Diaboleite (original) (raw)

A valid IMA mineral species - grandfathered

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About DiaboleiteHide

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Specific Gravity:

5.41 - 5.43

Crystal System:

Tetragonal

Name:

From Greek διά, "Dia", apart or distinct from, in allusion to its difference from boleite. Diaboléite (with diacritic) has been used, but this is not accepted usage (Burke 2008).

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:1276:4

22b2585f-b4f9-44c0-8ead-84f02c2917bb

IMA Classification of DiaboleiteHide

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Approved, 'Grandfathered' (first described prior to 1959)

IMA Formula:

CuPb2Cl2(OH)4

Type description reference:

Classification of DiaboleiteHide

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3.DB.05

3 : HALIDES
D : Oxyhalides, hydroxyhalides and related double halides
B : With Pb, Cu, etc.

10.6.1.1

10 : OXYHALIDES AND HYDROXYHALIDES
6 : AmBn(O,OH)pXq

8.8.13

8 : Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and Fluosilicates
8 : Halides of Pb

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Dbol IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of DiaboleiteHide

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Cleavage:

Perfect
On {001}, not easy.

Density:

5.41 - 5.43 g/cm3 (Measured) 5.48 g/cm3 (Calculated)

Optical Data of DiaboleiteHide

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RI values:

_n_ω = 1.980 _n_ε = 1.850

δ = 0.130

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Chemistry of DiaboleiteHide

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Mindat Formula:

Pb2CuCl2(OH)4

Crystallography of DiaboleiteHide

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Crystal System:

Tetragonal

Class (H-M):

4_m_ m - Ditetragonal Pyramidal

Cell Parameters:

a = 5.86 Å, c = 5.49 Å

Unit Cell V:

188.52 ų (Calculated from Unit Cell)

Morphology:

Crystals tabular {001}, with a square outline. The crystals are hemimorphic; the large base is negative; the positive pedion is lacking or is very small with a somewhat curved surface. Subparallel groups of thin plates. Rarely tetragonal prisms.

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0005469 Diaboleite Cooper M A, Hawthorne F C (1995) Diaboleite, Pb2Cu(OH)4Cl2, a defect perovskite structure with stereoactive lone-pair behavior of Pb The Canadian Mineralogist 33 1125-1129 1995 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
5.51 Å (10)
3.305 Å (9)
2.283 Å (10)
2.929 Å (8)
2.580 Å (9)
1.755 Å (9)
1.537 Å (9)

Type Occurrence of DiaboleiteHide

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Place of Conservation of Type Material:

The Natural History Museum, London, England, number 1923,521.
National Museum of Natural History, Washington, D.C., USA, number 94813.

Geological Setting of Type Material:

Oxidized iron and manganese ores.

Associated Minerals at Type Locality:

Reference:

Spencer, L.J., Mountain, E.D. (1923) New lead-copper minerals from the Mendip Hills (Somerset). Mineralogical Magazine: 20: 67-92 (78).

Other Language Names for DiaboleiteHide

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Relationship of Diaboleite to other SpeciesHide

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Common AssociatesHide

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Associated Minerals Based on Photo Data:

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3.DB. Rickturnerite Pb7O4[Mg(OH)4](OH)Cl3 Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
3.DB.10 Pseudoboleite Pb31Cu24Cl62(OH)48 Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_4/m m m
3.DB.15 Boleite KPb26Ag9Cu24(OH)48Cl62 Iso. m_3_m _(_4/_m_32/m ) : P m_3_m
3.DB.20 Cumengeite Pb21Cu20Cl42(OH)40 · 6H2O Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_4/m m m
3.DB.25 Bideauxite Pb2AgCl3(F,OH)2 Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
3.DB.30 Chloroxiphite Pb3CuO2Cl2(OH)2 Mon. 2/m : _P_21/m
3.DB.35 Hematophanite Pb4Fe3O8(OH,Cl) Tet. 4_m_ m : P_4_m m
3.DB.40 Asisite Pb7SiO9Cl2 Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_4/m m m
3.DB.40 Parkinsonite Pb7MoO9Cl2 Tet.
3.DB.40 Janchevite Pb7V5+(O8.5◻0.5)Cl2 Tric. 1 : _P_1
3.DB.45 Murdochite Cu12Pb2O15Cl2 Iso. m_3_m _(_4/_m_32/m ) : F m_3_m
3.DB.45 Eddavidite Cu12Pb2O15Br2 Iso. m_3_m _(_4/_m_32/m ) : F m_3_m
3.DB.50 Yedlinite Pb6Cr3+Cl6(O,OH,H2O)8 Trig. 3 : _R_3
3.DB.55 Siidraite Pb2Cu(OH)2I3 Orth. m m m _(_2/_m_2/_m_2/m ) : F d d d

Other InformationHide

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Notes:

Completely soluble in nitric acid.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for DiaboleiteHide

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Reference List:

**Palache, Charles, Berman, Harry, Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Ect. John Wiley and Sons, New York.**pp.82-83

Alun Humphreys, D., Thomas, John H., Williams, Peter A., Symes, Robert F. (1980) The chemical stability of mendipite, diaboleïte, chloroxiphite, and cumengéite, and their relationships to other secondary lead(II) minerals. Mineralogical Magazine, 43 (331) 901-904 doi:10.1180/minmag.1980.043.331.13

Localities for DiaboleiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Australia
South Australia City of Onkaparinga Chandlers Hill Mount Malvern Mine Kolitsch et al. (1999)
Western Australia Ashburton Shire Ashburton Downs Station [Mandarino +1 other reference
Mineral Claim 84 Cu deposit (Anticline prospect) Grice et al. (1991)
Austria
Carinthia Sankt Veit an der Glan District Guttaring Waitschach Slag localities Kolitsch et al. (2009) +2 other references
Chile
Antofagasta Antofagasta Province Cerro Palestina Estación Cerro Negro Magallanes district Covadonga mine Samples analysed by Dr. Jochen Schlüter (Hamburg University)
Magallanes mine "Yacimientos Metalíferos de Chile" +1 other reference
Cuevitas San Cristóbal Bolaco Mine Sample from the collection of Copiapó ...
Sierra Gorda Caracoles mining district Caracoles Casucha Mine V. Sapienza collection
La Poderosa Mine V. Sapienza collection
Margarita Mine Samples analysed by Dr. Jochen Schluter
San Francisco Mine M. Dini specimens
Santa Ana Mine Mücke (1972)
Unión Minera mine Samples analysed by Dr. Jochen Schlüter (Hamburg University)
La Compañia Mine collected and analysed by french ...
Taltal La Negra mine Samples analysed by Dr. Jochen Schlüter (Hamburg University)
Atacama Chañaral Province Caballo Muerto mining district Por si acaso mine gerhard mohn EDS and SEM
Copiapó Province Copiapó Cachiyuyo de Llampos mining district Dulcinea de Llampos Mine Robert Jenkins collections +1 other reference
France
Auvergne-Rhône-Alpes Loire Roanne Le Crozet Les Rats Mine slag dumps Chollet et al. (2013)
Provence-Alpes-Côte d'Azur Var Toulon Le Pradet Cap Garonne Mine Jean-Marie Claude collection +2 other references
La Gavaresse workings Jean-Marie Claude collection
North mine Favreau et al. (2024)
Germany
Hesse Kassel Region Hersfeld-Rotenburg Nentershausen Süß Richelsdorf Smelter Slag dumps Weiß (1990)
Lower Saxony Goslar District Langelsheim Astfeld Herzog Julius smelter slag locality van den Berg et al. (1990)
North Rhine-Westphalia Düsseldorf Essen Dellwig Christian Levin coal mine Weiß (1990)
Greece
Attica East Attica Lavreotiki Lavrion Mining District Km 3 Kaminiza mines Esperanza Mine
Sounion Cato Sounio mines Sounion Mine No. 19 Rieck et al. (1999) +1 other reference
Lavrion slag localities 40 (in German) +2 other references
Agios Nikolaos Cove slag locality Fritz Schreiber collection (SXRD-analysed by Uwe Kolitsch)
Harakas Cove slag locality Fritz Schreiber collection
Legrena Cove slag locality (Legraina Cove) Ko Jansen collection
Passa Limani Cove slag locality Gelaude et al. (1996)
Sounion Cove slag locality Gelaude et al. (1996)
Thorikos Bay slag locality Christian Rewitzer collection
Vrissaki Point slag locality Gelaude et al. (1996)
Iran
Isfahan Province Nain County Anarak District Chah Khouni Mine Bariand +1 other reference
Sebarz Mine (Sebraz Mine; Sebarg Mine) Bariand et al. (1963)
South Khorasan Province Tabas County Deyhuk District Nayband (Neyband) Seh-Changi Mine Encyclopedia of Minerals
Italy
Lazio Metropolitan City of Rome Capital Anzio Tor Caldara slag locality Marco Bonifazi collection
Liguria Genoa Genoa Varenna Valley Carpenara slag locality Rivista Mineralogica Italiana (Avril/Juin)
Tuscany Livorno Province Campiglia Marittima Madonna di Fucinaia (Madonna della Fucinaia) slag heaps Int. Assoc. of Collectors of Slag Minerals (2) +1 other reference
Capattoli Valley slag locality www.comune.pisa.it (2000)
Piombino Baratti slag locality Franzini et al. (1992) +2 other references
Sassetta Canina Valley Podere del Cancellino (Podere dei Cancellini) slag locality Jansen et al. (1998)
Suvereto Suvereto slag locality Luigi Chiappino data
Portugal
Beja Castro Verde Castro Verde e Casével Herdade da Misericórdia Mine Pedro Alves collection and analytical ...
South Africa
Northern Cape Namakwa District Municipality Khâi-Ma Local Municipality Aggeneys Cairncross et al. (1995)
Black Mountain (Swartberg mine) Meyer et al. (1986)
Spain
Asturias Vegadeo Meredo Bedures hill (Vidures hill) La Reixidora mine Calvo Rebollar et al. (2018)
UK
England Cornwall Crantock The Gannel Smelter slag locality BMS Newsletter 79 (http://britishmicromountsociety.homestead.com/Gannell-Smelter.html)
Padstow Gunver Head Cuddrabridge Mine (Guddrabridge Mine; Padstow Consols; Trevone Consols; Wheal Galway) Golley et al. (1995)
St Hilary Penberthy Croft Mine S. Rust collection
St Minver Trebetherick Daymer Bay
Somerset Mendip Cranmore Torr Works Quarry Turner (2006) +1 other reference
Nunney Colemans Quarry Day (1999)
Priddy Higher Pitts Mine (TL) Mineralogical Magazine (1923) +2 other references
Mendip Hills Palache et al. (1951)
Sedgemoor Cheddar Batts Coombe Quarry Turner et al. (2010)
USA
Arizona Cochise County Tombstone Mining District Gallagher Vanadium & Rare Minerals Corp Mine Rob Bowell
Silver Plume Mine Emerald Mine Marek Chorazewicz (2023)
Gila County Banner Mining District Christmas C and B Mine (C & B Mine; Vanadium Mine) Raman analyzed at the University of ...
Maricopa County Osborn Mining District Tonopah Belmont Mountain Tonopah-Belmont Mine Collected by and in the collection of ...
Tiger Wash Evening Star Mine Yang et al. (2016)
Painted Rock Mountains Painted Rock Mining District Theba Rowley Mine Wilson et al. (1974) +1 other reference
Pinal County Mammoth Mining District Betts (n.d.)
Tiger St. Anthony deposit Mammoth-Saint Anthony Mine Fahey et al. (1950) +5 other references
Collins Mine Palache (1941) +4 other references
Santa Cruz County Wrightson Mining District Temporal Gulch Gringo Gulch Anthony et al. (1995)
California San Bernardino County Silver Lake Mining District Soda Mountains Baker Otto Mountain Kampf et al. (2010)
Aga Mine Thorne (n.d.)
Bird Nest drift Joe Marty specimens
Bird Nest E3 Rocks & Minerals 86:132-142