Kotoite (original) (raw)

A valid IMA mineral species - grandfathered

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About KotoiteHide

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Colour:

Colorless; colorless in transmitted light

Lustre:

Vitreous, Sub-Vitreous

Crystal System:

Orthorhombic

Name:

Named in honor of Bundjirô Kotô (小藤文次郎) (8 April 1856, Iwami Province (now Shimane Prefecture) Japan - 8 March 1935, Tokyo, Japan), geologist and petrographer. He was a Professor of Geology, Science College, Imperial University of Tokyo, who first described the ore deposits of the type locality of Hol Kol.

Type locality has white to colorless masses in dolomite.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:2262:6

df31da50-b223-465c-a1ba-1c71ad92d2cc

IMA Classification of KotoiteHide

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Approved, 'Grandfathered' (first described prior to 1959)

Type description reference:

Classification of KotoiteHide

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6.AA.35

6 : BORATES
A : Monoborates
A : BO3, without additional anions; 1(D).

24.3.2.1

24 : ANHYDROUS BORATES
3 : AmBn[XO3]p

9.2.3

9 : Borates
2 : Borates of Be and Mg

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Ko IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of KotoiteHide

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Transparency:

Transparent, Translucent

Comment:

Generally low lustered granular

Colour:

Colorless; colorless in transmitted light

Parting:

On {101}. Also exhibits translation gliding.

Density:

3.10 g/cm3 (Measured) 3.06 g/cm3 (Calculated)

Optical Data of KotoiteHide

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RI values:

_n_α = 1.652 _n_β = 1.653 _n_γ = 1.673

2V:

Measured: 21° , Calculated: 26°

δ = 0.021

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Optical Extinction:

Parallel

Pleochroism:

Non-pleochroic

Chemistry of KotoiteHide

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Crystallography of KotoiteHide

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Crystal System:

Orthorhombic

Class (H-M):

m m m _(_2/_m_2/_m_2/m ) - Dipyramidal

Cell Parameters:

a = 5.401 Å, b = 8.422 Å, c = 4.507 Å

Ratio:

a:b:c = 0.641 : 1 : 0.535

Unit Cell V:

205.01 ų (Calculated from Unit Cell)

Morphology:

Massive, granular.

Twinning:

On {101} as the twin and composition plane, polysynthetic.

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0010864 Kotoite Effenberger H, Pertlik F (1984) Verfeinerung der kristallstrukturen der isotypen verbindungen M3(BO3)2 mit M=Mg, Co und Ni (strukturtyp: kotoit) Zeitschrift fur Kristallographie 166 129-140 1984 synthetic 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
3.46 Å (20)
2.67 Å (100)
2.32 Å (30)
2.23 Å (70)
2.18 Å (80)
1.73 Å (50)
1.67 Å (50)
1.52 Å (30)

Geological EnvironmentHide

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Type Occurrence of KotoiteHide

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General Appearance of Type Material:

Colorless massive to elongated grains to several mm.

Place of Conservation of Type Material:

The Natural History Museum, London, England, 1938,1286.
Harvard University, Cambridge, Massachusetts, USA, 94750.
National Museum of Natural History (Smithsonian), Washington, D.C., USA, 103502.

Geological Setting of Type Material:

Contact metamorphic zone of a granitic intrusion into dolomite.

Associated Minerals at Type Locality:

Reference:

Watanabe, T. (1939) Kotoit, ein neues gesteinsbildenes magnesiumborat. Mineralogische und petrographische Mitteilungen, Vienna: 50: 441-463.

Other Language Names for KotoiteHide

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Common AssociatesHide

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Associated Minerals Based on Photo Data:

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Fluorescence of KotoiteHide

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Other InformationHide

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Thermal Behaviour:

Melting Point = ~ 1340° C.

Notes:

Readily soluble in warm HCl or H2SO4.

Alters to Szaibelyite under hydrothermal conditions.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Kotoite in petrologyHide

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References for KotoiteHide

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Reference List:

**Palache, Charles, Berman, Harry, Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Ect. John Wiley and Sons, New York.**pp.328-329

Localities for KotoiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

China
Guangdong Heyuan Lianping Co. Dading Fe-Sn deposit Anthony
Hunan Hengyang Changning Co. Dayishan Sn-polymetallic ore field Qiliping Sn-Fe deposit Yang Guangming et al. (1985) +1 other reference
France
Occitanie Pyrénées-Orientales Céret Prats-de-Mollo-la-Preste Costabonne mines (Costabona mines) Aleksandrov et al. (2011)
Italy
Piedmont Metropolitan City of Turin Lessolo Calea Brosso Mine Gramaccioli (1978) +1 other reference
Japan
Iwate Prefecture Miyako City Dainikadokami mine Dr. Matsuo Nambu collection (curated at Geological Survey of Japan)
Kamineichi Neichi mine Masutomi Museum specimens +2 other references
North Korea
North Hwanghae Province Suan County Hol Kol Mine (Holgol; Suan; Namjong) Dana 7:II::323 +1 other reference
Eastern orebody watanabe (in: Geology and Mineral Resources of the Far East, University of Tokyo Press, 1969) +1 other reference
North orebody (New orebody) (TL) Tschermaks Min.Petr.Mitt. (1939) +2 other references
Western orebody watanabe (in: Geology and Mineral Resources of the Far East, University of Tokyo Press, 1969)
Romania
Bihor County Nucet Băiţa mining district Ş +1 other reference
Antoniu ore pipe Shimizu et al. (1998)
Pietroasa Ş +1 other reference
Aleului Valley Marincea et al. (2023)
Caraş-Severin County Baia Roshe Aleksandrov (2007)
Cluj County Iara Cacova Ierii Marincea (2000)
Russia
Khabarovsk Krai Dzhugdzhur Ridge Gonochan deposit Galuskina et al. (2008)
Krasnoyarsk Krai Taymyrskiy Autonomous Okrug Taimyr Peninsula Putoran Plateau Norilsk-Talnakh Mining Region Noril'sk Cu-Ni deposit Noril'sk-1 Cu-Ni deposit Medvezhyi Ruchei Mine Noril'sk I intrusive Shevko et al. (2019, September)
Republic of Karelia Pitkyarantsky District Pitkyaranta mining district Ivashchenko et al. (2006) +2 other references
Sakha [World of Stones 12:49]
Polar Yakutia Dogdo River Basin Tas-Khayakhtakh Range Titovskoe B deposit Aleksandrov (1998) +2 other references
Izvestkovyi Stream Snezhnoe B ore occurrence Galuskin +1 other reference
Nalednoe B ore occurrence Pavel.M. Kartashov (n.d.)
Verkhoyansk District Yana River Basin Dogdo river Kebirnin'ya creek (Nalednoye) W. Schreyer et al. (2003)
Spain
Andalusia Málaga Igualeja El Robledal Mine (Cañuelo skarn) Torres Ruiz +2 other references
USA
Alaska Nome Census Area Port Clarence Mining District Brooks Mountain Aleksandrov (1974b)
Nevada Elko County Railroad Mining District Alladin group Nevada Bunker Hill Mines Grey Eagle Mine (Lee Mine; Helen M. claims; Lucky May Mine) Gillerman (1982)
Utah Salt Lake County Little Cottonwood Mining District Alta Albian Basin Woodford et al. (2001)
Washington Snohomish County Darrington Mining District Jumbo Mountain Jumbo Mountain Nickel deposit Cannon (1975) +1 other reference