Kipushite (original) (raw)

A valid IMA mineral species - grandfathered

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About KipushiteHide

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Formula:

(Cu,Zn)5Zn(PO4)2(OH)6 · H2O

Crystal System:

Monoclinic

Name:

Named in 1985 by Paul Piret, Michel Deliens and Jacqueline Piret Meunier, after the type locality at the Kipushi Mine (Prince Léopold Mine), Kipushi, Lubumbashi (Elizabethville), Katanga (Shaba), Congo (Zaïre).

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:2215:2

f3783ea8-5b8f-4eb6-9581-58fbaf696916

IMA Classification of KipushiteHide

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Approved, 'Grandfathered' (first described prior to 1959)

IMA Formula:

Cu6(PO4)2(OH)6 · H2O

Type description reference:

Classification of KipushiteHide

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8.DE.

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
E : With only medium-sized cations, (OH, etc.):RO4 = 3:1

42.2.4.1

42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
2 : (AB)3(XO4)Zq·xH2O

19.6.6

19 : Phosphates
6 : Phosphates of Zn

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Kip IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of KipushiteHide

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Transparency:

Transparent, Translucent

Fracture:

Irregular/Uneven

Density:

3.8 g/cm3 (Measured) 3.904 g/cm3 (Calculated)

Optical Data of KipushiteHide

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RI values:

_n_α = 1.693(2) _n_β = 1.738(2) _n_γ = 1.740(2)

δ = 0.047

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Dispersion:

weak to distinct

Comments:

X = colorless; Y = blue; Z = bright blue.

Comments:

2V(meas.) = Small

Chemistry of KipushiteHide

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Mindat Formula:

(Cu,Zn)5Zn(PO4)2(OH)6 · H2O

Crystallography of KipushiteHide

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Crystal System:

Monoclinic

Class (H-M):

2/m - Prismatic

Cell Parameters:

a = 12.197(2) Å, b = 9.156(2) Å, c = 10.667(2) Å
β = 96.77(2)°

Ratio:

a:b:c = 1.332 : 1 : 1.165

Unit Cell V:

1,182.94 ų (Calculated from Unit Cell)

Morphology:

Elongated aggregates of prisms; prismatic crystals of which lateral faces are uneven and rounded. Prisms {111} are elongate along [101] and terminated principally by (100). Forms present: {102}, {012} and {111}.

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0005202 Kipushite Piret P, Deliens M, Piret-Meunier J (1985) Occurrence and crystal structure of kipushite, a new copper-zinc phosphate from Kipushi, Zaire The Canadian Mineralogist 23 35-42 1985 Kipushi, Zaire 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
4.03 Å (100)
2.554 Å (90)
2.970 Å (60)
1.531 Å (60b)
12.2 Å (50)
3.386 Å (45)
6.06 Å (40)

Geological EnvironmentHide

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Type Occurrence of KipushiteHide

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General Appearance of Type Material:

More or less elongated aggregates of prisms up to 3 mm or rarely as isolated prismatic crystals up to 0.3 mm.

Place of Conservation of Type Material:

A holotype specimen of kipushite is registered in the mineralogical collection of the Musee royal de I'Afrique centrale (No. 14.026).

Associated Minerals at Type Locality:

Reference:

Piret,P., Deliens, M. Piret-Meunier, J. (1985) Occurrence and crystal structure of kipushite, a new copper-zinc phosphate from Kipushi, Zaire. The Canadian Mineralogist: 23: 35-42.

Synonyms of KipushiteHide

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Other Language Names for KipushiteHide

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Common AssociatesHide

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Associated Minerals Based on Photo Data:

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8.DE. Goldhillite Cu5Zn(AsO4)2(OH)6 · H2O Mon. 2/m : _P_21/b
8.DE. Arsenoveszelyite Cu2Zn(AsO4)(OH)3 · 2H2O Mon. 2/m : _P_21/b
8.DE.05 Senegalite Al2(PO4)(OH)(OH)2 · H2O Orth. m _m_2
8.DE.10 Fluellite Al2(PO4)F2(OH) · 7H2O Orth. m m m _(_2/_m_2/_m_2/m ) : F d d d
8.DE.15 Bulachite Al6(AsO4)3(OH)9(H2O)4 · 2H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
8.DE.20 Zapatalite Cu3Al4(PO4)3(OH)9 · 4H2O Tet.
8.DE.25 Ceruleite Cu2Al7(AsO4)4(OH)13 · 11.5H2O Mon. 2/m
8.DE.30 Veszelyite (Cu,Zn)2Zn(PO4)(OH)3 · 2H2O Mon. 2/m : _P_21/b
8.DE.35 Philipsburgite Cu5Zn(AsO4)(PO4)(OH)6 · H2O Mon. 2/m : _P_21/b
8.DE.40 Juanitaite (Cu,Ca,Fe)10Bi(AsO4)4(OH)11 · 2H2O Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _P_42/n n m
8.DE.45 Iangreyite Ca2Al7(PO4)2(PO3OH)2(OH,F)15 · 8H2O Trig. 32 : _P_321

Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for KipushiteHide

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Localities for KipushiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Australia
New South Wales Yancowinna Co. Broken Hill district Broken Hill Block 14 opencut Birch et al. (1997)
Austria
Tyrol Kufstein District Brixlegg Geyer - Silberberg District Silberberg Stocker adit Schnorrer et al. (2002)
China
Yunnan Honghe Gejiu City Gejiu Sn-polymetallic ore field Laochang ore field (Laochang Mine) p.6 +1 other reference
Kunming Dongchuan District Hercule Shen's Collection
Sanguozhuang Hercule Shen
Dongchuan Cu Mine Li et al. (2023)
DR Congo (TL)
Haut-Katanga Kipushi Territory Kipushi Kipushi Mine (TL) Piret et al. (1985) +2 other references
Italy
Sardinia South Sardinia Province Domusnovas Sa Duchessa Mine Sergio Mascia - Probed
Republic of the Congo
Bouenza Department Mfouati District Mfouati Palabanda quarries www.spiriferminerals.com (2020)
Yanga Koubenza quarries Spirifer Minerals specimens
UK
England Cumbria Allerdale Caldbeck Low Pike north slopes ? Braithwaite et al. (1988) +1 other reference
Caldbeck Fells Mining Region ? Stanley et al. (1991)
USA
California San Bernardino County Silver Lake Mining District Soda Mountains Zzyzx Blue Bell Mine Chorazewicz M.
Montana Granite County Philipsburg Mining District (Flint Creek Mining District) Black Pine Mine Per. Comm. from Eugene Ford re XRD ...
Nevada Humboldt County Iron Point Mining District Valmy Silver Coin Mine Silver Coin Mine. Compact Disc. Paul ...
Lander County North Battle Mountain Mining District Snowstorm mine (Mountain View mine) Castor et al. (2004)