Garyansellite (original) (raw)

A valid IMA mineral species

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About GaryanselliteHide

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Formula:

(Mg,Fe)3(PO4)2(OH,O) · 1.5H2O

Crystal System:

Orthorhombic

Name:

Named in 1984 by Bozidar Darko Sturman and Pete J. Dunn in honor of Harold Gary Ansell (1943 - ), mineralogist with the Canadian Geological Survey. He was curator of the National Mineral Collection from 1972-1997.

Forms a series with kryzhanovskite. Structurally close to other members of the phosphoferrite–reddingite series (or phosphoferrite group).

Small (<1 mm) nearly colorless, zones, fringes, or patches in olive phosphosiderite.

The structure is layered, with layers comprising chains formed by edge-sharing M(2)O4(OH)(H2O) octahedra; these octahedra form dimers and these share edges with separate M(1)O4(H2O)2 octahedra. The chains are linked to layers through the common vertices of M(2); octahedra and octaahedral layers are connected via the phosphate tetrahedra.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:1655:7

c178c62a-c2fb-4da0-934b-2b9e68a31c53

IMA Classification of GaryanselliteHide

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IMA Formula:

Mg2Fe3+(PO4)2(OH) · 2H2O

Classification of GaryanselliteHide

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8.CC.05

8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
C : With only medium-sized cations, RO4:H2O = 1:1.5

40.3.2.5

40 : HYDRATED NORMAL PHOSPHATES,ARSENATES AND VANADATES
3 : A3(XO4)2·xH2O

19.14.12

19 : Phosphates
14 : Phosphates of Fe and other metals

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Gas IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of GaryanselliteHide

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Comment:

"bronze on cleavages"

Cleavage:

Distinct/Good
{001}

Density:

3.16(4) g/cm3 (Measured) 3.154 g/cm3 (Calculated)

Optical Data of GaryanselliteHide

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RI values:

_n_α = 1.733 _n_β = 1.757 _n_γ = 1.761

2V:

Measured: 55° , Calculated: 42°

δ = 0.028

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Comments:

reddish brown (X=Z), yellow (Y)

Comments:

Orientation: X = b, Y = a, Z = c; absorption: Z = X > Y

Chemistry of GaryanselliteHide

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Mindat Formula:

(Mg,Fe)3(PO4)2(OH,O) · 1.5H2O

Crystallography of GaryanselliteHide

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Crystal System:

Orthorhombic

Class (H-M):

m m m _(_2/_m_2/_m_2/m ) - Dipyramidal

Cell Parameters:

a = 9.45 Å, b = 9.89 Å, c = 8.19 Å

Ratio:

a:b:c = 0.956 : 1 : 0.828

Unit Cell V:

765.44 ų (Calculated from Unit Cell)

Comment:

Space group is Pbna; parameters from Zubkova et al. (2016): a=9.44738, b=9.85976, c=8.14154, V=758.38

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
3.156 Å (100)
2.705 Å (60)
4.93 Å (50)
3.098 Å (40)
4.26 Å (30)
2.535 Å (30)
2.213 Å (30)

Comments:

Rapid Creek, Yukon, Canada. Data from the type description.

Geological EnvironmentHide

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Type Occurrence of GaryanselliteHide

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General Appearance of Type Material:

Place of Conservation of Type Material:

Royal Ontario Museum, Toronto, Canada (registration no. M37306)

Geological Setting of Type Material:

fractures in a sedimentary iron formation; rare, low-temperature species

Associated Minerals at Type Locality:

Synonyms of GaryanselliteHide

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Other Language Names for GaryanselliteHide

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Relationship of Garyansellite to other SpeciesHide

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Other Members of this group:

Correianevesite Fe2+Mn2+2(PO4)2 · 3H2O Orth. m m m _(_2/_m_2/_m_2/m )
Kryzhanovskite (Fe3+,Mn2+)3(PO4)2(OH,H2O)3 Orth. m m m _(_2/_m_2/_m_2/m )
Landesite Mn2+3-xFe3+x(PO4)2(OH)x · (3-x)H2O Orth. m m m _(_2/_m_2/_m_2/m )
Phosphoferrite (Fe2+,Mn2+)3(PO4)2 · 3H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P m n a
Reddingite (Mn2+,Fe2+)3(PO4)2 · 3H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P m n a

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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8.CC. Correianevesite Fe2+Mn2+2(PO4)2 · 3H2O Orth. m m m _(_2/_m_2/_m_2/m )
8.CC.05 Kryzhanovskite (Fe3+,Mn2+)3(PO4)2(OH,H2O)3 Orth. m m m _(_2/_m_2/_m_2/m )
8.CC.05 Landesite Mn2+3-xFe3+x(PO4)2(OH)x · (3-x)H2O Orth. m m m _(_2/_m_2/_m_2/m )
8.CC.05 Phosphoferrite (Fe2+,Mn2+)3(PO4)2 · 3H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P m n a
8.CC.05 Reddingite (Mn2+,Fe2+)3(PO4)2 · 3H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P m n a
8.CC.10 Kaatialaite Fe(H2AsO4)3 · 5H2O Mon. 2/m
8.CC.15 Leogangite Cu10(AsO4)4(SO4)(OH)6 · 8H2O Mon. 2/m : _B_2/b

Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for GaryanselliteHide

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Reference List:

Zubkova, N. V., Pekov, I. V., Kasatkin, A. V., Chukanov, N. V., Ksenofontov, D. A., Pushcharovsky, D. Yu. (2016) Crystal structure and refined formula of garyansellite Mg2Fe3+(PO4)2(OH) · 2H2O. Doklady Earth Sciences, 467 (1) 299-302 doi:10.1134/s1028334x16030235

Localities for GaryanselliteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Canada
Yukon Dawson mining district Big Fish River Robinson et al. (1992)
Rapid Creek (TL) 150-152. +3 other references
Kulan Camp (Area A; Area 1) Locality 5 Tomes et al. (2012)
USA
South Dakota Pennington County Keystone Mining District Glendale Big Chief Mine ?