Feitknechtite (original) (raw)

A valid IMA mineral species

00952510014962192302430.jpg

07715450014946696148659.jpg

About FeitknechtiteHide

This section is currently hidden. Click the show button to view.

02158390015353615129306.jpg

Colour:

Lead-gray, brownish black

Lustre:

Resinous, Sub-Metallic, Dull, Earthy

Specific Gravity:

3.249 (Calculated)

Name:

Named in 1965 by Owen P. Brickner in honor of Walter Feitknecht [December 14, 1899 Schüpfen, Switzerland - 1975 Bern, Switzerland], systematic researcher relating to manganese oxide minerals and professor of Chemistry, University of Bern, Bern, Switzerland and who first synthesized the compound.

Black replacement of pyrochroite that yielded a mixture of hausmannite and feitknechtite. A specimen of black pyrochroite from the type locality was submitted to the RRUFF Project for Raman spectroscopic examination. Pyrochroite was detected, but not hausmannite or feitknechtite (Heixong Yang, personal communication, 2015).

The structure for a second, and perhaps novel, MnOOH polymorph (proposed designation ε-MnOOH), mixed with the synthetic feitknechtite, that is similar to β-MnOOH but with a different layer stacking.

Unique IdentifiersHide

This section is currently hidden. Click the show button to view.

Long-form identifier:

mindat:1:1:1473:7

261dc517-359c-4c41-9ee6-72b81b36c7ca

IMA Classification of FeitknechtiteHide

This section is currently hidden. Click the show button to view.

Type description reference:

Classification of FeitknechtiteHide

This section is currently hidden. Click the show button to view.

4.FE.25

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
F : Hydroxides (without V or U)
E : Hydroxides with OH, without H2O; sheets of edge-sharing octahedra

6.1.4.3

6 : HYDROXIDES AND OXIDES CONTAINING HYDROXYL
1 : XO(OH)

7.18.6

7 : Oxides and Hydroxides
18 : Oxides of Mn

Mineral SymbolsHide

This section is currently hidden. Click the show button to view.

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

Symbol Source Reference
Fkn IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
Fkn Warr (2020) Warr, L.N. (2020) Recommended abbreviations for the names of clay minerals and associated phases. Clay Minerals, 55, 261–264 doi:10.1180/clm.2020.30

Physical Properties of FeitknechtiteHide

This section is currently hidden. Click the show button to view.

Resinous, Sub-Metallic, Dull, Earthy

Colour:

Lead-gray, brownish black

Density:

3.249 g/cm3 (Calculated)

Comment:

ICDD lists D (measured and calculated) = 3.80. Could be an error

Optical Data of FeitknechtiteHide

This section is currently hidden. Click the show button to view.

RI values:

_n_ω = 2.055 _n_ε = 1.950

δ = 0.105

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Chemistry of FeitknechtiteHide

This section is currently hidden. Click the show button to view.

Crystallography of FeitknechtiteHide

This section is currently hidden. Click the show button to view.

Class (H-M):

3_m_ _(_32/m ) - Hexagonal Scalenohedral

Cell Parameters:

a = 3.32 Å, c = 4.71 Å

Unit Cell V:

44.96 ų (Calculated from Unit Cell)

Morphology:

Hexagonal platelets; granular, earthy.

Comment:

Space group for synthetic material. Note: the structure of another synthetic material (Post et al. 2023) is monoclinic, space group C2/m, a=5.6541(4), b=2.89075(2), c=4.8347(3) Å, β=108.0709(1) deg.

X-Ray Powder DiffractionHide

This section is currently hidden. Click the show button to view.

Powder Diffraction Data:

d-spacing Intensity
4.62 Å (100)
2.635 Å (50)
2.360 Å (20b)
1.960 Å (10b)
1.550 Å (1)
1.500 Å (1)

Comments:

ICDD 18-804 synthetic. Original data by Bricker (1965), but originally thought to be tetragonal.

Geological EnvironmentHide

This section is currently hidden. Click the show button to view.

Type Occurrence of FeitknechtiteHide

This section is currently hidden. Click the show button to view.

General Appearance of Type Material:

Black replacement of pyrochroite. May show trigonal platy appearance.

Geological Setting of Type Material:

Gossan zone of a manganiferous marble-hosted

Associated Minerals at Type Locality:

Reference:

Bricker, O. (1965) Some stability relations in the system Mn−O

2

−H

2

O at 25◦ and one atmosphere total pressure. American Mineralogist: 50: 1296–1354.

Other Language Names for FeitknechtiteHide

This section is currently hidden. Click the show button to view.

Common AssociatesHide

This section is currently hidden. Click the show button to view.

Associated Minerals Based on Photo Data:

This section is currently hidden. Click the show button to view.

Fluorescence of FeitknechtiteHide

This section is currently hidden. Click the show button to view.

Not fluorescent in ultraviolet

Other InformationHide

This section is currently hidden. Click the show button to view.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

This section is currently hidden. Click the show button to view.

References for FeitknechtiteHide

This section is currently hidden. Click the show button to view.

Reference List:

Tani, Y., Kumagai, H., Tamari, M., Umezawa, K., Gotore, O., Miyata, N. (2024): Mineralization of Ni2+-Bearing Mn Oxide through Simultaneous Sequestration of Ni2+ and Mn2+ by Enzymatically Active Fungal Mn Oxides. Minerals, 14, 330.

Luo, J., Segal, S.R., Wang, J.Y., Tian, Z.R., Suib, S.L. (1996) Synthesis, Characterization, and Reactivity of Feitknechtite. Materials Research Society Proceedings: 43: 3-8.

Grangeon, S., Warmont, F., Tournassat, C., Lanson, B., Lanson, M., Elkaïm, E., Claret, F. (2017) Nucleation and growth of feitknechtite from nanocrystalline vernadite precursor. European Journal of Mineralogy: 29: 767-776.

Localities for FeitknechtiteHide

This section is currently hidden. Click the show button to view.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

This section is currently hidden. Click the show button to view.

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Japan
Aichi Prefecture Kitashitara County Shitara Taguchi mine Yamada collection (Crystal World, Japan)
Iwate Prefecture Kuji City Yamagata Hinosawa mine Dr. Matsuo Nambu collection (curated at Geological Survey of Japan)
Kunohe-gun Noda Noda-Tamagawa mine Nambu +4 other references
Miyazaki Prefecture Nishiusuki District Takachiho Morowaku mine Fuzimoto (2006)
Nagano Prefecture Kamiina District Hamayokokawa mine (Hamayokogawa mine) Asahi orebody Akira Kato (2011)
Principal orebody Akira Kato (2011)
Oita Prefecture Tsukumi City Kuratomi mine Minerals Unlimited specimens (Ridgecrest, California)
Shiga Prefecture Kusatsu City Ioi mine Forrest Cureton specimens
Tochigi Prefecture Kanuma City Kaso Mine Akira Kato (undated manuscript)
Mexico
Durango Mapimí Municipality Mapimí Ojuela Mine Moore et al. (2003)
San Pedro Mine Panczner (1987)
Russia
Chelyabinsk Oblast Chebarkulsky District Zmeinogorskoe Mn deposit Chukanov et al. (2021)
South Africa
Northern Cape John Taolo Gaetsewe District Municipality Joe Morolong Local Municipality Middelplaats Mine Cairncross et al. (1995)
Wessels Mine PXRDs by John Attard and at University ... +1 other reference
Sweden
Dalarna County Hedemora Garpenberg Garpenberg Norra Mine - (Kjell Gatedal)
Örebro County Hällefors Grythyttan Sjögruvan Moore (1972)
Värmland County Filipstad Långban Ore District Långban Mine Holtstam et al. (1999)
Nordmark Odal Field Moss mine Langhof (2003)
Switzerland
St. Gallen Sarganserland Sargans Gonzen Mine Roth et al. (2013)
UK
Wales Gwynedd Aberdaron Rhiw Benallt Mine Cotterell (2008)
USA (TL)
New Jersey Sussex County Franklin Franklin Mine (TL) Frondel (1953) +2 other references