90(2)°

Ratio:

a:b:c = 4.247 : 1 : 3.567

Unit Cell V:

368.61 ų (Calculated from Unit Cell)

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0019201 Khaidarkanite Hager S L, Leverett P, Williams P A (2009) Possible structural and chemical relationships in the cyanotrichite group The Canadian Mineralogist 47 635-648 2009 Khaidarkan, Kyrgyzstan 0 293
0012502 Khaidarkanite Rastsvetaeva R K, Chukanov N V, Karpenko V Y (1997) Crystal structure of new native compound Cu4Al3(OH)14F3(H2O)2 Doklady Chemistry 353 45-48 1997 Khaidarkan, Kyrgyzstan 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
10.29 Å (80)
5.589 Å (90)
4.232 Å (100)
2.828 Å (90)
2.362 Å (100)
1.871 Å (80)
1.817 Å (80)

Geological EnvironmentHide

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Type Occurrence of KhaidarkaniteHide

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General Appearance of Type Material:

Flat, acicular crystals up to 0.03 × 0.05 × 7 mm, as radial aggregates up to 1 mm across, and as fibrous aggregates.

Place of Conservation of Type Material:

Fersman Mineralogical Museum, Moscow, and in the S.V. Tsaregorodtsev collection at the Ilmenskii Reservation, South Urals, Russia.

Geological Setting of Type Material:

oxidation zone of antimony-mercury deposit

Associated Minerals at Type Locality:

Reference:

Chukanov, N.V., Karpenko, V.Y., Rastsvetaeva, R.K., Zadov, A.E., Kuz'mina, O.V. (1999) Khaidarkanite Cu4Al3(OH)14F3·2H2O, new mineral from Khaidarkan deposit, Kyrgyzstan. Zapiski Vserossijskogo Mineralogicheskogo Obshchestva: 128(3): 58-63.

Synonyms of KhaidarkaniteHide

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Other Language Names for KhaidarkaniteHide

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Relationship of Khaidarkanite to other SpeciesHide

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Other Members of this group:

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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Other InformationHide

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IR Spectrum:

Absorption bands at 3490, 3400, 3190, 1630, 1560, 1135, 1101, 1036, 930, 885, 744, 658, 574, 508, and 452 cm–1

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for KhaidarkaniteHide

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Reference List:

Chukanov, N.V., Karpenko, V.Y., Rastsvetaeva, R.K., Zadov, A.E., Kuz'mina, O.V. (1999) Khaidarkanite Cu4Al3(OH)14F3·2H2O, new mineral from Khaidarkan deposit, Kyrgyzstan. Zapiski Vserossijskogo Mineralogicheskogo Obshchestva: 128(3): 58-63.

Mills, S. J., Christy, A. G., Schnyder, C., Favreau, G., Price, J. R. (2014) The crystal structure of camerolaite and structural variation in the cyanotrichite family of merotypes. Mineralogical Magazine, 78 (7) 1527-1552 doi:10.1180/minmag.2014.078.7.02

Localities for KhaidarkaniteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Austria
Salzburg Zell am See District Rauris Alteck - Hoher Sonnblick area Hoher Sonnblick North face Schnorrer et al. (2000)
Germany
Baden-Württemberg Freiburg Region Ortenaukreis Oberwolfach Clara Mine Kolitsch et al. (2010)
Italy
Friuli Venezia Giulia Udine Province Comeglians Bortolozzi et al. (2018)
Kyrgyzstan (TL)
Batken Region Kadamjay District Khaidarkan Sb-Hg deposit (TL) Chukanov et al. (1999) +1 other reference
Mednaya Gorka Robert Lavinsky specimen