Calciohilairite (original) (raw)

A valid IMA mineral species

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About CalciohilairiteHide

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Formula:

CaZr[SiO3]3 · 3H2O

Colour:

White to pale blue

Name:

For its chemical composition and relationship to hilairite

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:831:8

b75e196c-e676-476a-8efe-249dc6cfb598

IMA Classification of CalciohilairiteHide

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IMA Formula:

CaZrSi3O9 · 3H2O

Type description reference:

Classification of CalciohilairiteHide

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9.DM.10

9 : SILICATES (Germanates)
D : Inosilicates
M : Inosilicates with 6-periodic single chains

59.2.3.2

59 : CYCLOSILICATES Three-Membered Rings
2 : Three-Membered Rings, hydrated

14.10.21

14 : Silicates not Containing Aluminum
10 : Silicates of Zr or Hf

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Chlr IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of CalciohilairiteHide

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Colour:

White to pale blue

Density:

2.68(2) g/cm3 (Measured)

Optical Data of CalciohilairiteHide

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RI values:

_n_ω = 1.622(1) _n_ε = 1.619(1)

δ = 0.003

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Chemistry of CalciohilairiteHide

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Mindat Formula:

CaZr[SiO3]3 · 3H2O

Common Impurities:

Na,Cu,Al,Fe,Ti

Crystallography of CalciohilairiteHide

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Class (H-M):

32 - Trapezohedral

Cell Parameters:

a = 20.870(4) Å, c = 16.002(4) Å

Unit Cell V:

6,036.01 ų (Calculated from Unit Cell)

Morphology:

Two trigonal prisms {11-20}, {2-1-10} and two rhombohedrons {10-12} and {00-12}.

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0012381 Calciohilairite Pushcharovsky D Y, Pekov I V, Pasero M, Gobechiya E R, Merlino S, Zubkova N V (2002) Crystal structure of cation-deficient calciohilairite and possible mechanisms of decationization in mixed-framework minerals Crystallography Reports 47 748-752 2002 Lovozero massif, Kola Peninsula, Russia 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
5.231 Å (100)
3.013 Å (30)
3.137 Å (20)
5.993 Å (12)
2.607 Å (9)
2.900 Å (7)
3.197 Å (6)

Geological EnvironmentHide

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Type Occurrence of CalciohilairiteHide

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General Appearance of Type Material:

White to pale blue unaltered and altered crystals, to 2 mm.

Place of Conservation of Type Material:

National Museum of Natural History, Smithsonian Institution, Washington, D.C. (NMNH no. 161901 and 162182).
Russell C. Boggs collection (no. T990 to T996).

Geological Setting of Type Material:

Miarolitic cavities in peralkaline granite.

Associated Minerals at Type Locality:

Reference:

Boggs, R.C. (1988) Calciohilairite: CaZrSi3O9•3H2O The calcium analogue of hilairite from the Golden Horn batholith, Northern Cascades, Washington. American Mineralogist: 73: 1191-1194.

Synonyms of CalciohilairiteHide

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Other Language Names for CalciohilairiteHide

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Relationship of Calciohilairite to other SpeciesHide

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Other Members of this group:

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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Fluorescence of CalciohilairiteHide

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Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for CalciohilairiteHide

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Reference List:

Pushcharovskii, D.Yu., Pekov, I.V., Pazero, M. Gobechiya, E.R., Merlino, S., Zubkova, N.V. (2002) Crystal structure of cation-deficient calciohilairite and probable decationing mechanisms in minerals with mixed frameworks. Kristallographia: 47(5): 814-818. (in Russian)

Localities for CalciohilairiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Brazil
Minas Gerais Poços de Caldas alkaline complex Gomes et al. (2023)
Canada
Québec Montérégie La Vallée-du-Richelieu RCM Mont Saint-Hilaire Poudrette quarry (De-Mix quarry; Demix quarry; Uni-Mix quarry; Carrière Mont Saint-Hilaire; MSH) HORVÁTH et al. (2000)
Lajemmerais RCM Varennes & St-Amable Saint-Amable sill Horváth et al. (1998)
Demix-Varennes quarry Horváth et al. (1998)
Strange Lake complex (Lac Brisson complex) Miller (1990) +4 other references
Norway
Vestfold Larvik Malerød Midtfjellet Quarry Larsen (2021)
Tvedalen Tuften A/S Granit Quarry Larsen (2015)
Portugal
Madeira Madeira Island Machico Porto da Cruz Terra do Baptista gabbro outcrop Pedro Alves collection and analytical ...
Russia
Murmansk Oblast Lovozersky District Seidozero Lake Lepkhe-Nel'm Mt Pekov (2003)
Selsurt Mountain [AmMin 85:1562] +1 other reference
USA
Washington Okanogan County Golden Horn Batholith Markus B. Raschke et al. (2016)
Washington Pass (TL) Micro Probe Volume VI Number 8 +2 other references