Kukharenkoite-(Ce) (original) (raw)

A valid IMA mineral species

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About Kukharenkoite-(Ce)Hide

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Colour:

Yellow, red-brown, pink-grey, colourless

Crystal System:

Monoclinic

Name:

For Prof. Alexander Alexandrovich Kukharenko (Александр Алексеевич Кухаренко) (1914, Moscow, Russian Empire - 1993), Department of Mineralogy, St. Petersburg University, St. Petersburg, Russia. The suffix/modifier follows the Levinson rule for species with essential REE, indicating, in this case, predominant cerium.

Co-Type Localities:

Poudrette quarry (De-Mix quarry; Demix quarry; Uni-Mix quarry; Carrière Mont Saint-Hilaire; MSH), Mont Saint-Hilaire, La Vallée-du-Richelieu RCM, Montérégie, Québec, Canada
Demix-Varennes quarry, Saint-Amable sill, Varennes & St-Amable, Lajemmerais RCM, Montérégie, Québec, Canada
Kirovskii apatite mine, Kukisvumchorr Mt, Khibiny Massif, Murmansk Oblast, Russia
Vuoriyarvi alkaline-ultrabasic massif, Northern Karelia, Murmansk Oblast, Russia

This page provides mineralogical data about Kukharenkoite-(Ce).

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:7146:4

47c1cb2a-3eb9-4074-bf30-17aab884a4c8

IMA Classification of Kukharenkoite-(Ce)Hide

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Classification of Kukharenkoite-(Ce)Hide

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5.BD.10

5 : CARBONATES (NITRATES)
B : Carbonates with additional anions, without H2O
D : With rare earth elements (REE)

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Kkk-Ce IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of Kukharenkoite-(Ce)Hide

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Colour:

Yellow, red-brown, pink-grey, colourless

Hardness:

VHN25=280(25) kg/mm2 - Vickers

Optical Data of Kukharenkoite-(Ce)Hide

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RI values:

_n_α = 1.584 - 1.594 _n_β = 1.710 - 1.724 _n_γ = 1.715 - 1.728

2V:

Measured: 16° , Calculated: 18° to 20°

δ = 0.131 - 0.134

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Dispersion:

r > v moderate

Chemistry of Kukharenkoite-(Ce)Hide

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Mindat Formula:

Ba2Ce(CO3)3F

Crystallography of Kukharenkoite-(Ce)Hide

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Crystal System:

Monoclinic

Class (H-M):

2/m - Prismatic

Cell Parameters:

a = 13.406 Å, b = 5.072 Å, c = 6.707 Å
β = 106.57°

Ratio:

a:b:c = 2.643 : 1 : 1.322

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0005546 Kukharenkoite-(Ce) Krivovichev S V, Filatov S K, Zaitsev A N (1998) The crystal structure of kukharenkoite-(Ce), Ba2REE(CO3)3F,and an interpretation based on cation-coordinated F tetrahedra The Canadian Mineralogist 36 809-815 1998 0 293
0012563 Kukharenkoite-(Ce) Mercier N, Leblanc M (1993) Crystal growth and structures of rare earth fluorocarbonates: I. Structures of BaSm(CO3)2F and Ba3La2(CO3)5F2: revision of the corresponding huanghoite and cebaite type structures _cod_database_code 1000320 European Journal of Solid State and Inorganic Chemistry 30 195-205 1993 synthetic 0 293
0012566 Kukharenkoite-(Ce) Mercier N, Leblanc M (1993) Crystal growth and structures of rare earth fluorocarbonates: II. Structures of zhonghuacerite Ba2Ce(CO3)3F. Correlations between huanghoite, cebaite and zhonghuacerite type structures _cod_database_code 1000477 European Journal of Solid State and Inorganic Chemistry 30 207-216 1993 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
4.000 Å (100)
3.269 Å (100)
2.535 Å (20)
2.140 Å (40)
2.003 Å (40)

Comments:

The data are from the type description.

Geological EnvironmentHide

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Type Occurrence of Kukharenkoite-(Ce)Hide

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Co-Type Localities:

Poudrette quarry (De-Mix quarry; Demix quarry; Uni-Mix quarry; Carrière Mont Saint-Hilaire; MSH), Mont Saint-Hilaire, La Vallée-du-Richelieu RCM, Montérégie, Québec, Canada
Demix-Varennes quarry, Saint-Amable sill, Varennes & St-Amable, Lajemmerais RCM, Montérégie, Québec, Canada
Kirovskii apatite mine, Kukisvumchorr Mt, Khibiny Massif, Murmansk Oblast, Russia
Vuoriyarvi alkaline-ultrabasic massif, Northern Karelia, Murmansk Oblast, Russia

General Appearance of Type Material:

Small (0.01-1.0 mm), prismatic, bladed crystals, often in dendritc or stellate groups 2-3 mm across.

Place of Conservation of Type Material:

Canadian Museum of Nature, Ottawa, Ontario, Canada, numbers CMNI 81531 and CMNI 81533 (cotype).
Mining Museum, St. Petersburg, Russia, number 1/18303 (cotype).

Geological Setting of Type Material:

Kukharenkoite-(Ce) has 4 type localities with data derived from bona fide type specimens from all four localities. In fact we found the TL3 type specimen in 1976. TL 1: Kirov mine, Khibina massif, Kola Peninsula, Russia. TL 2: Poudrette quarry, Mont Saint-Hilaire, Rouville County, Québec [45 33' N, 73 08' W]. TL 3: Demix (Varennes) quarry, Saint-Amable sill, Saint-Amable and Varennes, Verchères County, Québec [45 39' N, 73 17' W]. TL 4: Vuorijärvi massif, Kola Peninsula, Russia.

Associated Minerals at Type Locality:

Synonyms of Kukharenkoite-(Ce)Hide

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Other Language Names for Kukharenkoite-(Ce)Hide

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Common AssociatesHide

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Associated Minerals Based on Photo Data:

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5.BD. Cordylite-(La) (Na,Ca)Ba(La,Ce,Sr)2(CO3)4F Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_63/m m c
5.BD.05 Cordylite-(Ce) NaBaCe2(CO3)4F Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_63/m m c
5.BD.05 Lukechangite-(Ce) Na3Ce2(CO3)4F Hex. 6_m_ m : P_63_m c
5.BD.05 Unnamed (Cordylite-like (Ca0.5[]0.5)BaCe2[CO3]4F) Ca◻Ba2Ce4[CO3]8F2
5.BD.10 Zhonghuacerite-(Ce) Ba2Ce(CO3)3F Trig.
5.BD.10 Kukharenkoite-(La) Ba2(La,Ce,Th)(CO3)3F Mon. 2/m : _P_21/m
5.BD.15 Cebaite-(Ce) Ba3Ce2(CO3)5F2 Mon. 2/m : _B_2/m
5.BD.15 Cebaite-(Nd) Ba3(Nd,Ce)2(CO3)5F2 Mon.
5.BD.18 Arisite-(Ce) NaCe2(CO3)2[F2x(CO3)1-x]F Hex. 6_m_2 : _P_6_m_2
5.BD.18 Arisite-(La) NaLa2(CO3)2[F2x(CO3)1-x]F Hex. 6_m_2 : _P_6_m_2
5.BD.20a Bastnäsite-(Ce) Ce(CO3)F Hex. 6_m_2 : _P_6_c_2
5.BD.20a Bastnäsite-(La) La(CO3)F Hex. 6_m_2 : P_62_c
5.BD.20a Bastnäsite-(Y) Y(CO3)F Hex. 6_m_2 : P_62_c
5.BD.20a Hydroxylbastnäsite-(Ce) Ce(CO3)(OH) Hex. 6 : _P_6
5.BD.20a Hydroxylbastnäsite-(Nd) Nd(CO3)(OH) Hex. 6_m_2 : P_62_c
5.BD.20a Hydroxylbastnäsite-(La) (La,Nd,Ce)(CO3)(OH,F) Hex. 6 : _P_6
5.BD.20b Parisite-(Ce) CaCe2(CO3)3F2 Mon. m : B b
5.BD.20b Parisite-(Nd) Ca(Nd,Ce,La)2(CO3)3F2 Mon. m : B b
5.BD.20d Röntgenite-(Ce) Ca2(Ce,La)3(CO3)5F3 Trig. 3 : _R_3
5.BD.20c Synchysite-(Ce) CaCe(CO3)2F Mon. 2/m : _B_2/b
5.BD.20c Synchysite-(Nd) CaNd(CO3)2F Orth.
5.BD.20c Synchysite-(Y) CaY(CO3)2F Mon. 2/m : _B_2/b
5.BD.20a Thorbastnäsite ThCa(CO3)2F2 · 3H2O Hex. 6_m_2 : P_62_c
5.BD.20a Bastnäsite-(Nd) Nd(CO3)F Hex. 6_m_2 : P_62_c
5.BD.20c Hydroxylsynchysite-(Ce) Ca(Ce,La)(CO3)2(OH)
5.BD.20c Synchysite-(La) Ca(La,Nd)(CO3)2F
5.BD.20b Parisite-(La) CaLa2(CO3)3F2 Mon.
5.BD.25 Horváthite-(Y) NaY(CO3)F2 Orth. m m m _(_2/_m_2/_m_2/m ) : P m m n
5.BD.25 Qaqarssukite-(Ce) Ba(Ce,REE)(CO3)2F Trig. 3 : _P_3
5.BD.35 Huanghoite-(Ce) BaCe(CO3)2F Trig. 3_m_ _(_32/m ) : R_3_m
5.BD.45 Bayanoboite-(Y) Ba2Y(CO3)2F3 Orth. m m m _(_2/_m_2/_m_2/m ) : P b c n

Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for Kukharenkoite-(Ce)Hide

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Reference List:

Zaitsev, A.N., Yakovenchuk, V.N., Chao, G.Y., Gault, R.A., Subbotin, V.V., Pakhomosky, Y.A. & Bogdanova, A.N. (1996): Kukharenkoite-(Ce), Ba2Ce(CO3)3F, a new mineral from Kola Peninsula, Russia and Québec, Canada. European Journal of Mineralogy 8, 1327-1336.

Horváth, László, Gault, Robert A., Tarassoff, Peter, Pfenninger-Horváth, Elsa (1998) Mineralogy of the Saint-Amable Sill, Varennes and Saint-Amable, Quebec. The Mineralogical Record, 29 (2) 83-118

Localities for Kukharenkoite-(Ce)Hide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Canada
British Columbia Cariboo Mining Division Wicheeda Lake Wicheeda Carbonatite Complex Dalsin (2013) +1 other reference
Québec Montérégie La Vallée-du-Richelieu RCM Mont Saint-Hilaire Poudrette quarry (De-Mix quarry; Demix quarry; Uni-Mix quarry; Carrière Mont Saint-Hilaire; MSH) (TL) ZAITSEV et al. (1996)
Lajemmerais RCM Varennes & St-Amable Saint-Amable sill Horváth et al. (1998)
Demix-Varennes quarry (TL) ZAITSEV et al. (1996) +1 other reference
Nord-du-Québec Jamésie Montviel carbonatite complex Nadeau et al. (2014) +2 other references
Russia
Irkutsk Oblast Vitim Plateau Biraya and Bya Rivers confluence area (Chara Basin) Biraya Fe-REE ore occurrence Koneva A.A. et al. (2010)
Ust'-Biraya C. Lemanski (re-entry of lost Mindat data)
Murmansk Oblast Khibiny Massif Kukisvumchorr Mt Kirovskii apatite mine (TL) Zaitsev et al. (1996) +1 other reference
The Carbonatite Stock in the vicinity of Tul'ilukht Bay Zaitsev et al. (1996) +3 other references
Northern Karelia Vuoriyarvi alkaline-ultrabasic massif (TL) ZAITSEV et al. (1996)
Spain
Canary Islands Santa Cruz de Tenerife Province Tenerife Los Blanquitos Dill et al. (2023)